ACCESSION: MSBNK-Fac_Eng_Univ_Tokyo-JP002701
RECORD_TITLE: LANOSTEROL-TRIMETHYLSILYL-ETHER; EI-B; MS
DATE: 2016.01.19 (Created 2008.10.21, modified 2011.05.06)
AUTHORS: HAYASHI A, DEPT. OF CHEMISTRY, FAC. OF SCI. AND TECHNOLOGY, KINKI UNIV.
LICENSE: CC BY-NC-SA

CH$NAME: LANOSTEROL-TRIMETHYLSILYL-ETHER
CH$COMPOUND_CLASS: N/A
CH$FORMULA: C₃₃H₅₈OSi
CH$EXACT_MASS: 498.42569
CH$SMILES: [H]C(C41C)(CCC(=C43)C(C2(C)CC3)(CCC2([H])C([H])(C)CCC=C(C)C)C)C(C(O[Si](C)(C)C)CC1)(C)C
CH$IUPAC: InChI=1S/C33H58OSi/c1-23(2)13-12-14-24(3)25-17-21-33(8)27-15-16-28-30(4,5)29(34-35(9,10)11)19-20-31(28,6)26(27)18-22-32(25,33)7/h13,24-25,28-29H,12,14-22H2,1-11H3/t24-,25+,28-,29-,31+,32+,33-/m0/s1
CH$LINK: CAS 55493-84-0
CH$LINK: INCHIKEY VUPPLGLOGXZZKA-ZXEXGRMMSA-N

AC$INSTRUMENT: SHIMADZU LKB-9000B
AC$INSTRUMENT_TYPE: EI-B
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION_ENERGY 70 eV

MS$FOCUSED_ION: ION_TYPE [M]+*

PK$SPLASH: splash10-0006-3946200000-1293091e58db84429012
PK$NUM_PEAK: 190
PK$PEAK: m/z int. rel.int.
  55 2.8 28
  67 2.4 24
  69 17.2 172
  70 0.13 1
  73 11.2 112
  74 1 10
  75 8.5 85
  76 0.1 1
  77 1 10
  79 1.8 18
  81 7.7 77
  82 0.12 1
  83 4.6 46
  91 3.4 34
  93 6.2 62
  94 0.13 1
  95 13.3 133
  96 1.6 16
  97 2.6 26
  105 0.59 6
  106 1 10
  107 8.6 86
  108 2.1 21
  109 2.5 25
  110 2.6 26
  111 3.8 38
  117 4.6 46
  118 0.13 1
  119 11 110
  120 2.2 22
  121 11.7 117
  122 0.28 3
  123 11.5 115
  124 1.4 14
  128 1.1 11
  129 1.07 11
  130 2.2 22
  131 6.7 67
  132 1.9 19
  133 0.79 8
  134 2.7 27
  135 14.9 149
  136 3.3 33
  137 0.67 7
  141 1.4 14
  142 1.1 11
  143 4.7 47
  144 0.27 3
  145 8.7 87
  146 2.5 25
  147 9.8 98
  148 0.24 2
  149 8.9 89
  151 2.5 25
  155 1.7 17
  156 0.1 1
  157 7.4 74
  158 3.2 32
  159 8.4 84
  160 0.39 4
  161 10.8 108
  162 2.5 25
  163 7.4 74
  164 0.15 2
  165 1.5 15
  169 2.5 25
  170 1.3 13
  171 0.62 6
  172 2.7 27
  173 9.2 92
  174 3.2 32
  175 0.94 9
  176 1.9 19
  177 3.4 34
  178 1 10
  183 0.35 4
  184 1.3 13
  185 5.4 54
  186 2.2 22
  187 1.3 13
  188 3.4 34
  189 12.9 129
  190 3.7 37
  191 0.45 5
  192 1.2 12
  197 2.9 29
  198 2.1 21
  199 0.42 4
  200 1.9 19
  201 8.1 81
  202 2.3 23
  203 0.71 7
  204 2.2 22
  205 3.1 31
  206 1 10
  209 0.1 1
  210 1.1 11
  211 3.4 34
  212 1.7 17
  213 0.6 6
  214 5.2 52
  215 12.1 121
  216 2.4 24
  217 0.28 3
  223 1.1 11
  225 4.2 42
  226 1.5 15
  227 1.33 13
  228 3.7 37
  229 9.7 97
  230 2.3 23
  231 0.28 3
  237 1 10
  239 2.6 26
  240 2.7 27
  241 1.42 14
  242 3.2 32
  243 5.5 55
  244 1.9 19
  245 0.18 2
  253 3.7 37
  254 1 10
  255 8.6 86
  256 0.28 3
  257 4 40
  258 1.1 11
  259 1.4 14
  267 0.14 1
  269 2.7 27
  270 2.1 21
  271 3.2 32
  272 0.19 2
  273 1.8 18
  281 2.3 23
  282 1.5 15
  283 0.41 4
  284 1.4 14
  285 1.9 19
  295 2.3 23
  296 0.11 1
  297 2.7 27
  298 1 10
  299 1.5 15
  309 0.28 3
  310 1.2 12
  311 5.4 54
  312 1.9 19
  313 0.11 1
  315 3.1 31
  319 1.1 11
  323 2.6 26
  324 0.15 2
  325 1.6 16
  331 1.2 12
  337 2.6 26
  338 0.1 1
  339 1.8 18
  345 1.4 14
  350 1.6 16
  351 0.19 2
  365 1.2 12
  367 1.4 14
  369 1.2 12
  377 0.13 1
  378 1.6 16
  383 1.5 15
  391 4.6 46
  393 99.99 999
  394 31.3 313
  395 5.6 56
  396 1.3 13
  405 0.1 1
  406 1.7 17
  407 1.9 19
  408 1.7 17
  413 0.21 2
  451 1 10
  467 1.1 11
  468 1.5 15
  469 0.18 2
  470 1.7 17
  471 1 10
  482 0.14 1
  483 21.3 213
  484 9.5 95
  485 2.8 28
  486 0.28 3
  497 2.1 21
  498 14.2 142
  499 6.1 61
//