MassBank Record: MSBNK-RIKEN_NPDepo-NGA03855
ACCESSION: MSBNK-RIKEN_NPDepo-NGA03855
RECORD_TITLE: Deltaline; LC-ESI-QQQ; MS2; Frag=135.0V CID@15.0; [M+HCOO]-
DATE: 2018.04.04
AUTHORS: Nogawa T, Okano A, CSRS, RIKEN
LICENSE: CC BY
COMMENT: Origin: Plant
COMMENT: SubCategory_DNP: Terpenoid alkaloids, Diterpene alkaloid, Delphinium alkaloid
CH$NAME: Deltaline
CH$COMPOUND_CLASS: Alkaloids
CH$FORMULA: C27H41NO8
CH$EXACT_MASS: 507.6297
CH$SMILES: CCN1C[C@]2(C)CCC(OC)C34C2[C@H](OC(C)=O)C2(OCO[C@@]25C[C@H](OC)[C@H]2C[C@]3(O)C5[C@H]2OC)[C@@H]14
CH$IUPAC: InChI=1S/C27H41NO8/c1-7-28-12-23(3)9-8-17(32-5)26-20(23)21(36-14(2)29)27(22(26)28)25(34-13-35-27)11-16(31-4)15-10-24(26,30)19(25)18(15)33-6/h15-22,30H,7-13H2,1-6H3/t15-,16+,17?,18+,19?,20?,21+,22+,23+,24+,25-,26?,27?/m1/s1
CH$LINK: CAS
6836-11-9
CH$LINK: CHEMSPIDER
145078 390331 4475551 23219130
CH$LINK: INCHIKEY
DTTPWCNKTMQMTE-ZRAURUGBSA-N
AC$INSTRUMENT: Agilent 6410 Triple Quadrupole LC/MS system
AC$INSTRUMENT_TYPE: LC-ESI-QQQ
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE NEGATIVE
MS$FOCUSED_ION: PRECURSOR_TYPE [M+HCOO]-
PK$SPLASH: splash10-006x-4898880000-92fb7301141b515d6348
PK$NUM_PEAK: 4322
PK$PEAK: m/z int. rel.int.
50.7 13.57 13
50.8 19.69 19
50.9 25.6 25
51.0 26.44 26
51.1 21.42 21
51.3 12.47 12
51.4 16.91 16
51.5 23.87 23
51.6 26.54 26
51.7 22.4 22
51.8 15.35 15
52.0 11.59 11
52.1 16.33 16
52.2 21.47 21
52.3 22.92 22
52.4 19.41 19
52.6 14.58 14
52.7 20.21 20
52.8 26.26 26
52.9 25.72 25
53.0 17.5 17
53.2 5.49 5
53.3 12.01 11
53.4 22.03 22
53.5 27.33 27
53.6 23.73 23
53.7 14.41 14
53.9 7.54 7
54.0 15.14 15
54.1 23.22 23
54.2 25.06 25
54.3 19.5 19
54.5 9.06 9
54.6 14.34 14
54.7 23.03 23
54.8 26.72 26
54.9 21.28 21
55.0 11.4 11
55.2 9.74 9
55.3 19.2 19
55.4 26.07 26
55.5 25.06 25
55.6 17.87 17
56.4 10.18 10
56.5 14.04 14
56.6 20.3 20
56.7 24.32 24
56.8 22.24 22
56.9 15.32 15
57.1 11.1 11
57.2 18.62 18
57.3 25.3 25
57.4 24.62 24
57.5 16.91 16
57.7 7.17 7
57.8 12.64 12
57.9 21.12 21
58.0 26.26 26
58.1 23.73 23
58.2 15.02 15
58.4 7.99 7
58.5 15.91 15
58.6 23.83 23
58.7 25.23 25
58.8 20.14 20
59.0 12.45 12
59.1 17.01 16
59.2 23.27 23
59.3 25.06 25
59.4 20.51 20
59.7 13.17 13
59.8 20.44 20
59.9 25.2 25
60.0 22.26 22
60.1 13.95 13
60.3 11.24 11
60.4 20.09 20
60.5 27.19 27
60.6 26.7 26
60.7 19.06 19
61.0 11.19 11
61.1 19.13 19
61.2 23.71 23
61.3 21.21 21
61.4 14.37 14
61.6 11.63 11
61.7 18.01 17
61.8 23.17 23
61.9 22.26 22
62.0 15.81 15
62.2 10.53 10
62.3 16.73 16
62.4 22.49 22
62.5 22.96 22
62.6 18.43 18
62.8 10.72 10
62.9 14.39 14
63.0 21.68 21
63.1 26.58 26
63.2 24.2 24
63.3 16.37 16
63.5 10.72 10
63.6 17.17 17
63.7 23.69 23
63.8 25.04 25
