ACCESSION: MSBNK-LCSB-LU025304
RECORD_TITLE: Danazol; LC-ESI-QFT; MS2; CE: 60; R=17500; [M+H]+
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 253
COMMENT: DATASET 20200303_ENTACT_RP_MIX505
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 9866
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 9865
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: Danazol
CH$NAME: (1S,2R,13R,14S,17R,18S)-17-ethynyl-2,18-dimethyl-7-oxa-6-azapentacyclo[11.7.0.02,10.04,8.014,18]icosa-4(8),5,9-trien-17-ol
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C22H27NO2
CH$EXACT_MASS: 337.2042
CH$SMILES: C[C@]12CC[C@H]3[C@@H](CCC4=CC5=C(C[C@]34C)C=NO5)[C@@H]1CC[C@@]2(O)C#C
CH$IUPAC: InChI=1S/C22H27NO2/c1-4-22(24)10-8-18-16-6-5-15-11-19-14(13-23-25-19)12-20(15,2)17(16)7-9-21(18,22)3/h1,11,13,16-18,24H,5-10,12H2,2-3H3/t16-,17+,18+,20+,21+,22+/m1/s1
CH$LINK: CAS
17230-88-5
CH$LINK: CHEBI
4315
CH$LINK: KEGG
C06938
CH$LINK: PUBCHEM
CID:28417
CH$LINK: INCHIKEY
POZRVZJJTULAOH-LHZXLZLDSA-N
CH$LINK: CHEMSPIDER
26436
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 60
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 18.811 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 79.0211
MS$FOCUSED_ION: PRECURSOR_M/Z 338.2115
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_INTENSITY 5674011.4375
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-05tg-3900000000-236562a534733094e439
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
50.0152 C4H2+ 1 50.0151 1.57
51.023 C4H3+ 1 51.0229 1.91
53.0022 C3HO+ 1 53.0022 -0.1
53.0386 C4H5+ 1 53.0386 0.89
54.0338 C3H4N+ 1 54.0338 -0.62
55.0179 C3H3O+ 1 55.0178 0.82
55.0542 C4H7+ 1 55.0542 0.25
56.0495 C3H6N+ 1 56.0495 0.65
65.0385 C5H5+ 1 65.0386 -1.01
67.0415 C4H5N+ 1 67.0417 -2.09
67.0542 C5H7+ 1 67.0542 0.04
68.0495 C4H6N+ 1 68.0495 -0.2
69.0335 C4H5O+ 1 69.0335 -0.05
69.0698 C5H9+ 1 69.0699 -0.73
70.0287 C3H4NO+ 1 70.0287 -0.27
70.0651 C4H8N+ 1 70.0651 -0.06
72.0443 C3H6NO+ 1 72.0444 -1.16
77.0385 C6H5+ 1 77.0386 -0.39
79.0542 C6H7+ 1 79.0542 0.01
80.0495 C5H6N+ 1 80.0495 0.03
81.0335 C5H5O+ 1 81.0335 0.7
81.0699 C6H9+ 1 81.0699 -0.16
82.0287 C4H4NO+ 1 82.0287 -0.13
82.0651 C5H8N+ 1 82.0651 0.23
83.0491 C5H7O+ 1 83.0491 -0.66
84.0444 C4H6NO+ 1 84.0444 0.07
84.0807 C5H10N+ 1 84.0808 -0.39
91.0542 C7H7+ 1 91.0542 0.25
92.0494 C6H6N+ 1 92.0495 -0.78
