ACCESSION: MSBNK-Athens_Univ-AU283006
RECORD_TITLE: Desonide; LC-ESI-QTOF; MS2; CE: Ramp 23.9-35.9 eV; R=35000; [M+H]+
DATE: 2019.05.31
AUTHORS: Nikiforos Alygizakis, Katerina Galani, Nikolaos Thomaidis, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2019 Department of Chemistry, University of Athens
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 2830
CH$NAME: Desonide
CH$NAME: (1S,2S,4R,8S,9S,11S,12S,13R)-11-hydroxy-8-(2-hydroxyacetyl)-6,6,9,13-tetramethyl-5,7-dioxapentacyclo[10.8.0.02,9.04,8.013,18]icosa-14,17-dien-16-one
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C24H32O6
CH$EXACT_MASS: 416.2198887
CH$SMILES: CC1(C)O[C@@H]2C[C@H]3[C@@H]4CCC5=CC(=O)C=C[C@]5(C)[C@H]4[C@@H](O)C[C@]3(C)[C@@]2(O1)C(=O)CO
CH$IUPAC: InChI=1S/C24H32O6/c1-21(2)29-19-10-16-15-6-5-13-9-14(26)7-8-22(13,3)20(15)17(27)11-23(16,4)24(19,30-21)18(28)12-25/h7-9,15-17,19-20,25,27H,5-6,10-12H2,1-4H3/t15-,16-,17-,19+,20+,22-,23-,24+/m0/s1
CH$LINK: CAS
638-94-8
CH$LINK: CHEBI
204734
CH$LINK: KEGG
D03696
CH$LINK: PUBCHEM
CID:5311066
CH$LINK: INCHIKEY
WBGKWQHBNHJJPZ-LECWWXJVSA-N
CH$LINK: CHEMSPIDER
4470603
CH$LINK: COMPTOX
DTXSID7046756
AC$INSTRUMENT: Bruker maXis Impact
AC$INSTRUMENT_TYPE: LC-ESI-QTOF
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE CID
AC$MASS_SPECTROMETRY: COLLISION_ENERGY Ramp 23.9-35.9 eV
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME Acclaim RSLC C18 2.2um, 2.1x100mm, Thermo
AC$CHROMATOGRAPHY: FLOW_GRADIENT 99/1 at 0-1 min, 61/39 at 3 min, 0.1/99.9 at 14-16 min, 99/1 at 16.1-20 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 uL/min at 0-3 min, 400 uL/min at 14 min, 480 uL/min at 16-19 min, 200 uL/min at 19.1-20 min
AC$CHROMATOGRAPHY: RETENTION_TIME 9.047 min
AC$CHROMATOGRAPHY: SOLVENT A 90:10 water:methanol with 0.01% formic acid and 5mM ammonium formate
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.01% formic acid and 5mM ammonium formate
MS$FOCUSED_ION: BASE_PEAK 417.2274
MS$FOCUSED_ION: PRECURSOR_M/Z 417.2272
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE identity on assigned fragments and MS1
MS$DATA_PROCESSING: WHOLE RMassBank 2.10.1
PK$SPLASH: splash10-00ba-0592000000-948abcd4f4b9ee00657a
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
55.0174 C3H3O+ 1 55.0178 -7.19
55.0537 C4H7+ 1 55.0542 -10.01
59.0486 C3H7O+ 1 59.0491 -9.38
67.0537 C5H7+ 1 67.0542 -7.27
69.0328 C4H5O+ 1 69.0335 -9.43
69.069 C5H9+ 1 69.0699 -13.05
71.0487 C4H7O+ 1 71.0491 -5.58
73.0281 C3H5O2+ 1 73.0284 -4.71
79.0536 C6H7+ 1 79.0542 -7.89
81.0328 C5H5O+ 1 81.0335 -8.86
81.0697 C6H9+ 1 81.0699 -2.64
83.0124 C4H3O2+ 1 83.0128 -4.25
83.0494 C5H7O+ 1 83.0491 3.33
