ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP012098
RECORD_TITLE: 6-METHYL-5-TRIMETHYLSILYLMETHYL-6-HEPTEN-2-ONE; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: HISAHIRO HAGIWARA, INSTITUTE FOR CHEMICAL REACTION SCIENCE TOHOKU UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: 6-METHYL-5-TRIMETHYLSILYLMETHYL-6-HEPTEN-2-ONE
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₂H₂₄OSi
CH$EXACT_MASS: 212.15964
CH$SMILES: CC(=O)CCC(C(C)=C)C[Si](C)(C)C
CH$IUPAC: InChI=1S/C12H24OSi/c1-10(2)12(8-7-11(3)13)9-14(4,5)6/h12H,1,7-9H2,2-6H3
CH$LINK: INCHIKEY AJNMYAQSXRODBL-UHFFFAOYSA-N

AC$INSTRUMENT: JEOL JMS-DX-300
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-00di-9500000000-2afa9eabf6f50ef8f1bb
PK$NUM_PEAK: 41
PK$PEAK: m/z int. rel.int.
  39 2.2 22
  41 3.3 33
  43 16.1 161
  44 2.9 29
  45 10.3 103
  53 2.2 22
  55 2.1 21
  58 2.6 26
  59 8.4 84
  67 2.4 24
  72 2.6 26
  73 99.99 999
  74 10.8 108
  75 41.6 416
  76 3.3 33
  77 2.7 27
  85 3.1 31
  93 2.2 22
  99 2.8 28
  107 15.1 151
  111 3.4 34
  112 2.6 26
  115 11.7 117
  121 3 30
  122 17.7 177
  123 2.7 27
  127 2.6 26
  129 5.4 54
  130 9.3 93
  139 2.5 25
  141 14.5 145
  142 2.5 25
  143 4.4 44
  144 4.3 43
  154 9.8 98
  155 2.2 22
  169 3.6 36
  183 1.8 18
  194 1.6 16
  197 5.1 51
  212 0.6 6
//