ACCESSION: MSBNK-NAIST-KNA00744
RECORD_TITLE: Phosphoenolpyruvic acid; LC-ESI-ITFT; MS; NEG
DATE: 2016.01.19 (Created 2009.11.19, modified 2011.08.03)
AUTHORS: Takahashi H, Kanaya S, Ogasawara N, Graduate School of Information Science, NAIST
LICENSE: CC BY-SA
COMMENT: [Spectral] Phosphoenolpyruvate (exact mass = 167.98237) and 6-Phospho-D-gluconate (exact mass = 276.02463) were not completely separated on HPLC under the present analytical conditions as described in "AC$XXX". Additionally some of the peaks in this data contains dimers and other unidentified ions.
CH$NAME: Phosphoenolpyruvate
CH$NAME: Phosphoenolpyruvic acid
CH$NAME: PEP
CH$COMPOUND_CLASS: Natural Product
CH$FORMULA: C3H5O6P
CH$EXACT_MASS: 167.98237
CH$SMILES: C=C(C(O)=O)OP(O)(O)=O
CH$IUPAC: InChI=1S/C3H5O6P/c1-2(3(4)5)9-10(6,7)8/h1H2,(H,4,5)(H2,6,7,8)
CH$LINK: CAS
138-08-9
CH$LINK: CHEBI
18021
CH$LINK: KEGG
C00074
CH$LINK: KNAPSACK
C00000798
CH$LINK: NIKKAJI
J9.706C
CH$LINK: PUBCHEM 3374
CH$LINK: INCHIKEY
DTBNBXWJWCWCIK-UHFFFAOYSA-N
CH$LINK: COMPTOX
DTXSID80861797
AC$INSTRUMENT: LTQ Orbitrap XL, Thermo Scientfic
AC$INSTRUMENT_TYPE: LC-ESI-ITFT
AC$MASS_SPECTROMETRY: MS_TYPE MS
AC$MASS_SPECTROMETRY: ION_MODE NEGATIVE
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 35eV
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$CHROMATOGRAPHY: COLUMN_NAME TOSOH TSKgel ODS-100V 5um Part no. 21456
AC$CHROMATOGRAPHY: FLOW_GRADIENT 0min:3%, 45min:97%, 50min:97%, 50.1:3%, 57min:3% (acetonitrile)
AC$CHROMATOGRAPHY: FLOW_RATE 0.5 ml/min
AC$CHROMATOGRAPHY: RETENTION_TIME 7.034992 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1%formate-water
AC$CHROMATOGRAPHY: SOLVENT B 0.1%formate-acetonitrile
MS$FOCUSED_ION: BASE_PEAK 275.017029
PK$SPLASH: splash10-00p0-0493110000-030918b5e462bfd35464
PK$NUM_PEAK: 731
PK$PEAK: m/z int. rel.int.
100.233195 747.580627 1
100.990901 662.185242 1
101.841061 706.941833 1
102.116761 677.076294 1
102.175860 728.689880 1
102.964428 809.225037 1
103.353801 685.183899 1
103.911690 840.638733 1
103.920096 1105.723633 1
104.993731 869.544006 1
105.452354 831.268860 1
106.006721 798.176575 1
106.580437 896.612122 1
106.583971 770.364075 1
107.991261 885.176575 1
108.361769 951.641907 1
108.558956 838.997375 1
109.186732 672.798035 1
110.023987 783.774841 1
110.985469 766.297424 1
111.634218 878.594788 1
112.517648 756.882874 1
114.465815 772.354797 1
114.951389 3521.943359 4
115.720836 785.029602 1
116.167338 905.571594 1
118.016252 699.958557 1
120.946090 811.043640 1
121.954021 855.055725 1
122.535978 671.262146 1
122.705548 862.651062 1
123.149992 742.012024 1
123.248683 762.775940 1
123.702061 823.081604 1
125.319479 815.560486 1
126.227144 745.595032 1
126.299518 722.522034 1
128.525880 736.346008 1
129.018959 5626.342285 7
130.853762 806.060364 1
132.115912 746.973572 1
133.363815 737.563416 1
133.416498 904.707214 1
134.047025 4894.249512 6
138.974691 780.606262 1
138.979953 25400.464844 30
144.447407 770.744934 1
144.753913 750.935852 1
145.890482 1392.970703 2
148.964139 7528.482910 9
149.358570 729.022278 1
150.665844 800.975525 1
150.979747 898.683167 1
152.071460 762.999695 1
152.251605 785.269104 1
152.809310 821.695496 1
152.894641 1225.432373 1
152.917146 1301.479248 2
152.988981 748.497498 1
154.733043 856.342224 1
156.098774 816.197205 1
156.938943 2668.351318 3
158.925159 4542.606934 5