85.0287 C4H5O2+ 1 85.0284 3.31
85.0649 C5H9O+ 1 85.0648 0.97
87.0438 C4H7O2+ 1 87.0441 -2.61
91.0544 C7H7+ 1 91.0542 1.88
93.0704 C7H9+ 1 93.0699 5.51
95.0496 C6H7O+ 1 95.0491 4.79
95.086 C7H11+ 1 95.0855 4.49
97.0288 C5H5O2+ 1 97.0284 4.2
97.0654 C6H9O+ 1 97.0648 6.18
99.0441 C5H7O2+ 1 99.0441 0.92
101.0239 C4H5O3+ 1 101.0233 6.05
101.059 C5H9O2+ 1 101.0597 -6.9
105.0709 C8H9+ 1 105.0699 9.57
107.0491 C7H7O+ 1 107.0491 -0.8
107.0868 C8H11+ 1 107.0855 11.64
109.0658 C7H9O+ 1 109.0648 9.23
109.1007 C8H13+ 1 109.1012 -4.46
111.0449 C6H7O2+ 1 111.0441 7.42
111.0817 C7H11O+ 1 111.0804 11.06
113.0601 C6H9O2+ 1 113.0597 3.21
115.0398 C5H7O3+ 1 115.039 7.48
115.0538 C9H7+ 1 115.0542 -3.59
117.0702 C9H9+ 1 117.0699 2.59
119.086 C9H11+ 1 119.0855 3.58
121.0646 C8H9O+ 1 121.0648 -1.64
122.0681 C7[13]CH9O+ 1 122.0687 -4.99
123.0447 C7H7O2+ 1 123.0441 5.61
123.0807 C8H11O+ 1 123.0804 1.78
125.0595 C7H9O2+ 1 125.0597 -1.95
128.0622 C10H8+ 1 128.0621 1.42
129.0703 C10H9+ 1 129.0699 3.65
131.0479 C9H7O+ 1 131.0491 -9.1
131.0847 C10H11+ 1 131.0855 -6.59
132.0556 C9H8O+ 1 132.057 -10.2
133.0642 C9H9O+ 1 133.0648 -4.73
133.1001 C10H13+ 1 133.1012 -8.16
135.0797 C9H11O+ 1 135.0804 -5.14
136.0836 C8[13]CH11O+ 1 136.0843 -5.16
137.0591 C8H9O2+ 1 137.0597 -4.28
137.0943 C9H13O+ 1 137.0961 -13.22
138.063 C7[13]CH9O2+ 1 138.0636 -4.58
139.0749 C8H11O2+ 1 139.0754 -3.47
141.0538 C7H9O3+ 1 141.0546 -6.11
141.0692 C11H9+ 1 141.0699 -5.03
142.0767 C11H10+ 1 142.0777 -7
143.0845 C11H11+ 1 143.0855 -6.88
145.0636 C10H9O+ 1 145.0648 -8.23
145.1004 C11H13+ 1 145.1012 -5.55
146.0699 C9[13]CH9O+ 1 146.0687 8.32
147.0797 C10H11O+ 1 147.0804 -4.89
148.0827 C9[13]CH11O+ 1 148.0843 -11.26
149.0584 C9H9O2+ 1 149.0597 -8.9
149.0954 C10H13O+ 1 149.0961 -4.83
151.0745 C9H11O2+ 1 151.0754 -5.65
153.0699 C12H9+ 1 153.0699 0.48
153.0896 C9H13O2+ 1 153.091 -9.37
155.0688 C8H11O3+ 1 155.0703 -9.31
155.0833 C12H11+ 1 155.0855 -14.37
157.0643 C11H9O+ 1 157.0648 -2.86
157.1006 C12H13+ 1 157.1012 -3.82
158.0713 C11H10O+ 1 158.0726 -8.19
159.0649 C7H11O4+ 1 159.0652 -1.69
159.0791 C11H11O+ 1 159.0804 -8.53
160.0834 C10[13]CH11O+ 1 160.0843 -6.03
161.0953 C11H13O+ 1 161.0961 -5.02
162.0971 C10[13]CH13O+ 1 162.1 -17.76
163.0742 C10H11O2+ 1 163.0754 -7.27
164.0776 C9[13]CH11O2+ 1 164.0793 -9.86
165.0896 C10H13O2+ 1 165.091 -8.65
167.0693 C9H11O3+ 1 167.0703 -5.77
167.0863 C13H11+ 1 167.0855 4.63
169.0632 C12H9O+ 1 169.0648 -9.69
169.0997 C13H13+ 1 169.1012 -8.78
170.0715 C12H10O+ 1 170.0726 -6.32
171.0797 C12H11O+ 1 171.0804 -4.27
172.0835 C11[13]CH11O+ 1 172.0843 -5.13
173.0953 C12H13O+ 1 173.0961 -4.4
174.0984 C11[13]CH13O+ 1 174.1 -9.03