93.0699 C7H9+ 1 93.0699 0.53
94.0652 C6H8N+ 1 94.0651 0.49
95.0492 C6H7O+ 1 95.0491 0.66
95.073 C6H9N+ 1 95.073 0.2
95.0855 C7H11+ 1 95.0855 0.17
96.0444 C5H6NO+ 1 96.0444 -0.24
96.0807 C6H10N+ 1 96.0808 -0.73
97.0648 C6H9O+ 1 97.0648 0.08
98.06 C5H8NO+ 1 98.06 -0.48
103.0543 C8H7+ 1 103.0542 0.4
104.0621 C8H8+ 1 104.0621 0.36
105.0699 C8H9+ 1 105.0699 0.4
106.0652 C7H8N+ 1 106.0651 0.32
107.0491 C7H7O+ 1 107.0491 -0.09
107.0728 C7H9N+ 1 107.073 -1.28
107.0855 C8H11+ 1 107.0855 -0.03
108.0445 C6H6NO+ 1 108.0444 0.68
108.0808 C7H10N+ 1 108.0808 0.04
109.0522 C6H7NO+ 1 109.0522 -0.27
109.0648 C7H9O+ 1 109.0648 0.2
109.1013 C8H13+ 1 109.1012 0.68
110.0602 C6H8NO+ 1 110.06 1.71
111.0801 C7H11O+ 1 111.0804 -3.17
115.0542 C9H7+ 1 115.0542 0.11
116.0621 C9H8+ 1 116.0621 0.34
117.0699 C9H9+ 1 117.0699 0.3
118.0651 C8H8N+ 1 118.0651 -0.41
119.0493 C8H7O+ 1 119.0491 1.4
119.0856 C9H11+ 1 119.0855 0.43
120.0444 C7H6NO+ 1 120.0444 0.43
120.0808 C8H10N+ 1 120.0808 0.42
121.0648 C8H9O+ 1 121.0648 0.25
121.0886 C8H11N+ 1 121.0886 0.39
121.1013 C9H13+ 1 121.1012 0.94
122.0601 C7H8NO+ 1 122.06 0.55
122.0964 C8H12N+ 1 122.0964 0.11
123.068 C7H9NO+ 1 123.0679 1.02
123.0804 C8H11O+ 1 123.0804 -0.56
124.0756 C7H10NO+ 1 124.0757 -0.62
128.0621 C10H8+ 1 128.0621 0.17
129.0699 C10H9+ 1 129.0699 0.2
130.0651 C9H8N+ 1 130.0651 -0.35
130.0776 C10H10+ 1 130.0777 -0.6
131.0493 C9H7O+ 1 131.0491 1.24
131.0732 C9H9N+ 1 131.073 1.66
131.0856 C10H11+ 1 131.0855 0.47
132.0572 C9H8O+ 1 132.057 1.6
132.0809 C9H10N+ 1 132.0808 0.63
132.0934 C10H12+ 1 132.0934 0.49
133.0521 C8H7NO+ 1 133.0522 -1.13
133.0649 C9H9O+ 1 133.0648 0.46
133.0888 C9H11N+ 1 133.0886 1.33
133.1012 C10H13+ 1 133.1012 0.28
134.06 C8H8NO+ 1 134.06 -0.3
134.0964 C9H12N+ 1 134.0964 -0.36
135.0679 C8H9NO+ 1 135.0679 0.18
135.0803 C9H11O+ 1 135.0804 -0.97
135.1045 C9H13N+ 1 135.1043 2.04
135.1171 C10H15+ 1 135.1168 1.9
136.0757 C8H10NO+ 1 136.0757 0.09
141.0699 C11H9+ 1 141.0699 0.09
142.0778 C11H10+ 1 142.0777 0.53
143.0856 C11H11+ 1 143.0855 0.23
144.0807 C10H10N+ 1 144.0808 -0.79
144.0934 C11H12+ 1 144.0934 0.35
145.0649 C10H9O+ 1 145.0648 0.64
145.0887 C10H11N+ 1 145.0886 0.91
145.1012 C11H13+ 1 145.1012 0.26
146.0725 C10H10O+ 1 146.0726 -0.5
146.0965 C10H12N+ 1 146.0964 0.4
147.0679 C9H9NO+ 1 147.0679 0.37
147.0805 C10H11O+ 1 147.0804 0.14
147.1043 C10H13N+ 1 147.1043 0.11