159.029304 3144.153076 4
160.911907 1445.198486 2
161.665775 808.889221 1
163.080842 740.609070 1
165.035663 924.173035 1
165.593854 756.627869 1
165.911959 787.111023 1
166.919859 1604.138916 2
166.937381 1860.036865 2
166.961018 889.901306 1
166.963872 2514.120361 3
166.967948 5540.324219 7
166.971616 12886.223633 15
166.974877 514453.468750 615
166.978546 15089.543945 18
166.982215 7121.835449 9
166.985884 2288.554199 3
166.994446 829.691345 1
167.012794 2127.860596 3
167.978097 9115.690430 11
168.792997 726.565002 1
168.889574 6346.936523 8
168.899112 1111.310791 1
168.978764 5709.178711 7
168.990385 4188.017090 5
169.019026 764.964661 1
169.457029 684.758911 1
171.997072 777.018005 1
173.048973 959.730286 1
174.101004 747.069763 1
174.601195 678.595886 1
174.927694 3727.357422 4
175.318248 1003.296936 1
175.492931 834.814758 1
176.897171 7006.145020 8
176.904284 1149.137451 1
176.906951 2172.695068 3
176.926068 25538.283203 31
176.995449 1534.992676 2
177.036386 861.473083 1
177.037276 888.890930 1
177.039946 42446.546875 51
177.043951 1447.539063 2
177.047957 790.321228 1
178.043327 1789.007568 2
178.443016 786.659973 1
179.422490 871.410950 1
179.562423 842.249207 1
179.880607 905.258362 1
180.665325 728.185974 1
180.906431 1325.367188 2
180.948271 1019.237976 1
180.990127 1010.081604 1
181.352251 752.518860 1
181.699266 904.509705 1
181.865038 800.079895 1
182.753311 813.695129 1
184.374832 1493.650146 2
185.399326 898.967224 1
185.892031 1844.375244 2
185.901609 1118.299316 1
193.345186 833.381531 1
193.482400 875.011658 1
194.880079 930.241882 1
194.917606 1815.765137 2
194.922747 5150.170410 6
194.926860 180965.375000 216
194.931488 4243.795410 5
194.936116 1997.713867 2
194.962858 760.508606 1
195.005553 910.990662 1
195.050321 12118.421875 14
195.926125 1116.317139 1
196.561340 933.912170 1
196.922651 13456.622070 16
196.931004 3758.089600 4
198.907903 12159.629883 15
198.922744 812.890686 1
198.982124 1840.005127 2
199.000686 20482.632813 24
200.906649 853.066833 1
201.997319 1002.965759 1
202.157966 786.602356 1
202.695567 880.859924 1
202.922567 1533.812988 2
203.959807 1129.504150 1
204.073772 854.022644 1
204.082585 853.871399 1
206.688987 862.591125 1
208.395492 773.979797 1
208.933075 883.845886 1
208.942775 8405.523438 10
210.195170 953.098328 1
212.024677 944.453674 1
213.016228 1235.087402 1
216.699806 881.198669 1
216.898225 2517.774170 3
216.903054 1667.432861 2
216.908485 59042.871094 71
216.913918 944.728088 1
218.642566 781.273865 1
218.884646 4090.176025 5
218.904838 4048.374756 5
220.697646 988.962341 1
226.975157 957.730286 1
227.226034 817.799622 1
227.983117 1773.876709 2
228.505605 762.745544 1
228.875424 3705.696045 4
228.901594 1816.651611 2
229.011556 1509.697998 2
230.142585 700.510071 1
231.934631 933.707947 1
232.873086 1560.997070 2
232.883158 5463.816406 7
233.901708 965.184631 1
234.338243 1031.606201 1
234.792313 722.875671 1
236.895790 742.554138 1
237.896434 2637.649414 3
238.904129 20185.470703 24
238.907617 1104.116455 1
238.995547 4699.208496 6
240.961435 798.599792 1
242.858697 1878.034912 2
243.696027 732.890808 1
244.860960 822.519592 1
244.932642 2115.914551 3
244.950025 733.041321 1
245.868112 3495.764404 4
245.916192 847.537415 1
245.993441 1317.694824 2
246.876361 1031.560547 1
246.885888 1515.939209 2
246.912275 11441.108398 14