175.0727 C11H11O2+ 1 175.0754 -15.12
175.1099 C12H15O+ 1 175.1117 -10.76
177.0896 C11H13O2+ 1 177.091 -8.16
179.0841 C14H11+ 1 179.0855 -8.05
179.1059 C11H15O2+ 1 179.1067 -4.47
181.0852 C10H13O3+ 1 181.0859 -4.22
181.0971 C14H13+ 1 181.1012 -22.3
182.0721 C13H10O+ 1 182.0726 -2.94
182.0909 C9[13]CH13O3+ 1 182.0898 5.83
183.0798 C13H11O+ 1 183.0804 -3.42
184.0851 C13H12O+ 1 184.0883 -16.99
185.0954 C13H13O+ 1 185.0961 -3.8
186.0992 C12[13]CH13O+ 1 186.1 -4.01
187.0748 C12H11O2+ 1 187.0754 -2.74
187.1104 C13H15O+ 1 187.1117 -7.27
188.1149 C12[13]CH15O+ 1 188.1156 -3.74
189.0907 C12H13O2+ 1 189.091 -1.64
190.0923 C11[13]CH13O2+ 1 190.0949 -13.88
191.0844 C15H11+ 1 191.0855 -6.04
192.0917 C15H12+ 1 192.0934 -8.5
193.0994 C15H13+ 1 193.1012 -9.36
195.0803 C14H11O+ 1 195.0804 -0.68
195.1001 C11H15O3+ 1 195.1016 -7.61
195.117 C15H15+ 1 195.1168 0.81
196.0872 C14H12O+ 1 196.0883 -5.19
197.0951 C14H13O+ 1 197.0961 -4.89
197.1309 C15H17+ 1 197.1325 -7.78
198.1009 C14H14O+ 1 198.1039 -15.28
199.0745 C13H11O2+ 1 199.0754 -4.55
199.1107 C14H15O+ 1 199.1117 -5.29
200.1147 C13[13]CH15O+ 1 200.1156 -4.93
201.0898 C13H13O2+ 1 201.091 -6.1
201.1285 C14H17O+ 2 201.1274 5.45
202.094 C13H14O2+ 1 202.0988 -23.73
203.1057 C13H15O2+ 1 203.1067 -4.62
205.0992 C16H13+ 1 205.1012 -9.63
207.1168 C16H15+ 1 207.1168 -0.14
208.0882 C15H12O+ 1 208.0883 -0.35
208.12 C15[13]CH15+ 1 208.1207 -3.31
209.0954 C15H13O+ 1 209.0961 -3.09
209.1316 C16H17+ 1 209.1325 -3.96
210.1032 C15H14O+ 1 210.1039 -3.19
211.1112 C15H15O+ 1 211.1117 -2.69
212.1159 C14[13]CH15O+ 1 212.1156 1.2
213.0903 C14H13O2+ 1 213.091 -3.39
213.1263 C15H17O+ 1 213.1274 -5.1
214.131 C14[13]CH17O+ 1 214.1313 -1.56
215.1064 C14H15O2+ 1 215.1067 -1.37
215.1413 C15H19O+ 1 215.143 -8.3
216.1087 C13[13]CH15O2+ 1 216.1106 -8.45
219.1167 C17H15+ 1 219.1168 -0.78
221.0948 C16H13O+ 1 221.0961 -5.94
221.1326 C17H17+ 1 221.1325 0.65
222.1023 C16H14O+ 1 222.1039 -7.49
223.1111 C16H15O+ 1 223.1117 -2.77
224.1165 C16H16O+ 1 224.1196 -13.82
225.1273 C16H17O+ 1 225.1274 -0.63
226.1341 C16H18O+ 1 226.1352 -4.74
227.1057 C15H15O2+ 1 227.1067 -4.39
227.1416 C16H19O+ 1 227.143 -6.33
228.1452 C15[13]CH19O+ 1 228.1469 -7.66
229.0881 C14H13O3+ 1 229.0859 9.37
229.1576 C16H21O+ 1 229.1587 -4.65
230.1099 C18H14+ 2 230.109 3.77
231.1175 C18H15+ 2 231.1168 3.09
233.0943 C17H13O+ 1 233.0961 -7.49
233.1338 C18H17+ 2 233.1325 5.57
234.1031 C17H14O+ 1 234.1039 -3.51
235.1115 C17H15O+ 1 235.1117 -0.88
235.1484 C18H19+ 2 235.1481 1.08
236.117 C17H16O+ 1 236.1196 -10.83
237.1272 C17H17O+ 1 237.1274 -0.88
238.1307 C16[13]CH17O+ 1 238.1313 -2.42
239.1062 C16H15O2+ 1 239.1067 -2.01
239.1427 C17H19O+ 1 239.143 -1.58
