ACCESSION: MSBNK-Eawag-EQ366406
RECORD_TITLE: Danofloxacin; LC-ESI-QFT; MS2; CE: 90; R=35000; [M+H]+
DATE: 2015.08.25
AUTHORS: Stravs M, Schymanski E, Singer H, Department of Environmental Chemistry, Eawag and Thomaidis N, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2015 Eawag, Duebendorf, Switzerland
COMMENT: CONFIDENCE standard compound
COMMENT: EAWAG_UCHEM_ID 3664
CH$NAME: Danofloxacin
CH$NAME: 1-cyclopropyl-6-fluoro-7-(5-methyl-2-aza-5-azoniabicyclo[2.2.1]heptan-2-yl)-4-oxoquinoline-3-carboxylate
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C19H20FN3O3
CH$EXACT_MASS: 357.14887
CH$SMILES: CN1C[C@@H]2C[C@H]1CN2C3=C(C=C4C(=C3)N(C=C(C4=O)C(=O)O)C5CC5)F
CH$IUPAC: InChI=1S/C19H20FN3O3/c1-21-7-12-4-11(21)8-22(12)17-6-16-13(5-15(17)20)18(24)14(19(25)26)9-23(16)10-2-3-10/h5-6,9-12H,2-4,7-8H2,1H3,(H,25,26)/t11-,12-/m0/s1
CH$LINK: CAS
112398-08-0
CH$LINK: PUBCHEM
CID:71335
CH$LINK: INCHIKEY
QMLVECGLEOSESV-RYUDHWBXSA-N
CH$LINK: CHEMSPIDER
64439
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 90 (nominal)
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME XBridge C18 3.5um, 2.1x50mm, Waters
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0 min, 50/50 at 4 min, 5/95 at 17 min, 5/95 at 25 min, 90/10 at 25.1 min, 90/10 at 30 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 ul/min
AC$CHROMATOGRAPHY: RETENTION_TIME 4.4 min
AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 164.9843
MS$FOCUSED_ION: PRECURSOR_M/Z 358.1561
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 1.9.6
PK$SPLASH: splash10-001i-9540000000-f54438c275c5c867006a
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
53.0022 C3HO+ 1 53.0022 0.92
53.0386 C4H5+ 1 53.0386 0.63
54.0339 C3H4N+ 1 54.0338 0.64
55.0417 C3H5N+ 1 55.0417 0.17
55.0543 C4H7+ 1 55.0542 0.79
56.0495 C3H6N+ 1 56.0495 0.97
57.0573 C3H7N+ 1 57.0573 -0.19
58.0651 C3H8N+ 1 58.0651 -0.27
60.0245 C2H3FN+ 1 60.0244 1.1
65.0386 C5H5+ 2 65.0386 0.67
66.0464 C5H6+ 2 66.0464 0.13
67.0417 C4H5N+ 1 67.0417 0.44
67.0543 C5H7+ 2 67.0542 0.5
68.0495 C4H6N+ 1 68.0495 0.21
69.0573 C4H7N+ 1 69.0573 0.57
69.0698 C5H9+ 2 69.0699 -1.11
70.0652 C4H8N+ 1 70.0651 0.35
74.0964 C4H12N+ 1 74.0964 0.19
75.0479 C3H6FN+ 1 75.0479 0.82
79.0417 C5H5N+ 1 79.0417 -0.01
79.0543 C6H7+ 2 79.0542 0.55
80.0495 C5H6N+ 1 80.0495 0.18
81.0574 C5H7N+ 1 81.0573 0.73
82.0651 C5H8N+ 1 82.0651 0.17
83.0729 C5H9N+ 1 83.073 -0.13
84.0808 C5H10N+ 1 84.0808 0.41
93.0573 C6H7N+ 1 93.0573 0.21
