ACCESSION: MSBNK-LCSB-LU099702
RECORD_TITLE: Mifepristone; LC-ESI-QFT; MS2; CE: 30; R=17500; [M+H]+
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 997
COMMENT: DATASET 20200303_ENTACT_RP_MIX502
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 8550
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 8547
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: Mifepristone
CH$NAME: (8S,11R,13S,14S,17S)-11-[4-(dimethylamino)phenyl]-17-hydroxy-13-methyl-17-prop-1-ynyl-1,2,6,7,8,11,12,14,15,16-decahydrocyclopenta[a]phenanthren-3-one
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C29H35NO2
CH$EXACT_MASS: 429.2668
CH$SMILES: CC#C[C@]1(O)CC[C@H]2[C@@H]3CCC4=CC(=O)CCC4=C3[C@H](C[C@]12C)C1=CC=C(C=C1)N(C)C
CH$IUPAC: InChI=1S/C29H35NO2/c1-5-15-29(32)16-14-26-24-12-8-20-17-22(31)11-13-23(20)27(24)25(18-28(26,29)2)19-6-9-21(10-7-19)30(3)4/h6-7,9-10,17,24-26,32H,8,11-14,16,18H2,1-4H3/t24-,25+,26-,28-,29-/m0/s1
CH$LINK: CAS
84371-65-3
CH$LINK: CHEBI
50692
CH$LINK: KEGG
D00585
CH$LINK: PUBCHEM
CID:55245
CH$LINK: INCHIKEY
VKHAHZOOUSRJNA-GCNJZUOMSA-N
CH$LINK: CHEMSPIDER
49889
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 30
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 16.426 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 79.0211
MS$FOCUSED_ION: PRECURSOR_M/Z 430.2741
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_INTENSITY 7763522.5
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-0089-0953200000-125f4359c6f39938434f
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
55.0178 C3H3O+ 1 55.0178 -0.17
55.0542 C4H7+ 1 55.0542 0.37
57.0335 C3H5O+ 1 57.0335 0.53
67.0541 C5H7+ 1 67.0542 -1.58
69.0334 C4H5O+ 1 69.0335 -1.06
69.0698 C5H9+ 1 69.0699 -1.62
79.0542 C6H7+ 1 79.0542 -0.59
81.0698 C6H9+ 1 81.0699 -0.61
83.049 C5H7O+ 1 83.0491 -1.93
85.0648 C5H9O+ 1 85.0648 -0.43
91.054 C7H7+ 1 91.0542 -2.31
93.0699 C7H9+ 1 93.0699 0
95.0492 C6H7O+ 1 95.0491 0.39
95.0855 C7H11+ 1 95.0855 -0.43
97.0647 C6H9O+ 1 97.0648 -0.44
105.0699 C8H9+ 1 105.0699 0.12
107.0491 C7H7O+ 1 107.0491 -0.58
107.0729 C7H9N+ 1 107.073 -0.14
107.0855 C8H11+ 1 107.0855 -0.24
109.0647 C7H9O+ 1 109.0648 -0.71
109.101 C8H13+ 1 109.1012 -1.2
111.0803 C7H11O+ 1 111.0804 -1.44
117.0699 C9H9+ 1 117.0699 -0.13
119.0855 C9H11+ 1 119.0855 -0.19
120.0808 C8H10N+ 1 120.0808 -0.13
121.0646 C8H9O+ 1 121.0648 -1.75
121.0886 C8H11N+ 1 121.0886 -0.22
121.1011 C9H13+ 1 121.1012 -0.75
122.0963 C8H12N+ 1 122.0964 -0.62
123.0804 C8H11O+ 1 123.0804 -0.48
125.0961 C8H13O+ 1 125.0961 0.2
129.0698 C10H9+ 1 129.0699 -0.86
131.0856 C10H11+ 1 131.0855 0.7
132.0808 C9H10N+ 1 132.0808 0.04
133.0648 C9H9O+ 1 133.0648 -0.24
133.0891 C9H11N+ 1 133.0886 3.85
133.1012 C10H13+ 1 133.1012 0.04
134.0963 C9H12N+ 1 134.0964 -0.6
135.0804 C9H11O+ 1 135.0804 -0.53
136.112 C9H14N+ 1 136.1121 -0.66
137.0961 C9H13O+ 1 137.0961 -0.15
141.0697 C11H9+ 1 141.0699 -1.13
143.0854 C11H11+ 1 143.0855 -0.64
145.0649 C10H9O+ 1 145.0648 0.42
145.1011 C11H13+ 1 145.1012 -0.69
146.0965 C10H12N+ 1 146.0964 0.19
147.0803 C10H11O+ 1 147.0804 -0.79
147.1043 C10H13N+ 1 147.1043 0.63
147.1166 C11H15+ 1 147.1168 -1.26
148.0756 C9H10NO+ 1 148.0757 -0.64
148.112 C10H14N+ 1 148.1121 -0.7
149.096 C10H13O+ 1 149.0961 -0.43
