ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP010697
RECORD_TITLE: (-)-2,6,6-TRIMETHYL-2(R)-VINYL-5(R)-ACETOXYTETRAHYDROPYRAN; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: EGUCHI S, FAC. OF SCIENCE, HIROSHIMA UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: (-)-2,6,6-TRIMETHYL-2(R)-VINYL-5(R)-ACETOXYTETRAHYDROPYRAN
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₁₂H₂₀O₃
CH$EXACT_MASS: 212.14124
CH$SMILES: C=CC(C)(C1)OC(C)(C)C([H])(OC(C)=O)C1
CH$IUPAC: InChI=1S/C12H20O3/c1-6-12(5)8-7-10(14-9(2)13)11(3,4)15-12/h6,10H,1,7-8H2,2-5H3/t10-,12+/m1/s1
CH$LINK: INCHIKEY IRWLDXUJBJPFNV-PWSUYJOCSA-N

AC$INSTRUMENT: HITACHI RMU-6L
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-0006-9200000000-e7e749a1f8bdb6b67e2d
PK$NUM_PEAK: 63
PK$PEAK: m/z int. rel.int.
  41 14 140
  42 2.5 25
  43 99.99 999
  44 0.45 5
  45 2.5 25
  53 5 50
  54 2 20
  55 1.35 14
  56 1.5 15
  57 2.5 25
  59 20 200
  60 0.2 2
  65 2 20
  67 8.5 85
  68 31 310
  69 0.55 6
  70 2.5 25
  71 6.5 65
  72 11 110
  75 0.2 2
  77 3.5 35
  78 1.5 15
  79 11 110
  80 0.2 2
  81 8 80
  82 4.5 45
  83 5 50
  84 0.25 3
  85 3.5 35
  86 2 20
  91 2 20
  93 1.4 14
  94 51 510
  95 8 80
  96 2.5 25
  97 0.4 4
  98 2 20
  99 2.5 25
  100 2.5 25
  101 1 10
  102 2 20
  107 2.5 25
  108 2 20
  109 0.2 2
  111 4.5 45
  112 2 20
  113 2 20
  114 0.3 3
  119 3 30
  121 2 20
  125 5.5 55
  126 0.3 3
  136 14 140
  137 11.5 115
  138 2.5 25
  143 0.45 5
  154 9 90
  155 7 70
  156 2.5 25
  170 0.1 1
  197 6.5 65
  198 2 20
  212 0.3 3
//