147.117 C11H15+ 1 147.1168 1.12
148.0757 C9H10NO+ 1 148.0757 0.08
149.0836 C9H11NO+ 1 149.0835 0.51
149.0957 C10H13O+ 1 149.0961 -2.48
150.0915 C9H12NO+ 1 150.0913 0.93
152.0621 C12H8+ 1 152.0621 0.56
153.0699 C12H9+ 1 153.0699 0.18
154.0654 C11H8N+ 1 154.0651 1.7
154.0777 C12H10+ 1 154.0777 -0.3
155.0856 C12H11+ 1 155.0855 0.31
156.0811 C11H10N+ 1 156.0808 2.11
156.0936 C12H12+ 1 156.0934 1.31
157.0649 C11H9O+ 1 157.0648 0.4
157.0891 C11H11N+ 1 157.0886 2.99
157.1012 C12H13+ 1 157.1012 0.35
158.0727 C11H10O+ 1 158.0726 0.32
158.0963 C11H12N+ 1 158.0964 -0.49
159.0806 C11H11O+ 1 159.0804 1.1
159.105 C11H13N+ 1 159.1043 4.81
159.117 C12H15+ 1 159.1168 0.96
160.0754 C10H10NO+ 1 160.0757 -1.73
160.0882 C11H12O+ 1 160.0883 -0.5
160.1119 C11H14N+ 1 160.1121 -1.02
161.0961 C11H13O+ 1 161.0961 0.28
161.1323 C12H17+ 1 161.1325 -1.2
162.0913 C10H12NO+ 1 162.0913 0.03
165.0698 C13H9+ 1 165.0699 -0.19
166.0779 C13H10+ 1 166.0777 1.03
167.0856 C13H11+ 1 167.0855 0.58
168.0806 C12H10N+ 1 168.0808 -1.2
168.0935 C13H12+ 1 168.0934 0.69
169.065 C12H9O+ 1 169.0648 1.47
169.0887 C12H11N+ 1 169.0886 0.63
169.1012 C13H13+ 1 169.1012 -0.02
170.0963 C12H12N+ 1 170.0964 -0.61
170.1093 C13H14+ 1 170.109 1.61
171.0807 C12H11O+ 1 171.0804 1.58
171.1044 C12H13N+ 1 171.1043 1.01
171.1168 C13H15+ 1 171.1168 0.02
172.0755 C11H10NO+ 1 172.0757 -0.97
172.1122 C12H14N+ 1 172.1121 0.67
173.0831 C11H11NO+ 1 173.0835 -2.18
173.0961 C12H13O+ 1 173.0961 -0.16
173.1323 C13H17+ 1 173.1325 -1.27
174.0915 C11H12NO+ 1 174.0913 0.75
174.1279 C12H16N+ 1 174.1277 0.87
176.1068 C11H14NO+ 1 176.107 -1.22
178.0779 C14H10+ 1 178.0777 1.15
179.0855 C14H11+ 1 179.0855 -0.12
180.0933 C14H12+ 1 180.0934 -0.44
181.0655 C13H9O+ 1 181.0648 4.1
181.0876 C13H11N+ 1 181.0886 -5.62
181.1013 C14H13+ 1 181.1012 0.51
182.0726 C13H10O+ 1 182.0726 -0.1
182.0962 C13H12N+ 1 182.0964 -1.38
182.1091 C14H14+ 1 182.109 0.61
183.0808 C13H11O+ 1 183.0804 2.18
183.1037 C13H13N+ 1 183.1043 -3.19
183.1171 C14H15+ 1 183.1168 1.46
184.0884 C13H12O+ 1 184.0883 0.86
184.1118 C13H14N+ 1 184.1121 -1.25
185.0959 C13H13O+ 1 185.0961 -0.86
185.1328 C14H17+ 1 185.1325 1.9
186.0917 C12H12NO+ 1 186.0913 1.89
186.128 C13H16N+ 1 186.1277 1.6
187.1112 C13H15O+ 1 187.1117 -2.93
188.1073 C12H14NO+ 1 188.107 1.67
189.0699 C15H9+ 1 189.0699 0.24
190.0779 C15H10+ 1 190.0777 1.22
191.0857 C15H11+ 1 191.0855 1.08
