ACCESSION: MSBNK-LCSB-LU025303
RECORD_TITLE: Danazol; LC-ESI-QFT; MS2; CE: 45; R=17500; [M+H]+
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 253
COMMENT: DATASET 20200303_ENTACT_RP_MIX505
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 9882
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 9880
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: Danazol
CH$NAME: (1S,2R,13R,14S,17R,18S)-17-ethynyl-2,18-dimethyl-7-oxa-6-azapentacyclo[11.7.0.02,10.04,8.014,18]icosa-4(8),5,9-trien-17-ol
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C22H27NO2
CH$EXACT_MASS: 337.2042
CH$SMILES: C[C@]12CC[C@H]3[C@@H](CCC4=CC5=C(C[C@]34C)C=NO5)[C@@H]1CC[C@@]2(O)C#C
CH$IUPAC: InChI=1S/C22H27NO2/c1-4-22(24)10-8-18-16-6-5-15-11-19-14(13-23-25-19)12-20(15,2)17(16)7-9-21(18,22)3/h1,11,13,16-18,24H,5-10,12H2,2-3H3/t16-,17+,18+,20+,21+,22+/m1/s1
CH$LINK: CAS
17230-88-5
CH$LINK: CHEBI
4315
CH$LINK: KEGG
C06938
CH$LINK: PUBCHEM
CID:28417
CH$LINK: INCHIKEY
POZRVZJJTULAOH-LHZXLZLDSA-N
CH$LINK: CHEMSPIDER
26436
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 45
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 18.811 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 79.0211
MS$FOCUSED_ION: PRECURSOR_M/Z 338.2115
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_INTENSITY 4449361.4375
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-00dj-2920000000-daa2e9a98f0ce3e604ca
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
53.0023 C3HO+ 1 53.0022 2.27
53.0386 C4H5+ 1 53.0386 0.82
55.0179 C3H3O+ 1 55.0178 0.89
55.0542 C4H7+ 1 55.0542 -0.03
56.0495 C3H6N+ 1 56.0495 0.24
65.0385 C5H5+ 1 65.0386 -1.59
67.0542 C5H7+ 1 67.0542 0.04
68.0495 C4H6N+ 1 68.0495 0.7
69.0333 C4H5O+ 1 69.0335 -2.37
69.0698 C5H9+ 1 69.0699 -0.73
70.0287 C3H4NO+ 1 70.0287 -0.05
70.0651 C4H8N+ 1 70.0651 -0.39
72.0444 C3H6NO+ 1 72.0444 -0.11
79.0542 C6H7+ 1 79.0542 0.01
80.0496 C5H6N+ 1 80.0495 0.98
81.0335 C5H5O+ 1 81.0335 -0.24
81.0699 C6H9+ 1 81.0699 0.5
82.0285 C4H4NO+ 1 82.0287 -2.55
82.0652 C5H8N+ 1 82.0651 0.42
83.049 C5H7O+ 1 83.0491 -1.67
84.0444 C4H6NO+ 1 84.0444 0.62
91.0543 C7H7+ 1 91.0542 0.33
93.07 C7H9+ 1 93.0699 1.02
94.0652 C6H8N+ 1 94.0651 0.9
95.0493 C6H7O+ 1 95.0491 1.15
95.0856 C7H11+ 1 95.0855 0.25
96.0444 C5H6NO+ 1 96.0444 0.32
96.0808 C6H10N+ 1 96.0808 0.39
97.0648 C6H9O+ 1 97.0648 0.47
98.0601 C5H8NO+ 1 98.06 0.76
103.0542 C8H7+ 1 103.0542 -0.04
105.0699 C8H9+ 1 105.0699 0.69
106.0652 C7H8N+ 1 106.0651 0.32
107.0492 C7H7O+ 1 107.0491 0.34