240.1117 C16H16O2+ 1 240.1145 -11.74
240.1464 C16[13]CH19O+ 1 240.1469 -2.47
241.1213 C16H17O2+ 1 241.1223 -4.13
241.1585 C17H21O+ 2 241.1587 -0.62
242.1632 C16[13]CH21O+ 1 242.1626 2.49
243.1192 C19H15+ 2 243.1168 9.83
243.139 C16H19O2+ 1 243.138 4.2
244.1248 C19H16+ 2 244.1247 0.56
245.096 C18H13O+ 2 245.0961 -0.3
245.1332 C19H17+ 2 245.1325 2.78
246.104 C18H14O+ 2 246.1039 0.2
247.1105 C18H15O+ 1 247.1117 -5.21
247.147 C19H19+ 1 247.1481 -4.52
248.118 C18H16O+ 1 248.1196 -6.13
249.0894 C17H13O2+ 1 249.091 -6.39
249.1266 C18H17O+ 1 249.1274 -3.21
249.1643 C19H21+ 2 249.1638 2.2
250.1323 C18H18O+ 1 250.1352 -11.78
251.1069 C17H15O2+ 1 251.1067 1.01
251.1431 C18H19O+ 2 251.143 0.05
252.1463 C17[13]CH19O+ 1 252.1469 -2.52
253.1217 C17H17O2+ 1 253.1223 -2.43
253.1574 C18H21O+ 1 253.1587 -4.91
254.1256 C16[13]CH17O2+ 1 254.1262 -2.4
254.1608 C17[13]CH21O+ 1 254.1626 -7.18
255.1372 C17H19O2+ 1 255.138 -3.09
255.1747 C18H23O+ 2 255.1743 1.29
257.0961 C19H13O+ 2 257.0961 -0.09
259.1097 C19H15O+ 1 259.1117 -7.99
259.1474 C20H19+ 1 259.1481 -2.91
260.1176 C19H16O+ 1 260.1196 -7.51
260.1499 C20H20+ 1 260.156 -23.11
261.1277 C19H17O+ 2 261.1274 1.15
262.1341 C19H18O+ 1 262.1352 -4.39
263.1081 C18H15O2+ 1 263.1067 5.36
263.1428 C19H19O+ 2 263.143 -0.85
264.1129 C18H16O2+ 1 264.1145 -5.97
264.1493 C19H20O+ 1 264.1509 -5.82
265.1588 C19H21O+ 2 265.1587 0.51
266.162 C18[13]CH21O+ 1 266.1626 -2.19
267.1373 C18H19O2+ 1 267.138 -2.47
267.173 C19H23O+ 1 267.1743 -5.06
268.1402 C17[13]CH19O2+ 1 268.1419 -6.17
268.1764 C19H24O+ 1 268.1822 -21.34
269.1324 C21H17+ 2 269.1325 -0.46
269.1532 C18H21O2+ 1 269.1536 -1.35
272.1213 C20H16O+ 2 272.1196 6.39
273.1249 C19[13]CH16O+ 1 273.1235 5.24
274.1316 C20H18O+ 1 274.1352 -13.25
275.143 C20H19O+ 2 275.143 0.01
276.1136 C19H16O2+ 1 276.1145 -3.35
276.1481 C20H20O+ 1 276.1509 -10.13
277.1222 C19H17O2+ 1 277.1223 -0.37
277.1592 C20H21O+ 2 277.1587 1.7
278.1273 C18[13]CH17O2+ 1 278.1262 4.06
278.1619 C19[13]CH21O+ 1 278.1626 -2.41
279.1377 C19H19O2+ 1 279.138 -0.94
279.1675 C18[13]C2H21O+ 1 279.1659 5.4
280.1423 C19H20O2+ 1 280.1458 -12.31
281.119 C18H17O3+ 1 281.1172 6.17
281.1535 C19H21O2+ 1 281.1536 -0.36
282.1589 C19H22O2+ 1 282.1614 -8.98
283.1318 C18H19O3+ 1 283.1329 -3.9
283.1692 C19H23O2+ 1 283.1693 -0.09
284.1718 C18[13]CH23O2+ 1 284.1732 -4.74
285.1474 C18H21O3+ 1 285.1485 -3.96
287.1433 C21H19O+ 2 287.143 0.89
288.1471 C20[13]CH19O+ 1 288.1469 0.58
290.1302 C20H18O2+ 1 290.1301 0.09
291.1345 C19[13]CH18O2+ 1 291.134 1.58
292.1433 C20H20O2+ 1 292.1458 -8.66
293.1532 C20H21O2+ 1 293.1536 -1.43
294.1582 C19[13]CH21O2+ 1 294.1575 2.51
295.1691 C20H23O2+ 1 295.1693 -0.67