192.0936 C15H12+ 1 192.0934 1.17
193.1013 C15H13+ 1 193.1012 0.88
194.0963 C14H12N+ 1 194.0964 -0.42
194.1091 C15H14+ 1 194.109 0.58
195.0806 C14H11O+ 1 195.0804 0.57
195.1166 C15H15+ 1 195.1168 -1.04
196.0881 C14H12O+ 1 196.0883 -0.73
196.1123 C14H14N+ 1 196.1121 1.03
196.1249 C15H16+ 1 196.1247 1.1
197.0962 C14H13O+ 1 197.0961 0.69
197.1328 C15H17+ 1 197.1325 1.42
198.1276 C14H16N+ 1 198.1277 -0.77
199.1117 C14H15O+ 1 199.1117 -0.33
200.1072 C13H14NO+ 1 200.107 0.85
202.078 C16H10+ 1 202.0777 1.66
202.1231 C13H16NO+ 1 202.1226 2.03
203.0856 C16H11+ 1 203.0855 0.47
204.0932 C16H12+ 1 204.0934 -0.92
205.1012 C16H13+ 1 205.1012 -0.08
206.1087 C16H14+ 1 206.109 -1.31
207.1066 C15H13N+ 1 207.1043 11.19
207.1167 C16H15+ 1 207.1168 -0.83
208.1115 C15H14N+ 1 208.1121 -2.62
208.1248 C16H16+ 1 208.1247 0.88
209.0959 C15H13O+ 1 209.0961 -1.1
209.1321 C16H17+ 1 209.1325 -1.94
210.1036 C15H14O+ 1 210.1039 -1.65
210.1279 C15H16N+ 1 210.1277 0.72
210.1393 C16H18+ 1 210.1403 -4.67
211.1118 C15H15O+ 1 211.1117 0.19
211.1481 C16H19+ 1 211.1481 0.08
215.0856 C17H11+ 1 215.0855 0.52
216.0936 C17H12+ 1 216.0934 0.97
217.1008 C17H13+ 1 217.1012 -1.61
218.1091 C17H14+ 1 218.109 0.52
219.1175 C17H15+ 1 219.1168 2.91
220.1122 C16H14N+ 1 220.1121 0.71
220.1245 C17H16+ 1 220.1247 -0.62
221.0958 C16H13O+ 1 221.0961 -1.45
221.1328 C17H17+ 1 221.1325 1.41
222.1279 C16H16N+ 1 222.1277 0.69
223.1117 C16H15O+ 1 223.1117 -0.02
223.1484 C17H19+ 1 223.1481 1.1
224.1433 C16H18N+ 1 224.1434 -0.29
225.1637 C17H21+ 1 225.1638 -0.42
226.1592 C16H20N+ 1 226.159 0.9
228.138 C15H18NO+ 1 228.1383 -1.43
229.1013 C18H13+ 1 229.1012 0.54
230.1093 C18H14+ 1 230.109 1.36
231.1168 C18H15+ 1 231.1168 0.06
232.1247 C18H16+ 1 232.1247 0.14
233.1327 C18H17+ 1 233.1325 1.15
235.1475 C18H19+ 1 235.1481 -2.77
237.1272 C17H17O+ 1 237.1274 -0.93
238.1209 C16H16NO+ 1 238.1226 -7.49
242.1903 C17H24N+ 1 242.1903 -0.06
245.1325 C19H17+ 1 245.1325 0.29
246.1408 C19H18+ 1 246.1403 2.17
247.1116 C18H15O+ 1 247.1117 -0.74
247.1482 C19H19+ 1 247.1481 0.34
248.1436 C18H18N+ 1 248.1434 0.92
262.1595 C19H20N+ 1 262.159 1.78
273.1284 C20H17O+ 1 273.1274 3.66
282.1862 C19H24NO+ 1 282.1852 3.43
294.1858 C20H24NO+ 1 294.1852 1.81
295.1929 C20H25NO+ 1 295.1931 -0.61
296.1643 C19H22NO2+ 1 296.1645 -0.72
310.2159 C21H28NO+ 1 310.2165 -2.09
PK$NUM_PEAK: 240
PK$PEAK: m/z int. rel.int.