107.0728 C7H9N+ 1 107.073 -1.21
107.0856 C8H11+ 1 107.0855 0.26
108.0443 C6H6NO+ 1 108.0444 -0.94
108.0808 C7H10N+ 1 108.0808 0.39
109.0524 C6H7NO+ 1 109.0522 2.11
109.0649 C7H9O+ 1 109.0648 0.9
109.1013 C8H13+ 1 109.1012 0.96
110.0601 C6H8NO+ 1 110.06 0.19
111.0804 C7H11O+ 1 111.0804 -0.15
112.0757 C6H10NO+ 1 112.0757 -0.01
115.0543 C9H7+ 1 115.0542 0.57
116.0621 C9H8+ 1 116.0621 0.14
117.0699 C9H9+ 1 117.0699 0.11
118.0653 C8H8N+ 1 118.0651 1.78
119.0856 C9H11+ 1 119.0855 0.63
120.0444 C7H6NO+ 1 120.0444 0.49
120.0809 C8H10N+ 1 120.0808 0.68
121.0648 C8H9O+ 1 121.0648 0.31
121.0888 C8H11N+ 1 121.0886 1.46
121.1012 C9H13+ 1 121.1012 0.31
122.0601 C7H8NO+ 1 122.06 0.49
122.0964 C8H12N+ 1 122.0964 0.05
123.068 C7H9NO+ 1 123.0679 0.83
123.0804 C8H11O+ 1 123.0804 -0.12
124.0758 C7H10NO+ 1 124.0757 0.98
128.062 C10H8+ 1 128.0621 -0.18
129.0699 C10H9+ 1 129.0699 -0.04
130.0653 C9H8N+ 1 130.0651 1.65
130.0778 C10H10+ 1 130.0777 0.8
131.0491 C9H7O+ 1 131.0491 -0.39
131.0856 C10H11+ 1 131.0855 0.94
132.0809 C9H10N+ 1 132.0808 0.86
133.0648 C9H9O+ 1 133.0648 -0.23
133.0889 C9H11N+ 1 133.0886 2.25
133.1012 C10H13+ 1 133.1012 0.17
134.0601 C8H8NO+ 1 134.06 0.27
134.0963 C9H12N+ 1 134.0964 -0.7
135.0681 C8H9NO+ 1 135.0679 1.42
135.0804 C9H11O+ 1 135.0804 0.05
135.1168 C10H15+ 1 135.1168 -0.02
136.0759 C8H10NO+ 1 136.0757 1.88
141.07 C11H9+ 1 141.0699 1.06
142.0777 C11H10+ 1 142.0777 0.21
143.0856 C11H11+ 1 143.0855 0.66
144.0809 C10H10N+ 1 144.0808 0.58
144.0935 C11H12+ 1 144.0934 0.78
145.0648 C10H9O+ 1 145.0648 -0.1
145.0888 C10H11N+ 1 145.0886 1.65
145.1012 C11H13+ 1 145.1012 0.47
146.0729 C10H10O+ 1 146.0726 2.22
146.0964 C10H12N+ 1 146.0964 -0.22
147.0805 C10H11O+ 1 147.0804 0.66
147.1169 C11H15+ 1 147.1168 0.19
148.0757 C9H10NO+ 1 148.0757 0.18
149.0835 C9H11NO+ 1 149.0835 0.2
149.0963 C10H13O+ 1 149.0961 1.1
150.0914 C9H12NO+ 1 150.0913 0.42
153.0701 C12H9+ 1 153.0699 1.57
154.0779 C12H10+ 1 154.0777 0.99
155.0855 C12H11+ 1 155.0855 0.02
156.0809 C11H10N+ 1 156.0808 0.93
156.0934 C12H12+ 1 156.0934 0.04
157.0646 C11H9O+ 1 157.0648 -1.15
157.1013 C12H13+ 1 157.1012 0.54
158.0965 C11H12N+ 1 158.0964 0.77
159.0804 C11H11O+ 1 159.0804 -0.05
159.1048 C11H13N+ 1 159.1043 3.75
159.1168 C12H15+ 1 159.1168 -0.1
160.076 C10H10NO+ 1 160.0757 2.09
160.0888 C11H12O+ 1 160.0883 3.31
160.1121 C11H14N+ 1 160.1121 0.41
161.0959 C11H13O+ 1 161.0961 -1.33
161.1326 C12H17+ 1 161.1325 0.79
162.0914 C10H12NO+ 1 162.0913 0.12
165.0698 C13H9+ 1 165.0699 -0.56
166.0774 C13H10+ 1 166.0777 -2
