ACCESSION: MSBNK-MSSJ-MSJ01067
RECORD_TITLE: Acetamiprid; GC-EI-Q; MS; Positive; M+*
DATE: 2017.07.13 (Created 2016.12.28)
AUTHORS: Shimadzu Corporation., Kyoto, Japan
LICENSE: CC BY
COPYRIGHT: Shimadzu Cooperation., Kyoto, Japan
PUBLICATION: Shimadzu Collection of Pesticide GCMS Data

CH$NAME: Acetamiprid
CH$COMPOUND_CLASS: Non-Natural Product; Pesticides
CH$FORMULA: C₁₀H₁₁ClN₄
CH$EXACT_MASS: 222.06722
CH$SMILES: N#CN=C(C)N(C)Cc(c1)cnc(Cl)c1
CH$IUPAC: InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3
CH$LINK: INCHIKEY WCXDHFDTOYPNIE-UHFFFAOYSA-N
CH$LINK: PUBCHEM CID:213021

AC$INSTRUMENT: GCMS-QP2010 Plus, Shimadzu
AC$INSTRUMENT_TYPE: GC-EI-Q
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION EI
AC$CHROMATOGRAPHY: COLUMN_NAME Ptx-5MS(RESTEK), 0.32 mm I.D. x 30 m, df=0.25 microm
AC$CHROMATOGRAPHY: COLUMN_TEMPERATURE 80 C (1 min)-20 C/min - 180 C - 5 C/min - 330C (10 min)
AC$CHROMATOGRAPHY: INJECTION_TEMPERATURE 260 C
AC$CHROMATOGRAPHY: RETENTION_TIME 17.0 min

MS$FOCUSED_ION: ION_TYPE [M]+*
MS$FOCUSED_ION: PRECURSOR_M/Z 222.07

PK$SPLASH: splash10-0zfu-9800000000-b82c70df6ee48ad132f5
PK$NUM_PEAK: 146
PK$PEAK: m/z int. rel.int.
  40 8 8
  41 92 92
  42 622 622
  43 131 131
  46 11 11
  47 10 10
  49 46 46
  50 77 77
  51 70 70
  52 60 60
  53 16 16
  54 56 56
  55 91 91
  56 999 999
  57 74 74
  58 5 5
  62 31 31
  63 213 213
  64 68 68
  65 98 98
  66 48 48
  67 363 363
  68 19 19
  69 39 39
  71 122 122
  72 17 17
  73 134 134
  75 99 99
  76 99 99
  77 38 38
  79 24 24
  80 38 38
  84 31 31
  85 39 39
  87 11 11
  90 347 347
  91 118 118
  92 40 40
  93 45 45
  94 6 6
  97 8 8
  98 37 37
  99 221 221
  100 32 32
  101 82 82
  102 25 25
  103 30 30
  104 15 15
  106 29 29
  109 15 15
  112 60 60
  113 33 33
  114 92 92
  116 32 32
  117 9 9
  118 19 19
  119 35 35
  121 7 7
  122 12 12
  124 15 15
  125 11 11
  126 589 589
  127 136 136
  128 204 204
  129 82 82
  130 15 15
  131 15 15
  132 7 7
  136 7 7
  138 7 7
  139 74 74
  141 214 214
  142 7 7
  143 76 76
  144 28 28
  145 5 5
  146 26 26
  152 725 725
  153 338 338
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  155 294 294
  156 28 28
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  166 262 262
  167 54 54
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  169 15 15
  170 19 19
  171 24 24
  172 6 6
  174 5 5
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  181 127 127
  182 58 58
  183 52 52
  184 9 9
  185 11 11
  187 50 50
  188 19 19
  194 17 17
  197 13 13
  198 60 60
  199 5 5
  200 49 49
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  212 7 7
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  222 72 72
  223 57 57
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  236 6 6
  240 6 6
  241 5 5
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  303 5 5
  336 5 5
  349 7 7
  352 5 5
  353 10 10
  355 17 17
  412 13 13
  431 7 7
  457 5 5
  460 5 5
  485 5 5
  488 6 6
  492 7 7
  496 5 5
  497 13 13
  506 8 8
  511 11 11
  537 10 10
  567 6 6
  570 19 19
  585 7 7
  597 12 12
//