94.0652 C6H8N+ 1 94.0651 0.79
95.0492 C6H7O+ 2 95.0491 0.83
95.0606 C5H7N2+ 1 95.0604 2.9
96.0445 C5H6NO+ 1 96.0444 0.73
96.0808 C6H10N+ 1 96.0808 0.25
97.0761 C5H9N2+ 1 97.076 0.36
105.0449 C6H5N2+ 1 105.0447 1.57
107.0293 C7H4F+ 1 107.0292 0.98
109.0449 C7H6F+ 1 109.0448 1.15
115.0417 C8H5N+ 1 115.0417 0.78
115.0542 C9H7+ 2 115.0542 -0.14
116.0495 C8H6N+ 1 116.0495 0.21
117.0574 C8H7N+ 1 117.0573 0.59
122.0401 C7H5FN+ 1 122.0401 0.3
126.0466 C10H6+ 2 126.0464 1.42
127.0545 C10H7+ 2 127.0542 2.39
128.0496 C9H6N+ 1 128.0495 0.97
128.0621 C10H8+ 2 128.0621 0.69
129.0449 C8H5N2+ 1 129.0447 1.28
129.0702 C10H9+ 2 129.0699 2.5
130.0653 C9H8N+ 1 130.0651 1.42
132.0243 C8H3FN+ 1 132.0244 -0.94
133.0449 C9H6F+ 1 133.0448 0.56
134.0401 C8H5FN+ 1 134.0401 0.2
134.0603 C8H8NO+ 1 134.06 1.79
135.0479 C8H6FN+ 1 135.0479 0.08
136.0559 C8H7FN+ 1 136.0557 1.37
140.0495 C10H6N+ 1 140.0495 0.03
141.0575 C10H7N+ 1 141.0573 1.34
142.0653 C10H8N+ 1 142.0651 1.23
143.0608 C9H7N2+ 1 143.0604 2.69
144.0444 C9H6NO+ 1 144.0444 0.28
145.0323 C9H4FN+ 1 145.0322 0.22
145.0648 C10H9O+ 2 145.0648 -0.22
146.0401 C9H5FN+ 1 146.0401 0.59
146.047 C8H6N2O+ 1 146.0475 -3.25
146.0527 C10H7F+ 1 146.0526 0.69
146.0593 C9H8NO+ 1 146.06 -4.93
147.048 C9H6FN+ 1 147.0479 1.1
147.0606 C10H8F+ 1 147.0605 0.99
148.0558 C9H7FN+ 1 148.0557 0.65
149.0512 C8H6FN2+ 1 149.051 1.39
150.035 C8H5FNO+ 1 150.035 0.08
151.0429 C8H6FNO+ 1 151.0428 0.51
152.0498 C11H6N+ 1 152.0495 2.33
153.0577 C11H7N+ 1 153.0573 2.41
154.0652 C11H8N+ 1 154.0651 0.61
155.0605 C10H7N2+ 1 155.0604 0.94
155.0729 C11H9N+ 1 155.073 -0.46
156.0683 C10H8N2+ 1 156.0682 0.39
156.081 C11H10N+ 1 156.0808 1.63
158.0402 C10H5FN+ 1 158.0401 0.86
158.0601 C10H8NO+ 1 158.06 0.19
159.0482 C10H6FN+ 1 159.0479 1.77
159.0607 C11H8F+ 1 159.0605 1.54
160.0437 C9H5FN2+ 1 160.0431 3.89
160.0558 C10H7FN+ 1 160.0557 0.91
161.0274 C9H4FNO+ 1 161.0271 1.78
161.0513 C9H6FN2+ 1 161.051 2.09
161.0636 C10H8FN+ 1 161.0635 0.75
162.0353 C9H5FNO+ 1 162.035 1.98
162.0591 C9H7FN2+ 1 162.0588 1.93
162.0714 C10H9FN+ 1 162.0714 0.41
163.0429 C9H6FNO+ 1 163.0428 0.41
163.0669 C9H8FN2+ 1 163.0666 1.88
164.0506 C9H7FNO+ 1 164.0506 0.01
165.0702 C13H9+ 2 165.0699 1.66
166.0529 C11H6N2+ 2 166.0525 2.29
166.0655 C12H8N+ 2 166.0651 2.37
167.0604 C11H7N2+ 1 167.0604 0.15
167.0729 C12H9N+ 1 167.073 -0.42
168.0684 C11H8N2+ 1 168.0682 0.89
168.0807 C12H10N+ 1 168.0808 -0.69
169.0761 C11H9N2+ 1 169.076 0.56
170.0602 C11H8NO+ 1 170.06 1.06