167.0856 C13H11+ 1 167.0855 0.49
168.0934 C13H12+ 1 168.0934 0.14
169.1013 C13H13+ 1 169.1012 0.7
170.0965 C12H12N+ 1 170.0964 0.46
170.1087 C13H14+ 1 170.109 -1.62
171.0805 C12H11O+ 1 171.0804 0.07
171.1168 C13H15+ 1 171.1168 -0.25
172.076 C11H10NO+ 1 172.0757 1.78
172.1121 C12H14N+ 1 172.1121 0.14
173.0837 C11H11NO+ 1 173.0835 0.91
173.0961 C12H13O+ 1 173.0961 0.1
173.1201 C12H15N+ 1 173.1199 1.3
173.1325 C13H17+ 1 173.1325 0.23
174.0917 C11H12NO+ 1 174.0913 1.89
174.1279 C12H16N+ 1 174.1277 0.96
175.1119 C12H15O+ 1 175.1117 0.74
176.1068 C11H14NO+ 1 176.107 -0.96
178.0779 C14H10+ 1 178.0777 0.89
179.0856 C14H11+ 1 179.0855 0.23
180.0932 C14H12+ 1 180.0934 -0.6
181.0646 C13H9O+ 1 181.0648 -0.87
181.1011 C14H13+ 1 181.1012 -0.25
182.0962 C13H12N+ 1 182.0964 -1.3
182.109 C14H14+ 1 182.109 0.11
183.0804 C13H11O+ 1 183.0804 0.01
183.1043 C13H13N+ 1 183.1043 0.14
183.1069 C13H13N+ 1 183.1043 14.23
183.1169 C14H15+ 1 183.1168 0.13
184.0883 C13H12O+ 1 184.0883 0.19
184.1119 C13H14N+ 1 184.1121 -0.91
185.0963 C13H13O+ 1 185.0961 1.04
185.1325 C14H17+ 1 185.1325 0.33
186.0914 C12H12NO+ 1 186.0913 0.49
186.1278 C13H16N+ 1 186.1277 0.2
187.1117 C13H15O+ 1 187.1117 0.01
187.1485 C14H19+ 1 187.1481 1.84
188.1072 C12H14NO+ 1 188.107 1.02
191.0856 C15H11+ 1 191.0855 0.2
192.0936 C15H12+ 1 192.0934 1.33
193.1012 C15H13+ 1 193.1012 0.32
194.0965 C14H12N+ 1 194.0964 0.21
194.109 C15H14+ 1 194.109 -0.04
195.0807 C14H11O+ 1 195.0804 1.51
195.1169 C15H15+ 1 195.1168 0.45
196.0882 C14H12O+ 1 196.0883 -0.34
196.1121 C14H14N+ 1 196.1121 0.33
196.1247 C15H16+ 1 196.1247 0.47
197.0959 C14H13O+ 1 197.0961 -0.85
197.1325 C15H17+ 1 197.1325 -0.12
198.1275 C14H16N+ 1 198.1277 -0.93
199.1117 C14H15O+ 1 199.1117 -0.1
199.1484 C15H19+ 1 199.1481 1.16
200.1071 C13H14NO+ 1 200.107 0.77
200.1438 C14H18N+ 1 200.1434 2.18
201.1276 C14H17O+ 1 201.1274 1.09
202.1229 C13H16NO+ 1 202.1226 1.5
203.0857 C16H11+ 1 203.0855 1
204.0933 C16H12+ 1 204.0934 -0.4
205.1013 C16H13+ 1 205.1012 0.74
206.1093 C16H14+ 1 206.109 1.36
207.117 C16H15+ 1 207.1168 1.01
208.1134 C15H14N+ 1 208.1121 6.17
208.1249 C16H16+ 1 208.1247 1.18
209.0962 C15H13O+ 1 209.0961 0.65
209.1324 C16H17+ 1 209.1325 -0.48
210.1037 C15H14O+ 1 210.1039 -1.21
210.1279 C15H16N+ 1 210.1277 0.87
210.1402 C16H18+ 1 210.1403 -0.31
211.1123 C15H15O+ 1 211.1117 2.43
211.1487 C16H19+ 1 211.1481 2.83
212.1074 C14H14NO+ 1 212.107 2.03
212.1432 C15H18N+ 1 212.1434 -0.96
213.1276 C15H17O+ 1 213.1274 0.88
214.1226 C14H16NO+ 1 214.1226 -0.01