296.1727 C19[13]CH23O2+ 1 296.1732 -1.7
297.148 C19H21O3+ 1 297.1485 -1.8
297.1761 C18[13]C2H23O2+ 1 297.1765 -1.25
299.1622 C19H23O3+ 1 299.1642 -6.66
305.1537 C21H21O2+ 1 305.1536 0.32
306.1572 C20[13]CH21O2+ 1 306.1575 -0.9
307.1629 C19[13]C2H21O2+ 1 307.1609 6.66
311.1646 C20H23O3+ 1 311.1642 1.32
312.1668 C20H24O3+ 1 312.172 -16.66
313.1801 C20H25O3+ 1 313.1798 0.95
314.1838 C19[13]CH25O3+ 1 314.1837 0.4
321.1498 C21H21O3+ 1 321.1485 3.86
323.1646 C21H23O3+ 1 323.1642 1.39
324.168 C20[13]CH23O3+ 1 324.1681 -0.33
325.1714 C19[13]C2H23O3+ 1 325.1714 -0.24
341.1752 C21H25O4+ 1 341.1747 1.46
342.1783 C20[13]CH25O4+ 1 342.1786 -0.92
343.176 C19[13]C2H25O4+ 1 343.182 -17.41
363.1962 C24H27O3+ 1 363.1955 2.07
381.2073 C24H29O4+ 1 381.206 3.2
399.218 C24H31O5+ 1 399.2166 3.51
400.2211 C23[13]CH31O5+ 1 400.2205 1.44
401.2236 C22[13]C2H31O5+ 1 401.2239 -0.7
PK$NUM_PEAK: 263
PK$PEAK: m/z int. rel.int.
55.0174 1348 12
55.0537 948 8
59.0486 6032 57
67.0537 1080 10
69.0328 1248 11
69.069 956 9
71.0487 1488 14
73.0281 636 6
79.0536 2092 19
81.0328 1240 11
81.0697 7032 66
83.0124 920 8
83.0494 2128 20
85.0287 716 6
85.0649 864 8
87.0438 1984 18
91.0544 2468 23
93.0704 5400 51
95.0496 2060 19
95.086 4868 46
97.0288 1160 10
97.0654 2672 25
99.0441 2360 22
101.0239 6668 63
101.059 608 5
105.0709 3556 33
107.0491 928 8
107.0868 3592 33
109.0658 3424 32
109.1007 584 5
111.0449 884 8
111.0817 664 6
113.0601 1016 9
115.0398 844 7
115.0538 1400 13
117.0702 1952 18
119.086 5152 48
121.0646 26608 251
122.0681 2364 22
123.0447 948 8
123.0807 1884 17
125.0595 924 8
128.0622 1164 11
129.0703 1464 13
131.0479 664 6
131.0847 3184 30
132.0556 1748 16
133.0642 3548 33
133.1001 1384 13
135.0797 18452 174
136.0836 2324 21
137.0591 8400 79
137.0943 596 5
138.063 1068 10
139.0749 4284 40
141.0538 1712 16
141.0692 596 5
142.0767 608 5
143.0845 2748 25
145.0636 5456 51
145.1004 2780 26
146.0699 860 8
147.0797 105660 999
148.0827 11520 108
149.0584 2180 20
149.0954 2508 23
151.0745 2456 23
153.0699 608 5
153.0896 764 7
155.0688 5724 54
155.0833 2296 21
157.0643 708 6
157.1006 3520 33
158.0713 3868 36
159.0649 776 7
159.0791 14916 141
160.0834 2420 22
161.0953 17384 164
162.0971 1964 18
163.0742 11824 111
164.0776 1160 10
165.0896 1300 12
167.0693 1696 16
167.0863 708 6
169.0632 664 6
169.0997 1780 16
170.0715 588 5
171.0797 42352 400
172.0835 5504 52
173.0953 82320 778
174.0984 11472 108
175.0727 1084 10
175.1099 2808 26
177.0896 2336 22
179.0841 1448 13
179.1059 720 6
181.0852 4132 39
181.0971 1248 11
182.0721 800 7
182.0909 628 5
183.0798 2464 23
184.0851 924 8
185.0954 16304 154
186.0992 2924 27
187.0748 2312 21