171.0478 C11H6FN+ 1 171.0479 -0.34
171.0555 C10H7N2O+ 1 171.0553 1.12
172.0558 C11H7FN+ 1 172.0557 0.62
173.0516 C10H6FN2+ 1 173.051 3.57
173.0636 C11H8FN+ 1 173.0635 0.47
174.0351 C10H5FNO+ 1 174.035 0.81
174.0591 C10H7FN2+ 1 174.0588 1.91
174.0713 C11H9FN+ 1 174.0714 -0.02
175.0429 C10H6FNO+ 1 175.0428 0.72
175.0669 C10H8FN2+ 1 175.0666 1.7
176.0507 C10H7FNO+ 1 176.0506 0.58
176.0746 C10H9FN2+ 1 176.0744 0.98
177.0821 C10H10FN2+ 1 177.0823 -0.69
178.0427 C10H7FO2+ 1 178.0425 1.3
178.0542 C9H7FN2O+ 1 178.0537 2.63
178.0663 C10H9FNO+ 1 178.0663 0.23
179.0378 C9H6FNO2+ 1 179.0377 0.4
179.0606 C12H7N2+ 1 179.0604 1.15
180.0448 C9H7FNO2+ 2 180.0455 -3.91
180.0684 C12H8N2+ 1 180.0682 0.83
180.081 C13H10N+ 1 180.0808 1.13
181.0761 C12H9N2+ 1 181.076 0.58
182.0398 C12H5FN+ 1 182.0401 -1.23
182.0597 C12H8NO+ 1 182.06 -1.7
182.0843 C12H10N2+ 2 182.0838 2.31
183.055 C11H7N2O+ 1 183.0553 -1.74
183.068 C12H9NO+ 1 183.0679 0.74
183.0919 C12H11N2+ 2 183.0917 1.39
184.0558 C12H7FN+ 1 184.0557 0.52
184.0634 C11H8N2O+ 2 184.0631 1.55
184.0756 C12H10NO+ 1 184.0757 -0.44
185.051 C11H6FN2+ 1 185.051 0.25
185.0637 C12H8FN+ 1 185.0635 0.82
185.0714 C11H9N2O+ 2 185.0709 2.33
186.059 C11H7FN2+ 1 186.0588 1.03
186.0715 C12H9FN+ 1 186.0714 0.73
187.0303 C10H4FN2O+ 1 187.0302 0.6
187.043 C11H6FNO+ 1 187.0428 1.32
187.0668 C11H8FN2+ 1 187.0666 0.95
188.0143 C10H3FNO2+ 1 188.0142 0.57
188.038 C10H5FN2O+ 1 188.038 -0.01
188.051 C11H7FNO+ 1 188.0506 2.24
188.0744 C11H9FN2+ 1 188.0744 0.06
189.046 C10H6FN2O+ 1 189.0459 0.54
189.0824 C11H10FN2+ 1 189.0823 0.67
190.0539 C10H7FN2O+ 1 190.0537 1.09
190.0665 C11H9FNO+ 1 190.0663 1.17
191.0619 C10H8FN2O+ 1 191.0615 1.9
191.0731 C14H9N+ 1 191.073 0.57
192.0457 C10H7FNO2+ 1 192.0455 0.92
192.0686 C13H8N2+ 2 192.0682 2.29
192.0804 C14H10N+ 1 192.0808 -1.9
193.0538 C10H8FNO2+ 1 193.0534 2.44
193.0763 C13H9N2+ 2 193.076 1.32
194.0838 C13H10N2+ 1 194.0838 -0.15
195.0192 C11H3N2O2+ 2 195.0189 1.52
195.0318 C9H6FNO3+ 2 195.0326 -4.27
195.0554 C12H7N2O+ 1 195.0553 0.77
195.092 C13H11N2+ 2 195.0917 1.87
196.0628 C12H8N2O+ 1 196.0631 -1.71
197.0508 C12H6FN2+ 1 197.051 -0.72
197.0706 C12H9N2O+ 1 197.0709 -1.87
197.1077 C13H13N2+ 2 197.1073 2
198.0587 C12H7FN2+ 1 198.0588 -0.24
198.0716 C13H9FN+ 1 198.0714 1.04
199.0667 C12H8FN2+ 1 199.0666 0.54
200.0507 C12H7FNO+ 1 200.0506 0.21
200.0746 C12H9FN2+ 1 200.0744 1.01
201.0586 C12H8FNO+ 1 201.0584 0.63
201.0823 C12H10FN2+ 1 201.0823 0.08
202.0301 C11H5FNO2+ 1 202.0299 1.22