216.0933 C17H12+ 1 216.0934 -0.16
217.1013 C17H13+ 1 217.1012 0.64
218.1091 C17H14+ 1 218.109 0.52
219.1166 C17H15+ 1 219.1168 -1.13
220.1249 C17H16+ 1 220.1247 0.91
221.1322 C17H17+ 1 221.1325 -1.07
222.1281 C16H16N+ 1 222.1277 1.58
223.1121 C16H15O+ 1 223.1117 1.69
223.148 C17H19+ 1 223.1481 -0.67
224.1432 C16H18N+ 1 224.1434 -0.91
225.127 C16H17O+ 1 225.1274 -1.53
225.1637 C17H21+ 1 225.1638 -0.28
226.159 C16H20N+ 1 226.159 -0.31
227.1431 C16H19O+ 1 227.143 0.41
228.1386 C15H18NO+ 1 228.1383 1.38
229.1013 C18H13+ 1 229.1012 0.54
230.1088 C18H14+ 1 230.109 -0.7
231.1167 C18H15+ 1 231.1168 -0.34
232.1246 C18H16+ 1 232.1247 -0.12
233.0956 C17H13O+ 1 233.0961 -2.02
233.1329 C18H17+ 1 233.1325 1.74
234.1274 C17H16N+ 1 234.1277 -1.23
234.1403 C18H18+ 1 234.1403 -0.01
235.1119 C17H15O+ 1 235.1117 0.77
235.1481 C18H19+ 1 235.1481 -0.05
237.1273 C17H17O+ 1 237.1274 -0.22
237.1637 C18H21+ 1 237.1638 -0.19
238.1227 C16H16NO+ 1 238.1226 0.2
239.1437 C17H19O+ 1 239.143 2.89
241.1584 C17H21O+ 1 241.1587 -1.27
242.1903 C17H24N+ 1 242.1903 -0.13
243.1178 C19H15+ 1 243.1168 3.95
245.1325 C19H17+ 1 245.1325 0.17
246.1409 C19H18+ 1 246.1403 2.24
247.1118 C18H15O+ 1 247.1117 0.06
247.148 C19H19+ 1 247.1481 -0.47
248.1437 C18H18N+ 1 248.1434 1.29
249.1278 C18H17O+ 1 249.1274 1.7
249.164 C19H21+ 1 249.1638 1.05
250.159 C18H20N+ 1 250.159 0.04
251.1429 C18H19O+ 1 251.143 -0.7
253.159 C18H21O+ 1 253.1587 1.27
257.1336 C20H17+ 1 257.1325 4.5
259.1487 C20H19+ 1 259.1481 2.26
260.1565 C20H20+ 1 260.156 1.98
261.1275 C19H17O+ 1 261.1274 0.57
261.1641 C20H21+ 1 261.1638 1.35
262.1591 C19H20N+ 1 262.159 0.27
263.1435 C19H19O+ 1 263.143 1.76
263.1808 C20H23+ 1 263.1794 5.21
264.1751 C19H22N+ 1 264.1747 1.69
265.1587 C19H21O+ 1 265.1587 0.06
268.1695 C18H22NO+ 1 268.1696 -0.39
270.185 C18H24NO+ 1 270.1852 -1.02
273.1269 C20H17O+ 1 273.1274 -1.93
275.1797 C21H23+ 1 275.1794 0.97
281.1909 C20H25O+ 1 281.19 3.36
282.1854 C19H24NO+ 1 282.1852 0.62
283.1688 C19H23O2+ 1 283.1693 -1.55
292.1697 C20H22NO+ 1 292.1696 0.44
292.2062 C21H26N+ 1 292.206 0.82
293.1901 C21H25O+ 1 293.19 0.39
294.1854 C20H24NO+ 1 294.1852 0.67
295.1698 C20H23O2+ 1 295.1693 1.79
295.1933 C20H25NO+ 1 295.1931 0.74
296.1648 C19H22NO2+ 1 296.1645 0.83
296.2012 C20H26NO+ 1 296.2009 1.11
303.1747 C22H23O+ 1 303.1743 1.12
309.1847 C21H25O2+ 1 309.1849 -0.56
310.2167 C21H28NO+ 1 310.2165 0.37
320.2011 C22H26NO+ 1 320.2009 0.68
321.1852 C22H25O2+ 1 321.1849 0.95
338.2117 C22H28NO2+ 1 338.2115 0.72
PK$NUM_PEAK: 257
PK$PEAK: m/z int. rel.int.