63.9 20.16 20
64.7 13.41 13
64.8 16.65 16
64.9 22.38 22
65.0 26.07 26
65.1 24.74 24
65.2 18.73 18
65.4 11.14 11
65.5 15.93 15
65.6 22.28 22
65.7 24.27 24
65.8 20.25 20
66.0 11.68 11
66.1 15.63 15
66.2 22.73 22
66.3 26.56 26
66.4 23.08 23
66.5 14.55 14
66.7 7.94 7
66.8 15.02 15
66.9 22.35 22
67.0 23.06 23
67.1 16.65 16
67.3 10.16 10
67.4 17.26 17
67.5 24.88 24
67.6 26.23 26
67.7 20.23 20
67.8 12.01 11
68.0 11.17 11
68.1 17.92 17
68.2 22.49 22
68.3 21.51 21
68.4 16.3 16
68.6 10.65 10
68.7 15.11 15
68.8 21.72 21
68.9 25.37 25
69.0 22.7 22
69.1 15.95 15
69.3 14.09 14
69.4 20.86 20
69.5 25.04 25
69.6 21.7 21
69.7 12.99 12
69.9 8.34 8
70.0 16.87 16
70.1 24.36 24
70.2 24.5 24
70.3 18.06 18
70.5 11.19 11
70.6 15.91 15
70.7 20.7 20
70.8 21.26 21
70.9 17.57 17
71.2 12.64 12
71.3 16.63 16
71.4 19.97 19
71.5 19.86 19
71.6 16.19 16
71.8 12.36 12
71.9 17.15 17
72.0 22.19 22
72.1 22.59 22
72.2 17.75 17
72.5 12.08 12
72.6 18.15 18
72.7 22.38 22
72.8 20.37 20
72.9 13.06 13
73.1 9.32 9
73.2 18.66 18
73.3 27.4 27
73.4 28.5 28
73.5 22.1 22
74.4 13.38 13
74.5 19.88 19
74.6 24.9 24
74.7 24.08 24
74.8 17.29 17
75.0 8.5 8
75.1 14.76 14
75.2 22.82 22
75.3 24.83 24
75.4 18.99 18
75.6 8.95 8
75.7 14.34 14
75.8 22.54 22
75.9 26.61 26
76.0 22.99 22
76.1 14.11 14
76.3 7.71 7
76.4 15.84 15
76.5 24.76 24
76.6 27.12 27
76.7 21.51 21
76.9 11.7 11
77.0 16.42 16
77.1 22.66 22
77.2 24.08 24
77.3 19.34 19
77.6 11.7 11
77.7 18.78 18
77.8 24.53 24
77.9 24.08 24
78.0 17.45 17
78.2 8.06 8
78.3 13.97 13
78.4 23.06 23
78.5 27.66 27
78.6 24.27 24
78.7 16.54 16
78.9 12.5 12
79.0 17.92 17
79.1 22.7 22
79.2 23.17 23
79.3 19.13 19
79.5 12.61 12
79.6 16.49 16
79.7 22.26 22
79.8 23.66 23
79.9 18.1 18
80.2 10.98 10
80.3 18.13 18
80.4 22.78 22
80.5 21.47 21
80.6 15.3 15
80.8 8.76 8
80.9 14.79 14
81.0 21.58 21
81.1 22.49 22
81.2 16.89 16
81.4 10.56 10
81.5 16.42 16
81.6 23.06 23
81.7 24.62 24
81.8 19.95 19
82.0 11.03 11
82.1 15.32 15
82.2 23.06 23
82.3 27.66 27
82.4 25.06 25
82.5 17.15 17
82.7 11.26 11
82.8 18.66 18
82.9 26.26 26
83.0 27.33 27
83.1 21.05 21
83.4 13.06 13
83.5 20.84 20
83.6 25.32 25
83.7 22.49 22
83.8 15.11 15
84.0 11.47 11
84.1 18.43 18
84.2 24.99 24
84.3 25.77 25
84.4 20.51 20
84.6 11.98 11
84.7 16.09 16
84.8 22.82 22
84.9 26.05 26
85.0 21.98 21
85.1 13.2 13
85.3 8.69 8
85.4 16.16 16
85.5 21.47 21
85.6 19.22 19
85.7 11.98 11
85.9 7.62 7
86.0 14.51 14
86.1 22.19 22
86.2 24.85 24
86.3 20.84 20
86.5 12.59 12
86.6 17.24 17
86.7 24.46 24
86.8 27.56 27
86.9 23.27 23
87.0 14.81 14
87.2 10.37 10
87.3 17.38 17
87.4 23.38 23
87.5 22.75 22
87.6 16.3 16
87.8 10.98 10
87.9 17.94 17
88.0 25.23 25
88.1 26.82 26
88.2 21.96 21
88.5 15.67 15