187.1104 10168 96
188.1149 1564 14
189.0907 2876 27
190.0923 608 5
191.0844 568 5
192.0917 1580 14
193.0994 1480 13
195.0803 2236 21
195.1001 720 6
195.117 780 7
196.0872 1888 17
197.0951 13272 125
197.1309 1252 11
198.1009 3408 32
199.0745 652 6
199.1107 11688 110
200.1147 1904 18
201.0898 2412 22
201.1285 720 6
202.094 688 6
203.1057 1196 11
205.0992 996 9
207.1168 4748 44
208.0882 1672 15
208.12 960 9
209.0954 11184 105
209.1316 1160 10
210.1032 6608 62
211.1112 21488 203
212.1159 3588 33
213.0903 2748 25
213.1263 8868 83
214.131 1520 14
215.1064 3020 28
215.1413 912 8
216.1087 600 5
219.1167 1304 12
221.0948 7288 68
221.1326 1040 9
222.1023 5460 51
223.1111 17548 165
224.1165 6152 58
225.1273 90428 854
226.1341 73804 697
227.1057 1960 18
227.1416 38804 366
228.1452 6240 58
229.0881 1180 11
229.1576 708 6
230.1099 556 5
231.1175 704 6
233.0943 1112 10
233.1338 636 6
234.1031 2332 22
235.1115 11640 110
235.1484 1192 11
236.117 4052 38
237.1272 34456 325
238.1307 6232 58
239.1062 2024 19
239.1427 21316 201
240.1117 920 8
240.1464 4696 44
241.1213 780 7
241.1585 15236 144
242.1632 2600 24
243.1192 748 7
243.139 668 6
244.1248 568 5
245.096 664 6
245.1332 1288 12
246.104 1448 13
247.1105 3244 30
247.147 1300 12
248.118 5372 50
249.0894 800 7
249.1266 12796 120
249.1643 688 6
250.1323 4364 41
251.1069 1108 10
251.1431 10924 103
252.1463 2488 23
253.1217 3228 30
253.1574 6892 65
254.1256 740 6
254.1608 1508 14
255.1372 2684 25
255.1747 596 5
257.0961 564 5
259.1097 1244 11
259.1474 1872 17
260.1176 1276 12
260.1499 808 7
261.1277 7700 72
262.1341 9588 90
263.1081 1752 16
263.1428 32216 304
264.1129 932 8
264.1493 14944 141
265.1588 76664 724
266.162 16900 159
267.1373 4360 41
267.173 4124 38
268.1402 1100 10
268.1764 1036 9
269.1324 544 5
269.1532 1292 12
272.1213 3368 31
273.1249 760 7
274.1316 800 7
275.143 5224 49
276.1136 612 5
276.1481 2168 20
277.1222 3120 29
277.1592 38100 360
278.1273 972 9
278.1619 8932 84
279.1377 5516 52
279.1675 1056 9
280.1423 2880 27
281.119 588 5
281.1535 9800 92
282.1589 3808 36
283.1318 680 6
283.1692 8916 84
284.1718 2108 19
285.1474 544 5
287.1433 12980 122
288.1471 3132 29
290.1302 1892 17
291.1345 564 5
292.1433 1124 10
293.1532 8016 75
294.1582 2776 26
295.1691 34560 326
296.1727 6220 58
297.148 1612 15
297.1761 812 7
299.1622 664 6
305.1537 35708 337
306.1572 8856 83
307.1629 900 8
311.1646 1956 18
312.1668 740 6
313.1801 7588 71
314.1838 1568 14
321.1498 644 6
323.1646 59632 563
324.168 14276 134
325.1714 1612 15
341.1752 24176 228
342.1783 7224 68
343.176 536 5
363.1962 860 8
381.2073 836 7
399.218 93368 882
400.2211 23616 223
401.2236 3192 30
//