53.0023 2832.2 9
53.0386 6285.5 20
55.0179 9799.2 32
55.0542 13362.1 44
56.0495 49867.2 164
65.0385 5421.2 17
67.0542 33982.5 111
68.0495 5073.9 16
69.0333 8839.3 29
69.0698 12982.9 42
70.0287 106563 351
70.0651 123174 405
72.0444 4459.6 14
79.0542 67587.9 222
80.0496 13348 43
81.0335 12124.5 39
81.0699 62666.9 206
82.0285 3190.8 10
82.0652 18516.9 60
83.049 5458.2 17
84.0444 96175.6 316
91.0543 104633.1 344
93.07 90346.6 297
94.0652 42492.8 139
95.0493 17697.5 58
95.0856 40757 134
96.0444 33991.2 111
96.0808 8272 27
97.0648 10231 33
98.0601 4805.8 15
103.0542 11554.7 38
105.0699 129565.2 426
106.0652 37793.2 124
107.0492 12318.3 40
107.0728 5442 17
107.0856 54138.4 178
108.0443 7431.4 24
108.0808 40442.5 133
109.0524 3382.2 11
109.0649 20251.6 66
109.1013 26326.5 86
110.0601 25482.4 83
111.0804 4347.3 14
112.0757 2933.8 9
115.0543 23730.3 78
116.0621 7994.1 26
117.0699 80086.2 263
118.0653 3799 12
119.0856 92449.3 304
120.0444 66468.7 218
120.0809 193786.6 638
121.0648 127973.5 421
121.0888 11131.8 36
121.1012 22471.1 74
122.0601 38290.5 126
122.0964 29234.1 96
123.068 19384.5 63
123.0804 9596.7 31
124.0758 16855.4 55
128.062 22218 73
129.0699 62843.3 207
130.0653 5375.5 17
130.0778 8513.4 28
131.0491 6597.2 21
131.0856 119238.4 392
132.0809 10349.9 34
133.0648 18201.4 59
133.0889 5321.1 17
133.1012 46538.1 153
134.0601 15920 52
134.0963 29977.4 98
135.0681 3853.4 12
135.0804 24808.6 81
135.1168 9561.4 31
136.0759 16541.1 54
141.07 31528 103
142.0777 22956.5 75
143.0856 94322.5 310
144.0809 9724.4 32
144.0935 5443.9 17
145.0648 14976.8 49
145.0888 3690.7 12
145.1012 68106.3 224
146.0729 2988.1 9
146.0964 20824.3 68
147.0805 53458.3 176
147.1169 17264.9 56
148.0757 303274.5 999
149.0835 10912.1 35
149.0963 8207.6 27
150.0914 31647.3 104
153.0701 10078.5 33
154.0779 14886.8 49
155.0855 62929.3 207
156.0809 4598.7 15
156.0934 14398.6 47
157.0646 7053.6 23
157.1013 94116.7 310
158.0965 15170.8 49
159.0804 25624.9 84
159.1048 4325.2 14
159.1168 34685.9 114
160.076 7145.6 23
160.0888 3336.8 10
160.1121 19334.5 63
161.0959 22524.2 74
161.1326 9736.2 32
162.0914 23615.4 77
165.0698 15766.6 51
166.0774 10413.1 34
167.0856 38594 127
168.0934 10853.3 35
169.1013 65482.6 215
170.0965 6682.9 22
170.1087 5833.8 19
171.0805 17746 58
171.1168 54222.1 178
172.076 2700.8 8
172.1121 13234.3 43
173.0837 3278.3 10
173.0961 26796 88
173.1201 4760.6 15
173.1325 8118.1 26
174.0917 16453.2 54
174.1279 18015.4 59
175.1119 8049.8 26
176.1068 8400 27