88.6 21.86 21
88.7 25.39 25
88.8 22.92 22
88.9 16.54 16
89.1 13.41 13
89.2 20.02 19
89.3 26.47 26
89.4 27.14 27
89.5 20.79 20
89.7 9.27 9
89.8 14.41 14
89.9 22.78 22
90.0 26.4 26
90.1 22.47 22
90.4 15.32 15
90.5 20.93 20
90.6 23.73 23
90.7 21.58 21
90.8 16.4 16
91.0 13.13 13
91.1 18.59 18
91.2 24.41 24
91.3 25.09 25
91.4 19.55 19
91.7 13.1 13
91.8 20.21 20
91.9 24.83 24
92.0 22.96 22
92.1 16.51 16
92.3 13.92 13
92.4 20.86 20
92.5 26.26 26
92.6 25.58 25
92.7 19.86 19
92.9 12.66 12
93.0 16.58 16
93.1 22.24 22
93.2 23.9 23
93.3 18.83 18
93.5 6.45 6
93.6 11.0 10
93.7 21.47 21
93.8 30.04 30
93.9 30.9 30
94.0 24.13 24
94.1 15.25 15
94.3 13.27 13
94.4 19.6 19
94.5 22.92 22
94.6 19.32 19
94.7 11.63 11
94.9 9.46 9
95.0 17.87 17
95.1 25.32 25
95.2 25.39 25
95.3 17.87 17
95.5 9.93 9
95.6 18.03 18
95.7 25.72 25
95.8 24.6 24
95.9 15.58 15
96.1 6.56 6
96.2 13.34 13
96.3 21.7 21
96.4 25.41 25
96.5 22.4 22
97.4 8.88 8
97.5 17.19 17
97.6 26.02 25
97.7 28.31 28
97.8 22.54 22
98.1 13.43 13
98.2 21.61 21
98.3 26.23 26
98.4 22.87 22
98.7 14.13 14
98.8 23.2 23
98.9 29.41 29
99.0 27.07 27
99.1 18.15 18
99.3 8.64 8
99.4 14.39 14
99.5 21.72 21
99.6 24.34 24
99.7 19.95 19
99.8 12.1 12
100.0 9.88 9
100.1 17.47 17
100.2 23.73 23
100.3 23.31 23
100.4 16.89 16
100.6 11.21 11
100.7 18.06 18
100.8 24.97 24
100.9 25.32 25
101.0 18.41 18
101.2 7.26 7
101.3 12.66 12
101.4 21.02 20
101.5 24.57 24
101.6 20.42 20
101.7 12.8 12
101.9 10.51 10
102.0 17.5 17
102.1 23.94 23
102.2 24.74 24
102.3 19.29 19
102.5 11.17 11
102.6 16.89 16
102.7 24.6 24
102.8 26.77 26
102.9 20.88 20
103.2 12.82 12
103.3 19.72 19
103.4 23.64 23
103.5 22.38 22
103.6 18.27 18
103.8 16.37 16
103.9 20.58 20
104.0 24.36 24
104.1 23.52 23
104.2 17.26 17
104.4 8.74 8
104.5 15.0 14
104.6 23.83 23
104.7 27.84 27
104.8 24.22 24
104.9 17.12 17
105.1 15.42 15
105.2 21.02 20
105.3 24.88 24
105.4 23.36 23
105.5 16.89 16
105.7 8.46 8
105.8 14.41 14
105.9 23.27 23
106.0 27.4 27
106.1 23.43 23
106.2 15.53 15
106.4 13.43 13
106.5 19.6 19
106.6 23.62 23
106.7 22.1 22
106.8 16.51 16
107.0 12.89 12
107.1 19.18 19
107.2 25.37 25
107.3 25.58 25
107.4 19.15 19
107.6 9.37 9
107.7 15.07 15
107.8 24.08 24
107.9 28.75 28
108.0 25.04 25
108.1 16.07 16
108.3 9.2 9
108.4 15.0 14
108.5 21.07 21
108.6 22.7 22
108.7 19.48 19
108.9 14.2 14
109.0 17.29 17
109.1 21.61 21
109.2 22.92 22
109.3 18.92 18
109.6 10.42 10
109.7 19.69 19
109.8 27.82 27
109.9 27.84 27
110.0 19.74 19
110.2 9.32 9
110.3 16.75 16
110.4 25.44 25
110.5 26.33 26
110.6 18.34 18
110.8 6.94 6
110.9 13.5 13
111.0 22.61 22
111.1 26.44 26
111.2 22.1 22
111.3 13.62 13
111.5 10.91 10
111.6 19.39 19
111.7 26.65 26
111.8 26.58 26
111.9 19.01 18