246.940865 2230.469727 3
247.838478 2028.115479 2
247.848062 977.430481 1
248.845534 4908.735352 6
248.855176 4979.940918 6
248.864818 1176.760498 1
249.629820 780.667786 1
254.892665 911.793518 1
255.792280 871.301453 1
256.014252 1973.023926 2
256.852918 812.537048 1
256.870807 1459.200928 2
256.993745 2407.835205 3
256.999194 2632.227539 3
257.006200 145726.312500 174
257.012427 3128.255615 4
257.016320 970.048523 1
257.019433 1265.204102 2
258.009405 6648.771973 8
258.868132 1146.865967 1
259.010620 1707.448486 2
260.811636 836.520325 1
262.413720 830.530334 1
264.867469 1108.597900 1
264.878056 1245.849609 1
264.920414 1250.017822 1
264.927746 3531.151367 4
264.935078 7766.264160 9
264.942411 403193.187500 482
264.948929 9493.205078 11
264.956262 3595.720459 4
264.963596 999.367126 1
265.017384 1344.378174 2
265.940860 1575.352783 2
265.944956 8392.662109 10
266.323918 741.448792 1
266.937547 13031.449219 16
266.945787 5260.910645 6
266.957324 3115.248291 4
268.922808 2055.983643 2
268.941972 779.051697 1
269.360766 754.821838 1
272.956090 1829.613281 2
273.798107 858.855652 1
274.779084 877.611389 1
274.937494 2750.022705 3
274.952137 1116.544922 1
274.988318 2157.923828 3
274.993487 3007.071533 4
274.996933 1625.067383 2
275.002103 7576.247070 9
275.008996 17028.425781 20
275.016751 835524.750000 999
275.024506 18173.939453 22
275.032261 8496.561523 10
275.040017 2349.111572 3
275.077077 1168.823486 1
275.096903 2860.652100 3
275.255588 1351.502441 2
276.019884 40938.433594 49
277.020676 8026.380371 10
277.024161 1625.415283 2
278.024294 1099.253174 1
278.947975 926.973694 1
280.872332 1629.471436 2
282.906551 800.657654 1
285.099324 890.161316 1
286.736137 917.019836 1
286.910509 1158.441162 1
286.923364 28723.425781 34
288.899438 5269.500488 6
288.908716 3011.104980 4
288.918922 1142.650391 1
288.947686 1121.312988 1
289.008013 1447.912598 2
289.015440 3884.136963 5
289.024723 9633.895508 12
289.033078 438517.968750 524
289.040505 9447.173828 11
289.048861 3899.318604 5
289.058146 1463.458984 2
289.118507 1783.242432 2
289.429902 813.056580 1
289.980485 1196.256836 1
290.035537 23052.876953 28
290.039270 1502.906006 2
291.035716 5229.014160 6
292.893439 1743.009277 2
296.997916 6986.873535 8
298.907252 2890.022217 3
298.974632 2042.314209 2
300.003774 3891.585205 5
300.859706 6037.122070 7
301.031332 780.945496 1
302.888112 2402.243652 3
302.897076 1229.655273 1
305.430661 938.388611 1
305.572908 860.506165 1
306.862688 1654.196533 2
307.279503 758.081848 1
308.858866 4757.105469 6
308.862968 1170.242676 1
308.867070 4659.532227 6
309.858084 1262.411865 2
309.867359 743.153259 1
309.870450 735.919739 1
310.854911 850.554382 1
310.924300 1307.019287 2
314.875934 1969.451904 2
315.188633 904.443665 1
316.985061 2496.791260 3
317.852636 4574.224121 5
317.863342 1821.431152 2
318.854972 804.021790 1
318.861426 26198.513672 31
318.933512 9185.819336 11
319.919347 757.633728 1
319.932320 807.968323 1
319.936645 1041.618408 1
320.876091 880.409241 1
326.868451 7781.975098 9
327.421823 894.453552 1
328.045066 1355.894043 2
328.811981 1209.381592 1
328.935929 3834.791260 5
330.841103 3952.778076 5
330.849062 746.711243 1
331.000330 2483.536133 3
334.949155 1288.696777 2
334.956104 108608.445313 130
334.966528 2513.394775 3
335.960199 5706.322266 7
336.240758 746.860779 1