178.0779 7830.7 25
179.0856 18613.6 61
180.0932 11066.3 36
181.0646 3431.5 11
181.1011 45728 150
182.0962 2635 8
182.109 11055 36
183.0804 9960.9 32
183.1043 3422.4 11
183.1069 3927.2 12
183.1169 46282.9 152
184.0883 3932.5 12
184.1119 11907.8 39
185.0963 29441 96
185.1325 25576.5 84
186.0914 6742.6 22
186.1278 6982.7 23
187.1117 12110.2 39
187.1485 5574.3 18
188.1072 9080 29
191.0856 6845.2 22
192.0936 10718.3 35
193.1012 36496.6 120
194.0965 3172.9 10
194.109 7649.4 25
195.0807 5669.8 18
195.1169 38939 128
196.0882 2897.9 9
196.1121 6180.1 20
196.1247 8891.7 29
197.0959 10899 35
197.1325 20844.9 68
198.1275 7466.3 24
199.1117 11208.6 36
199.1484 6341.1 20
200.1071 9635.2 31
200.1438 4049.6 13
201.1276 3303.7 10
202.1229 7250.6 23
203.0857 7383.8 24
204.0933 14842.6 48
205.1013 23796.4 78
206.1093 12084.3 39
207.117 28241.2 93
208.1134 3487.1 11
208.1249 6457.1 21
209.0962 6656.5 21
209.1324 25281.1 83
210.1037 3130.8 10
210.1279 6272 20
210.1402 5122.5 16
211.1123 11867.8 39
211.1487 12863.8 42
212.1074 2928 9
212.1432 5714.4 18
213.1276 7796.4 25
214.1226 5380.7 17
216.0933 3554.4 11
217.1013 16883.3 55
218.1091 10662.5 35
219.1166 27825.5 91
220.1249 9788.3 32
221.1322 18543.1 61
222.1281 4910.6 16
223.1121 7240.7 23
223.148 16911.6 55
224.1432 2937.5 9
225.127 11704.3 38
225.1637 23921.4 78
226.159 4178.6 13
227.1431 7474.5 24
228.1386 8577.6 28
229.1013 2917.6 9
230.1088 3522.9 11
231.1167 14955.1 49
232.1246 8977.5 29
233.0956 2861.5 9
233.1329 17021.3 56
234.1274 3814.8 12
234.1403 4032.4 13
235.1119 6230.6 20
235.1481 17101 56
237.1273 7070.4 23
237.1637 3789.2 12
238.1227 2717.9 8
239.1437 4809.1 15
241.1584 2655.4 8
242.1903 15160.7 49
243.1178 3565 11
245.1325 13545 44
246.1409 10677 35
247.1118 3452.8 11
247.148 8536 28
248.1437 4126.4 13
249.1278 5112.3 16
249.164 5236.1 17
250.159 2647.5 8
251.1429 8779.1 28
253.159 12611.3 41
257.1336 2582.1 8
259.1487 4917.9 16
260.1565 10709.4 35
261.1275 3530.1 11
261.1641 5549.2 18
262.1591 3579.9 11
263.1435 6038.7 19
263.1808 3189 10
264.1751 5620.9 18
265.1587 5383.5 17
268.1695 3953.5 13
270.185 12734.7 41
273.1269 3484.3 11
275.1797 6049.4 19
281.1909 2881.3 9
282.1854 6215.4 20
283.1688 10926.2 35
292.1697 4761.9 15
292.2062 13963 45
293.1901 6285.1 20
294.1854 6973.2 22
295.1698 7860.3 25
295.1933 22014 72
296.1648 15308.6 50
296.2012 17961.6 59
303.1747 2873.6 9
309.1847 2955.7 9
310.2167 90215.4 297
320.2011 6245.4 20
321.1852 5787.1 19
338.2117 126130.9 415
//