112.2 11.82 11
112.3 19.64 19
112.4 23.64 23
112.5 20.93 20
112.6 14.6 14
112.8 12.26 12
112.9 18.1 18
113.0 22.8 22
113.1 22.21 22
113.2 16.91 16
113.4 10.7 10
113.5 15.07 15
113.6 20.86 20
113.7 22.99 22
113.8 19.48 19
114.0 11.47 11
114.1 15.58 15
114.2 22.52 22
114.3 25.6 25
114.4 21.93 21
114.5 14.83 14
114.7 11.24 11
114.8 16.42 16
114.9 21.07 21
115.0 20.77 20
115.1 15.72 15
115.3 10.35 10
115.4 14.76 14
115.5 19.88 19
115.6 21.56 21
115.7 18.71 18
116.0 12.45 12
116.1 18.97 18
116.2 24.85 24
116.3 25.11 25
116.4 19.29 19
116.6 10.77 10
116.7 15.65 15
116.8 22.21 22
116.9 23.8 23
117.0 18.55 18
117.2 8.78 8
117.3 13.97 13
117.4 22.99 22
117.5 28.5 28
117.6 25.86 25
117.7 17.38 17
117.9 10.53 10
118.0 17.08 17
118.1 23.97 23
118.2 25.11 25
118.3 19.57 19
118.5 10.0 9
118.6 15.3 15
118.7 23.73 23
118.8 27.66 27
118.9 23.22 23
119.0 14.55 14
119.2 12.99 12
119.3 21.21 21
119.4 26.79 26
119.5 24.55 24
119.6 16.0 15
119.8 8.15 8
119.9 16.42 16
120.0 26.44 26
120.1 30.06 30
120.2 24.95 24
120.3 16.0 15
120.5 13.34 13
120.6 21.65 21
120.7 29.25 29
120.8 29.53 29
120.9 21.4 21
121.7 12.45 12
121.8 18.24 18
121.9 25.91 25
122.0 28.43 28
122.1 22.87 22
122.2 12.92 12
122.4 7.66 7
122.5 15.77 15
122.6 23.43 23
122.7 24.04 24
122.8 17.17 17
123.0 8.5 8
123.1 16.61 16
123.2 27.42 27
123.3 31.72 31
123.4 25.81 25
123.5 14.86 14
123.7 11.19 11
123.8 19.81 19
123.9 25.79 25
124.0 24.01 23
124.1 16.4 16
124.3 8.39 8
124.4 13.67 13
124.5 21.0 20
124.6 24.48 24
124.7 21.47 21
125.6 11.8 11
125.7 17.5 17
125.8 21.98 21
125.9 20.56 20
126.0 14.25 14
126.2 9.46 9
126.3 15.72 15
126.4 23.2 23
126.5 26.63 26
126.6 23.69 23
126.7 16.89 16
126.9 12.73 12
127.0 17.19 17
127.1 18.92 18
127.2 14.39 14
127.4 5.23 5
127.5 10.63 10
127.6 19.88 19
127.7 26.09 26
127.8 24.6 24
127.9 16.68 16
128.1 9.3 9
128.2 17.24 17
128.3 26.19 26
128.4 28.19 28
128.5 21.96 21
128.6 13.1 13
128.8 11.1 11
128.9 18.03 18
129.0 24.01 23
129.1 24.5 24
129.2 19.22 19
129.4 13.67 13
129.5 20.93 20
129.6 28.71 28
129.7 28.87 28
129.8 20.3 20
130.0 8.01 8
130.1 14.74 14
130.2 24.57 24
130.3 29.74 29
130.4 27.0 26
130.5 19.32 19
131.3 9.11 9
131.4 14.95 14
131.5 24.18 24
131.6 27.49 27
131.7 20.86 20
131.9 7.52 7
132.0 13.83 13
132.1 23.41 23
132.2 28.1 28
132.3 24.88 24
132.4 17.01 16
132.6 10.07 10
132.7 14.44 14
132.8 18.85 18
132.9 18.85 18
133.0 14.72 14
133.2 10.35 10
133.3 15.18 15
133.4 21.54 21
133.5 23.78 23
133.6 19.41 19
133.9 12.8 12
134.0 20.02 19
134.1 24.27 24
134.2 21.63 21
134.5 13.17 13
134.6 20.95 20
134.7 27.21 27
134.8 27.03 27
134.9 20.51 20
135.2 12.52 12
135.3 21.19 21
135.4 27.68 27
135.5 26.7 26
135.6 19.34 19