202.0541 C11H7FN2O+ 1 202.0537 1.82
202.0664 C12H9FNO+ 1 202.0663 0.8
202.0903 C12H11FN2+ 1 202.0901 1.15
203.0617 C11H8FN2O+ 1 203.0615 0.75
204.033 C10H5FN2O2+ 1 204.033 0.01
205.0536 C11H8FNO2+ 1 205.0534 1.23
205.0765 C11H10FN2O+ 2 205.0772 -3.4
206.025 C10H5FNO3+ 1 206.0248 0.98
206.0839 C14H10N2+ 1 206.0838 0.24
207.0559 C13H7N2O+ 2 207.0553 3.05
207.0917 C14H11N2+ 1 207.0917 0.22
208.0862 C13H10N3+ 1 208.0869 -3.33
211.0668 C13H8FN2+ 1 211.0666 1.12
212.0749 C13H9FN2+ 1 212.0744 2.04
212.0871 C14H11FN+ 1 212.087 0.59
213.0462 C12H6FN2O+ 1 213.0459 1.51
213.0824 C13H10FN2+ 1 213.0823 0.69
214.0546 C12H7FN2O+ 1 214.0537 4.01
214.0666 C13H9FNO+ 1 214.0663 1.74
214.0904 C13H11FN2+ 1 214.0901 1.41
215.0253 C11H4FN2O2+ 1 215.0251 0.87
215.0618 C12H8FN2O+ 1 215.0615 1.22
216.0696 C12H9FN2O+ 1 216.0693 1.42
217.041 C11H6FN2O2+ 1 217.0408 1.14
217.0772 C12H10FN2O+ 1 217.0772 0.29
218.0488 C11H7FN2O2+ 1 218.0486 0.84
218.0838 C15H10N2+ 1 218.0838 -0.41
219.0919 C12H12FN2O+ 2 219.0928 -4.05
220.0408 C11H7FNO3+ 1 220.0404 1.37
221.0482 C11H8FNO3+ 1 221.0483 -0.1
221.071 C14H9N2O+ 2 221.0709 0.41
221.1075 C15H13N2+ 2 221.1073 0.97
222.0441 C10H7FN2O3+ 1 222.0435 2.56
222.0709 C15H9FN+ 1 222.0714 -2.13
223.0506 C13H7N2O2+ 2 223.0502 1.73
223.0666 C14H8FN2+ 1 223.0666 0.03
223.0868 C14H11N2O+ 2 223.0866 0.85
224.0749 C14H9FN2+ 1 224.0744 1.93
225.0823 C14H10FN2+ 1 225.0823 0.16
226.0533 C13H7FN2O+ 2 226.0537 -1.74
227.0617 C13H8FN2O+ 1 227.0615 0.85
227.0979 C14H12FN2+ 1 227.0979 -0.06
228.0533 C12H8N2O3+ 1 228.0529 1.74
228.0692 C13H9FN2O+ 2 228.0693 -0.8
229.0772 C13H10FN2O+ 1 229.0772 0.36
230.085 C13H11FN2O+ 1 230.085 0.16
231.0927 C13H12FN2O+ 2 231.0928 -0.55
233.036 C11H6FN2O3+ 1 233.0357 1.34
233.0481 C12H8FNO3+ 2 233.0483 -0.91
234.0562 C12H9FNO3+ 1 234.0561 0.31
235.0516 C11H8FN2O3+ 1 235.0513 1.25
235.0867 C15H11N2O+ 2 235.0866 0.56
236.0593 C11H9FN2O3+ 1 236.0592 0.42
236.0825 C11H11FN3O2+ 3 236.083 -1.87
237.1025 C15H13N2O+ 2 237.1022 1.18
238.0976 C14H12N3O+ 2 238.0975 0.47
239.0615 C14H8FN2O+ 2 239.0615 0.09
239.0982 C15H12FN2+ 1 239.0979 1.16
240.0701 C14H9FN2O+ 1 240.0693 3.11
241.0771 C14H10FN2O+ 2 241.0772 -0.49
243.0566 C13H8FN2O2+ 1 243.0564 0.73
244.0644 C13H9FN2O2+ 1 244.0643 0.46
247.0519 C12H8FN2O3+ 1 247.0513 2.36
253.0773 C15H10FN2O+ 2 253.0772 0.37
254.049 C14H7FN2O2+ 1 254.0486 1.39
255.0566 C14H8FN2O2+ 1 255.0564 0.7
256.0646 C14H9FN2O2+ 1 256.0643 1.46
259.0514 C13H8FN2O3+ 2 259.0513 0.21