336.857822 1040.880127 1
336.943108 8224.073242 10
336.960636 1335.488770 2
336.972323 1668.325195 2
338.987934 1320.770996 2
339.743868 794.107117 1
343.994060 25194.769531 30
344.269054 833.953552 1
344.997932 2084.875000 2
345.793506 737.845276 1
346.812592 7695.116211 9
348.850785 1115.578369 1
350.959164 5660.936035 7
354.973237 10160.558594 12
356.938612 6030.681641 7
357.201214 731.592346 1
358.915216 17519.189453 21
358.955044 1197.683350 1
359.363984 941.280334 1
359.918066 1502.144531 2
362.908857 16164.757813 19
364.903721 1211.631104 1
367.705096 882.349915 1
368.998012 1280.650391 2
372.879846 1130.765137 1
372.958759 1873.043701 2
372.962842 1957.794922 2
372.971007 7148.845703 9
372.983255 336325.718750 402
372.995504 6490.190918 8
373.007753 3059.850830 4
373.977356 1101.535645 1
373.986921 16497.878906 20
374.979552 12735.699219 15
374.987784 6480.660645 8
376.954584 1108.470215 1
378.872798 7035.148926 8
378.909026 906.231140 1
378.941079 2615.210205 3
384.890107 5664.333496 7
386.013882 2877.175293 3
386.866415 3606.071289 4
386.977136 1160.909912 1
386.985765 1379.673828 2
386.990080 1439.699463 2
386.998710 150339.781250 180
387.011656 2648.559082 3
387.867498 6936.708984 8
388.003195 8423.222656 10
388.824666 1009.914246 1
388.875370 4479.984863 5
388.995650 4495.968262 5
389.002898 3513.555420 4
389.232027 892.946838 1
390.891253 6133.062012 7
390.980335 1018.912170 1
391.284319 847.121521 1
391.849383 937.364197 1
394.275709 901.224548 1
394.965882 19791.068359 24
395.901832 1273.440674 2
395.968813 1249.578125 1
396.941202 2193.728271 3
397.803228 887.496887 1
398.890736 2449.098389 3
398.899767 5420.500488 6
400.856185 1418.650635 2
400.895611 1419.928955 2
401.013926 3040.094482 4
401.490751 869.704773 1
402.009540 4981.125977 6
406.826533 1931.811035 2
407.884347 887.986267 1
407.893685 1530.908203 2
408.010441 5874.064941 7
408.821326 885.814514 1
408.893175 15488.416016 19
408.902548 3909.319580 5
408.982231 14765.591797 18
409.013485 884.283386 1
409.410730 868.936951 1
409.985726 1285.446289 2
410.026507 2095.373047 3
410.929959 3084.263916 4
410.956715 2310.708496 3
412.915411 2862.760010 3
414.905708 1647.643799 2
415.820536 1812.532959 2
415.834955 719.753479 1
416.828418 6940.017578 8
416.900779 15306.128906 18
416.912037 1787.928711 2
418.824435 1290.929199 2
418.895697 1014.021912 1
421.910115 976.937561 1
424.907540 1480.047852 2
424.988636 4440.361328 5
425.895516 4573.803711 5
426.021747 26997.662109 32
426.903606 17978.138672 21
427.023617 2648.448730 3
428.920483 1448.520264 2
429.919128 2815.819824 3
430.916193 30929.554688 37
430.924643 2137.866211 3
431.915035 1550.283447 2
432.903740 814.849670 1
432.912248 1982.735107 2
432.924161 9645.938477 12
437.332985 793.657898 1
439.912002 2444.672363 3
442.350387 1162.809814 1
442.982086 1225.656738 1
442.997940 104778.070313 125
443.013795 1707.644287 2
444.001986 8710.652344 10
444.484929 792.044617 1
445.002356 1923.425293 2
453.640979 844.860779 1
454.906836 4490.337891 5
456.881993 1248.694336 1
456.998254 1328.416504 2
457.001945 1091.222412 1
457.014866 73164.179688 87
457.031479 1199.005859 1
457.046247 1098.560059 1
458.018817 5899.532227 7
459.018647 1200.778320 1
460.344415 838.183411 1
461.054341 1441.754395 2
464.980868 4098.767090 5
466.957249 7320.668945 9
469.101704 835.104675 1