50.0152 2850.4 11
51.023 3642.4 15
53.0022 5256.2 22
53.0386 20769.7 86
54.0338 5565.6 23
55.0179 14326 59
55.0542 22106.8 92
56.0495 39307.2 164
65.0385 14033.6 58
67.0415 3565.4 14
67.0542 65008.7 272
68.0495 6217.7 26
69.0335 8747.2 36
69.0698 10113.9 42
70.0287 92468.3 387
70.0651 104608.8 437
72.0443 4555.3 19
77.0385 5544.1 23
79.0542 145693.7 609
80.0495 27305.2 114
81.0335 16660.8 69
81.0699 66617 278
82.0287 3289 13
82.0651 18104.3 75
83.0491 4241.5 17
84.0444 61507.4 257
84.0807 3346.3 14
91.0542 238608.6 999
92.0494 12767.9 53
93.0699 149910.2 627
94.0652 57609.7 241
95.0492 46807.1 195
95.073 5339.8 22
95.0855 42284.6 177
96.0444 28909.7 121
96.0807 9192.2 38
97.0648 7256.9 30
98.06 2925.9 12
103.0543 37897.8 158
104.0621 3388.6 14
105.0699 199567.4 835
106.0652 87439 366
107.0491 15093.2 63
107.0728 10979.2 45
107.0855 54132.2 226
108.0445 7397.3 30
108.0808 35335.9 147
109.0522 3321.3 13
109.0648 19471 81
109.1013 22015.3 92
110.0602 13818.4 57
111.0801 2916.2 12
115.0542 60946.8 255
116.0621 23571.4 98
117.0699 112401.2 470
118.0651 10440.5 43
119.0493 9524.9 39
119.0856 104984.8 439
120.0444 60931.8 255
120.0808 212759.9 890
121.0648 146568.8 613
121.0886 12938.5 54
121.1013 19901.3 83
122.0601 36470.1 152
122.0964 34211.7 143
123.068 16013.9 67
123.0804 8406.7 35
124.0756 11602.1 48
128.0621 77383.4 323
129.0699 93020.2 389
130.0651 14158.9 59
130.0776 17578.7 73
131.0493 8514.8 35
131.0732 9089.6 38
131.0856 120391.4 504
132.0572 3074.3 12
132.0809 17078.6 71
132.0934 2458.7 10
133.0521 4231.7 17
133.0649 21868 91
133.0888 4295.6 17
133.1012 32360.3 135
134.06 15376.2 64
134.0964 39564.7 165
135.0679 7030.5 29
135.0803 19168.9 80
135.1045 2961.9 12
135.1171 3070.2 12
136.0757 13570.4 56
141.0699 53764.1 225
142.0778 56752.3 237
143.0856 95989.8 401
144.0807 15458.7 64
144.0934 9620.1 40
145.0649 19911.3 83
145.0887 8279.2 34
145.1012 64186.9 268
146.0725 4392.1 18
146.0965 17654.4 73
147.0679 3128.1 13
147.0805 53805.5 225
147.1043 4267.8 17
147.117 9250.2 38
148.0757 194660.4 814
149.0836 15237.9 63
149.0957 2799.5 11
150.0915 15359.3 64
152.0621 6209 25
153.0699 30459.2 127
154.0654 2876.8 12
154.0777 27773.5 116
155.0856 74861.8 313
156.0811 6171.5 25
156.0936 24351.5 101
157.0649 8452.8 35
157.0891 5469.6 22
157.1012 70130.1 293
158.0727 6373.2 26
158.0963 14245.6 59