273.0672 C14H10FN2O3+ 2 273.067 0.56
275.0824 C14H12FN2O3+ 2 275.0826 -0.93
278.0928 C16H12N3O2+ 3 278.0924 1.43
298.0983 C16H13FN3O2+ 2 298.0986 -1.18
PK$NUM_PEAK: 245
PK$PEAK: m/z int. rel.int.
53.0022 12590.2 18
53.0386 4134.8 6
54.0339 2976.1 4
55.0417 1845.8 2
55.0543 12942.5 19
56.0495 4068.1 6
57.0573 2618.9 3
58.0651 1736 2
60.0245 730.3 1
65.0386 13039.8 19
66.0464 2050.6 3
67.0417 79358.8 119
67.0543 8816.8 13
68.0495 24338.2 36
69.0573 740.9 1
69.0698 1888 2
70.0652 68519.7 103
74.0964 900 1
75.0479 711.9 1
79.0417 1038.3 1
79.0543 7240.8 10
80.0495 44603.5 67
81.0574 34363.4 51
82.0651 664316.2 999
83.0729 52259.1 78
84.0808 22677 34
93.0573 681.6 1
94.0652 40823.6 61
95.0492 3898.6 5
95.0606 691.5 1
96.0445 4835.1 7
96.0808 27141 40
97.0761 5415 8
105.0449 2387 3
107.0293 945.3 1
109.0449 1621.4 2
115.0417 915.3 1
115.0542 3713.3 5
116.0495 3023.9 4
117.0574 2292.8 3
122.0401 2788.8 4
126.0466 806.1 1
127.0545 3500.3 5
128.0496 3808 5
128.0621 2174.5 3
129.0449 2093.2 3
129.0702 741.9 1
130.0653 1588.4 2
132.0243 1805.7 2
133.0449 10493 15
134.0401 2423.5 3
134.0603 940.3 1
135.0479 8326.3 12
136.0559 6148.2 9
140.0495 5530.8 8
141.0575 3653.6 5
142.0653 1035.8 1
143.0608 756.4 1
144.0444 1924.7 2
145.0323 679.5 1
145.0648 3394.8 5
146.0401 5564.2 8
146.047 789.9 1
146.0527 11650.3 17
146.0593 935.5 1
147.048 2097.3 3
147.0606 3971.3 5
148.0558 11030.1 16
149.0512 4784.7 7
150.035 3146.9 4
151.0429 3565.4 5
152.0498 4626.8 6
153.0577 919.3 1
154.0652 18487.3 27
155.0605 8901.7 13
155.0729 3238.2 4
156.0683 2176 3
156.081 1039 1
158.0402 2351.1 3
158.0601 1021.9 1
159.0482 6546.6 9
159.0607 938.1 1
160.0437 3648.4 5
160.0558 17002.7 25
161.0274 2252.3 3
161.0513 7549.8 11
161.0636 6262.2 9
162.0353 4390.3 6
162.0591 8176.9 12
162.0714 2441.6 3
163.0429 2192.3 3
163.0669 2360 3
164.0506 6967.5 10
165.0702 3300.5 4
166.0529 795.2 1
166.0655 2012 3
167.0604 10586.1 15
167.0729 2113.3 3
168.0684 16211.3 24
168.0807 1838.3 2
169.0761 4094 6
170.0602 4093.7 6
171.0478 1899.1 2
171.0555 1838.4 2
172.0558 64009 96
173.0516 9102.1 13
173.0636 14612.3 21
174.0351 6480.6 9
174.0591 6300 9
174.0713 10565.5 15
175.0429 1646.5 2
175.0669 5318.3 7
176.0507 2443.1 3
176.0746 857.5 1
177.0821 800.4 1
178.0427 3365.3 5
178.0542 6782 10
178.0663 17874.1 26
179.0378 4180.7 6
179.0606 14972.9 22
180.0448 3452.3 5
180.0684 2229.5 3
180.081 2215.4 3
181.0761 5145.6 7
182.0398 991.4 1
182.0597 2950.3 4
182.0843 1995 3