470.951864 9313.886719 11
472.948987 943.415833 1
476.839859 950.620667 1
477.900009 1832.168945 2
478.542148 927.660339 1
478.908252 2222.698730 3
478.997367 2605.089111 3
480.972194 7807.922363 9
481.980182 708.075256 1
484.966729 4587.433594 5
485.835533 1727.475586 2
486.842620 3552.944336 4
486.915689 2445.504150 3
486.962381 1253.883789 1
492.932812 10669.258789 13
495.909206 3025.290527 4
496.918492 6468.432129 8
499.975466 1081.486084 1
500.931525 4710.811035 6
502.939246 5683.445801 7
506.947938 4978.748535 6
508.924726 1145.811279 1
509.830451 741.393738 1
509.926161 3341.816162 4
511.977311 1314.539551 2
522.913242 2879.251221 3
523.987993 2100.254883 3
524.870627 2872.116455 3
526.898428 1032.883545 1
528.882849 2794.131104 3
533.029593 3854.594482 5
533.893226 1143.098633 1
533.963153 1097.173096 1
537.879900 1064.902344 1
538.885318 9335.674805 11
540.966431 9966.018555 12
547.045642 3538.287354 4
551.041493 40224.402344 48
552.044846 3166.745117 4
552.861782 878.153870 1
552.874062 1804.863037 2
554.982467 11424.999023 14
558.898464 1954.724854 2
561.875936 863.316345 1
562.946890 4522.500000 5
565.034560 912.035095 1
565.057398 69873.296875 84
565.077700 1153.494385 1
565.911030 911.750061 1
566.061124 8620.376953 10
566.190913 874.221985 1
567.059872 3083.138428 4
573.022719 1943.377441 2
573.043452 1854.563477 2
576.963940 6155.856445 7
578.914288 1019.999084 1
578.940605 3155.020508 4
579.072217 68884.578125 82
579.095912 907.264587 1
580.076577 7359.455566 9
581.075613 2594.247803 3
584.811677 2051.971680 2
584.883825 2571.177002 3
586.906737 1444.141113 2
587.038388 1712.791992 2
589.015777 2835.579346 3
592.967909 797.594177 1
593.874651 1336.477051 2
594.884887 3889.078857 5
594.958908 2054.180176 2
597.903489 1097.890625 1
598.899105 5551.177246 7
599.106838 879.768738 1
600.639084 839.713562 1
600.906162 1859.485352 2
601.053687 1783.421143 2
603.029625 1524.186768 2
603.228314 698.791199 1
604.916928 1019.950745 1
604.959094 2538.430176 3
607.893361 2435.885986 3
608.899850 5413.854492 6
608.973663 6835.427246 8
609.979991 1159.236816 1
610.980256 4199.028320 5
617.967338 1041.857422 1
618.975684 1644.734131 2
620.018584 5458.491699 7
622.989781 2524.331787 3
624.995252 5773.494629 7
625.597895 841.170105 1
627.043053 938.560974 1
631.987624 1010.749207 1
634.033718 1210.882568 1
634.936544 1400.715088 2
635.033282 885.230042 1
636.854252 1650.272217 2
638.027928 2419.856445 3
645.014783 1046.381104 1
646.978366 1371.218018 2
647.261388 783.364197 1
648.954053 2456.635010 3
649.007153 10396.958008 12
650.014168 2172.264893 3
654.824898 1754.425781 2
655.883570 890.507385 1
656.483776 842.035950 1
661.617357 850.283997 1
662.270530 819.734192 1
663.024651 18733.968750 22
664.025684 1666.167969 2
664.899400 1362.801025 2
665.028986 1440.303223 2
670.988450 2096.863037 3
674.929841 2003.251465 2
676.901926 1140.417480 1
677.038365 11944.849609 14
678.916088 2641.158203 3
679.046450 911.161560 1
685.006033 3496.778320 4
686.981654 1069.114258 1
692.849799 1217.057373 1
696.864005 955.234070 1
697.688440 813.770569 1
699.020359 4673.895508 6
702.046972 973.769226 1
702.926395 1471.708740 2
703.264532 860.643250 1
706.868813 2813.191406 3
706.939831 2808.301025 3
708.946969 1280.184326 2
712.020403 1350.547363 2
716.945538 1915.009521 2
719.024610 3663.654785 4