159.0806 19665.5 82
159.105 4613.9 19
159.117 19948.3 83
160.0754 5296 22
160.0882 2894.7 12
160.1119 18562 77
161.0961 13287.4 55
161.1323 5090.5 21
162.0913 16259.3 68
165.0698 38054.1 159
166.0779 19966.7 83
167.0856 43974.1 184
168.0806 4989.8 20
168.0935 16561.6 69
169.065 3007.7 12
169.0887 3440.7 14
169.1012 55806.7 233
170.0963 8045 33
170.1093 5090.4 21
171.0807 14008 58
171.1044 5164.5 21
171.1168 25158.1 105
172.0755 4803.2 20
172.1122 13892.8 58
173.0831 2513.8 10
173.0961 12419.2 51
173.1323 4167.4 17
174.0915 10401.9 43
174.1279 8702.2 36
176.1068 2864.5 11
178.0779 19557.1 81
179.0855 35783.2 149
180.0933 17021.1 71
181.0655 2589.7 10
181.0876 2468.2 10
181.1013 37858.5 158
182.0726 2667.1 11
182.0962 6244.7 26
182.1091 13311.7 55
183.0808 5909.4 24
183.1037 3592.5 15
183.1171 28460.1 119
184.0884 3410 14
184.1118 8039.4 33
185.0959 13423.4 56
185.1328 10098 42
186.0917 2572 10
186.128 4274.5 17
187.1112 5148.2 21
188.1073 4733.6 19
189.0699 4945.3 20
190.0779 6443.8 26
191.0857 18646.6 78
192.0936 18234.1 76
193.1013 29096 121
194.0963 3844.3 16
194.1091 13009 54
195.0806 6632.5 27
195.1166 25095.1 105
196.0881 3109.1 13
196.1123 3573.5 14
196.1249 5280.2 22
197.0962 6392 26
197.1328 12128.6 50
198.1276 5844.4 24
199.1117 5444.8 22
200.1072 4337.7 18
202.078 4950.6 20
202.1231 4307.1 18
203.0856 19520.4 81
204.0932 11081.4 46
205.1012 27002.9 113
206.1087 11455.5 47
207.1066 3597.7 15
207.1167 17340.3 72
208.1115 4675.7 19
208.1248 7124.1 29
209.0959 6435.2 26
209.1321 10249.2 42
210.1036 2647.3 11
210.1279 6416.8 26
210.1393 2623.5 10
211.1118 6213.3 26
211.1481 6100.8 25
215.0856 6325.7 26
216.0936 6514 27
217.1008 20826.9 87
218.1091 10480.7 43
219.1175 16546.7 69
220.1122 3049.5 12
220.1245 8335.2 34
221.0958 3967.1 16
221.1328 7871.7 32
222.1279 3784.9 15
223.1117 4843.8 20
223.1484 4719.6 19
224.1433 3983.4 16
225.1637 6342.7 26
226.1592 4261.9 17
228.138 5333.6 22
229.1013 3342.5 13
230.1093 4712.7 19
231.1168 14021.3 58
232.1247 7728.6 32
233.1327 5493.2 22
235.1475 4045.9 16
237.1272 4529 18
238.1209 3051.2 12
242.1903 2949.9 12
245.1325 9404.9 39
246.1408 2794.9 11
247.1116 2638.9 11
247.1482 3909.1 16
248.1436 4118.2 17
262.1595 3469.6 14
273.1284 2927.6 12
282.1862 2504.1 10
294.1858 4344.5 18
295.1929 17952.2 75
296.1643 3841.4 16
310.2159 10505.9 43
//