183.055 762.9 1
183.068 779.8 1
183.0919 991.4 1
184.0558 2540.3 3
184.0634 2741.9 4
184.0756 1489 2
185.051 941.6 1
185.0637 7094.1 10
185.0714 2486 3
186.059 9205 13
186.0715 5330.2 8
187.0303 12876.7 19
187.043 4765.7 7
187.0668 57818.8 86
188.0143 12107.9 18
188.038 765 1
188.051 3828.3 5
188.0744 2757.7 4
189.046 9220 13
189.0824 2552.7 3
190.0539 2703.2 4
190.0665 808.7 1
191.0619 3745.3 5
191.0731 2740.3 4
192.0457 1871.9 2
192.0686 2493.3 3
192.0804 3037.5 4
193.0538 1793.3 2
193.0763 7444.3 11
194.0838 2165.9 3
195.0192 2290.3 3
195.0318 772.2 1
195.0554 3488.2 5
195.092 1847.1 2
196.0628 2919.2 4
197.0508 2327.3 3
197.0706 3444.9 5
197.1077 808.9 1
198.0587 4408.6 6
198.0716 3699.9 5
199.0667 26324.9 39
200.0507 11624.2 17
200.0746 7503.7 11
201.0586 11667.8 17
201.0823 5586.5 8
202.0301 1676.9 2
202.0541 2528.7 3
202.0664 17499.4 26
202.0903 4750 7
203.0617 25343.2 38
204.033 2035.1 3
205.0536 4624.9 6
205.0765 2771.7 4
206.025 1015.4 1
206.0839 2558.2 3
207.0559 2648.3 3
207.0917 1884.6 2
208.0862 1484.9 2
211.0668 7052.7 10
212.0749 4852.7 7
212.0871 11809.4 17
213.0462 1036.3 1
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214.0666 3160.7 4
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215.0253 39577.2 59
215.0618 38460.1 57
216.0696 2993.7 4
217.041 16622.4 24
217.0772 3537.9 5
218.0488 8887.1 13
218.0838 697.5 1
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220.0408 2641.5 3
221.0482 861.6 1
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221.1075 848.2 1
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223.0506 861.2 1
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224.0749 2889.7 4
225.0823 3117.1 4
226.0533 4268.5 6
227.0617 16765.1 25
227.0979 3087.5 4
228.0533 1991.5 2
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230.085 1008.3 1
231.0927 3438.2 5
233.036 17380.4 26
233.0481 1830.5 2
234.0562 723.3 1
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236.0593 2878.1 4
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238.0976 2490.6 3
239.0615 2003.2 3
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240.0701 1607.2 2
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243.0566 2008.2 3
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253.0773 2852.5 4
254.049 999.9 1
255.0566 102072.7 153
256.0646 978.1 1
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273.0672 29678.6 44
275.0824 748.5 1
278.0928 1846.9 2
298.0983 701 1
//