720.955448 2193.566406 3
722.963848 2877.703857 3
725.966351 959.108337 1
728.147917 1322.147949 2
730.958733 1724.688477 2
733.039104 9497.232422 11
733.654435 854.656189 1
734.045046 1371.889160 2
735.045531 1135.633057 1
742.068353 3005.586914 4
742.981973 1242.872559 1
743.066156 1383.089355 2
744.944871 2023.188721 2
747.054416 7775.992676 9
748.112550 937.959412 1
750.841592 898.548767 1
752.866961 1060.271484 1
754.140894 817.944275 1
755.022029 1229.917969 1
756.993514 1392.699951 2
760.991449 2253.790527 3
766.105670 8796.211914 11
766.879454 1558.852051 2
768.901623 933.625793 1
770.026714 959.737732 1
771.012689 858.357483 1
775.004123 1927.179688 2
775.877169 1558.278320 2
776.882589 1933.710205 2
776.956233 1891.844727 2
782.972907 2482.595215 3
785.836818 877.934631 1
786.957587 2204.126465 3
796.991745 2093.957520 3
806.050409 2021.728760 2
808.116724 52524.687500 63
809.120249 10123.463867 12
810.108219 1525.290283 2
810.125644 1395.613770 2
816.991124 2345.412842 3
819.015534 1284.922119 2
820.066056 1510.019531 2
830.100175 1948.751465 2
831.004618 8001.402832 10
832.981435 847.318054 1
832.995062 1023.202820 1
841.079471 5402.560547 6
842.085017 939.206604 1
845.019674 6181.200684 7
846.027648 1150.568115 1
852.033653 1225.717529 1
852.988308 2142.086182 3
854.741896 827.789368 1
855.096097 7990.934082 10
856.103228 2077.772705 2
861.027232 2244.140137 3
865.950508 909.851257 1
866.123852 2996.573730 4
869.112562 3592.194336 4
873.007909 1139.066650 1
874.173807 785.657288 1
874.921404 970.521790 1
888.939265 1400.056152 2
899.987285 825.896667 1
901.023682 1815.794678 2
905.985271 1212.226563 1
906.088321 1080.298584 1
913.961452 822.672913 1
915.037777 2475.118896 3
918.541105 1094.032227 1
925.034056 1220.050049 1
938.011068 898.675842 1
939.048612 4776.622070 6
940.049759 1133.288574 1
953.061591 6906.448242 8
961.038186 986.874084 1
967.083692 3558.933350 4
968.078800 1141.275635 1
974.030135 1141.771484 1
982.510494 943.674744 1
989.047956 1074.158691 1
998.983138 884.815613 1
1005.969235 6064.883301 7
1006.970641 1409.982666 2
1009.062721 2973.908447 4
1013.004506 1423.058105 2
1023.081163 3309.689697 4
1037.097140 1110.306885 1
1050.688538 815.081482 1
1063.886402 866.924866 1
1080.924348 960.331848 1
1099.152449 1204.208740 1
1105.965432 9705.364258 12
1106.966746 2532.194336 3
1113.824532 780.610779 1
1121.044025 3079.418457 4
1123.729407 845.782410 1
1125.696261 1002.666809 1
1128.606095 812.288757 1
1129.014515 1082.068115 1
1135.066361 1734.509766 2
1165.985321 3704.677734 4
1166.986407 1133.366943 1
1205.956640 3783.448486 5
1206.138642 815.590393 1
1206.962121 1401.276123 2
1217.953304 1343.345459 2
1229.070887 968.931580 1
1243.102501 1614.712646 2
1250.037395 859.513245 1
1255.953397 2396.173340 3
1256.954705 1556.218506 2
1265.978062 11966.471680 14
1266.982865 4504.094727 5
1282.971940 1968.819336 2
1305.962819 1526.633789 2
1317.939253 5584.638184 7
1347.395570 957.718445 1
1355.939238 1332.417480 2
1356.949159 949.370056 1
1365.974981 9171.701172 11
1366.967491 2380.840820 3
1387.974689 905.912415 1
1417.754032 898.520325 1
1417.935590 4408.434570 5
1427.649086 950.277771 1
1443.681423 1116.382813 1
1459.995886 865.383972 1
1464.750333 1024.329102 1
1465.958479 3153.774170 4
1466.977026 1071.015625 1
1471.061846 890.484680 1
1487.887337 986.473938 1
//