135.8 13.38 13
135.9 20.49 20
136.0 27.12 27
136.1 27.05 27
136.2 20.86 20
137.1 12.66 12
137.2 19.79 19
137.3 27.07 27
137.4 28.29 28
137.5 22.28 22
138.3 7.01 7
138.4 10.93 10
138.5 19.15 19
138.6 25.58 25
138.7 25.04 25
138.8 18.24 18
139.0 11.4 11
139.1 17.45 17
139.2 24.2 24
139.3 25.65 25
139.4 20.74 20
139.6 11.28 11
139.7 15.56 15
139.8 23.03 23
139.9 26.49 26
140.0 22.42 22
140.3 14.88 14
140.4 22.1 22
140.5 27.35 27
140.6 26.63 26
140.7 19.88 19
140.8 11.24 11
141.0 9.18 9
141.1 16.19 16
141.2 21.16 21
141.3 20.04 20
141.6 15.07 15
141.7 21.79 21
141.8 26.89 26
141.9 25.84 25
142.0 18.71 18
142.2 8.41 8
142.3 13.45 13
142.4 20.88 20
142.5 23.8 23
142.6 19.88 19
142.9 13.57 13
143.0 20.14 20
143.1 24.29 24
143.2 23.01 22
143.3 17.8 17
143.5 12.45 12
143.6 16.54 16
143.7 21.49 21
143.8 22.38 22
143.9 18.15 18
144.1 11.33 11
144.2 16.37 16
144.3 24.43 24
144.4 28.94 28
144.5 26.05 26
144.6 18.66 18
144.8 14.51 14
144.9 20.32 20
145.0 25.25 25
145.1 24.29 24
145.2 17.45 17
145.4 9.2 9
145.5 15.23 15
145.6 23.57 23
145.7 27.66 27
145.8 24.43 24
145.9 17.19 17
146.1 15.18 15
146.2 22.66 22
146.3 27.98 27
146.4 25.53 25
146.5 16.65 16
146.7 9.81 9
146.8 17.59 17
146.9 24.15 24
147.0 22.92 22
147.1 15.58 15
147.3 11.14 11
147.4 18.76 18
147.5 26.0 25
147.6 26.72 26
147.7 20.56 20
147.9 10.65 10
148.0 15.25 15
148.1 23.2 23
148.2 28.22 28
148.3 26.56 26
148.4 19.62 19
148.6 12.19 12
148.7 17.43 17
148.8 23.99 23
148.9 25.95 25
149.0 21.47 21
149.1 14.32 14
149.3 13.03 13
149.4 19.97 19
149.5 25.13 25
149.6 23.59 23
149.7 16.63 16
149.9 11.42 11
150.0 17.24 17
150.1 23.01 22
150.2 24.18 24
150.3 20.39 20
150.5 13.9 13
150.6 17.54 17
150.7 22.31 22
150.8 23.31 23
150.9 19.9 19
151.1 13.99 13
151.2 16.7 16
151.3 21.93 21
151.4 25.46 25
151.5 23.92 23
151.6 18.29 18
151.8 13.5 13
151.9 18.34 18
152.0 23.87 23
152.1 25.16 25
152.2 20.02 19
152.5 11.14 11
152.6 19.39 19
152.7 25.18 25
152.8 23.76 23
152.9 16.89 16
153.1 11.17 11
153.2 16.44 16
153.3 21.56 21
153.4 22.05 22
153.5 17.89 17
153.7 11.59 11
153.8 14.83 14
153.9 19.81 19
154.0 21.61 21
154.1 18.29 18
154.3 10.77 10
154.4 14.06 14
154.5 20.23 20
154.6 24.46 24
154.7 23.52 23
154.8 18.03 18
155.0 12.17 12
155.1 18.22 18
155.2 25.77 25
155.3 27.82 27
155.4 21.82 21
155.5 12.38 12
155.7 10.0 9
155.8 17.82 17
155.9 23.66 23
156.0 23.06 23
156.1 17.87 17
156.3 13.9 13
156.4 18.8 18
156.5 23.87 23
156.6 24.2 24
156.7 18.76 18
156.9 10.42 10
157.0 15.35 15
157.1 22.61 22
157.2 25.93 25
157.3 22.17 22
157.4 13.76 13
157.6 8.32 8
157.7 15.88 15
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599.6 18.71 18
//
system version 2.2.8-SNAPSHOT