150.0913 C9H12NO+ 1 150.0913 -0.08
151.075 C9H11O2+ 1 151.0754 -2.14
155.0853 C12H11+ 1 155.0855 -1.42
157.0649 C11H9O+ 1 157.0648 0.55
157.0883 C11H11N+ 1 157.0886 -2.11
157.1012 C12H13+ 1 157.1012 -0.09
158.0961 C11H12N+ 1 158.0964 -1.98
159.0804 C11H11O+ 1 159.0804 -0.47
159.1045 C11H13N+ 1 159.1043 1.8
159.1167 C12H15+ 1 159.1168 -0.81
160.112 C11H14N+ 1 160.1121 -0.38
161.096 C11H13O+ 1 161.0961 -0.42
161.12 C11H15N+ 1 161.1199 0.49
162.1277 C11H16N+ 1 162.1277 -0.43
163.1116 C11H15O+ 1 163.1117 -0.74
167.0858 C13H11+ 1 167.0855 1.93
169.1011 C13H13+ 1 169.1012 -0.32
171.0805 C12H11O+ 1 171.0804 0.56
171.1041 C12H13N+ 1 171.1043 -0.99
171.1165 C13H15+ 1 171.1168 -2.16
172.112 C12H14N+ 1 172.1121 -0.44
173.0961 C12H13O+ 1 173.0961 -0.21
173.1197 C12H15N+ 1 173.1199 -1.22
174.1277 C12H16N+ 1 174.1277 0.12
175.1118 C12H15O+ 1 175.1117 0.34
175.1354 C12H17N+ 1 175.1356 -0.83
176.1434 C12H18N+ 1 176.1434 0.23
179.0855 C14H11+ 1 179.0855 0.07
181.1012 C14H13+ 1 181.1012 -0.07
183.0803 C13H11O+ 1 183.0804 -0.82
183.1168 C14H15+ 1 183.1168 -0.2
184.1121 C13H14N+ 1 184.1121 0.17
185.0961 C13H13O+ 1 185.0961 -0.04
185.1198 C13H15N+ 1 185.1199 -0.73
185.1321 C14H17+ 1 185.1325 -2.14
186.1276 C13H16N+ 1 186.1277 -0.54
187.1116 C13H15O+ 1 187.1117 -0.57
187.1356 C13H17N+ 1 187.1356 0.3
188.1433 C13H18N+ 1 188.1434 -0.41
189.1276 C13H17O+ 1 189.1274 0.85
190.1227 C12H16NO+ 1 190.1226 0.56
191.0853 C15H11+ 1 191.0855 -1.01
193.1012 C15H13+ 1 193.1012 0
195.0803 C14H11O+ 1 195.0804 -0.54
195.117 C15H15+ 1 195.1168 0.75
197.0961 C14H13O+ 1 197.0961 0.22
197.1325 C15H17+ 1 197.1325 0.33
198.1039 C14H14O+ 1 198.1039 -0.22
198.1276 C14H16N+ 1 198.1277 -0.79
199.1117 C14H15O+ 1 199.1117 -0.04
199.1354 C14H17N+ 1 199.1356 -0.6
200.1196 C14H16O+ 1 200.1196 0.37
200.1432 C14H18N+ 1 200.1434 -0.8
201.1273 C14H17O+ 1 201.1274 -0.37
202.1225 C13H16NO+ 1 202.1226 -0.48
205.1011 C16H13+ 1 205.1012 -0.38
207.1169 C16H15+ 1 207.1168 0.12
208.1238 C16H16+ 1 208.1247 -3.89
209.0958 C15H13O+ 1 209.0961 -1.46
209.1322 C16H17+ 1 209.1325 -1.29
210.1042 C15H14O+ 1 210.1039 1.11
210.1277 C15H16N+ 1 210.1277 -0.08
211.1117 C15H15O+ 1 211.1117 -0.31
211.1354 C15H17N+ 1 211.1356 -0.63
212.1193 C15H16O+ 1 212.1196 -1.29
212.1433 C15H18N+ 1 212.1434 -0.45
213.1274 C15H17O+ 1 213.1274 -0.04
213.1511 C15H19N+ 1 213.1512 -0.56
214.1225 C14H16NO+ 1 214.1226 -0.64
214.1348 C15H18O+ 1 214.1352 -2.07
214.1589 C15H20N+ 1 214.159 -0.53
215.1066 C14H15O2+ 1 215.1067 -0.29
215.1433 C15H19O+ 1 215.143 1.01
217.1009 C17H13+ 1 217.1012 -1.31
219.1171 C17H15+ 1 219.1168 1.2
220.124 C17H16+ 1 220.1247 -2.94
221.096 C16H13O+ 1 221.0961 -0.44
221.1324 C17H17+ 1 221.1325 -0.14
222.1278 C16H16N+ 1 222.1277 0.38
223.1117 C16H15O+ 1 223.1117 0.03
223.1363 C16H17N+ 1 223.1356 3.15
223.148 C17H19+ 1 223.1481 -0.35
224.1436 C16H18N+ 1 224.1434 1.12
225.1273 C16H17O+ 1 225.1274 -0.53
225.1511 C16H19N+ 1 225.1512 -0.28
226.1225 C15H16NO+ 1 226.1226 -0.55
226.159 C16H20N+ 1 226.159 0.02
227.1308 C15H17NO+ 1 227.1305 1.36
227.1428 C16H19O+ 1 227.143 -0.94
228.1378 C15H18NO+ 1 228.1383 -2.23
228.1748 C16H22N+ 1 228.1747 0.61
229.1222 C15H17O2+ 1 229.1223 -0.64
231.1173 C18H15+ 1 231.1168 1.85
232.1247 C18H16+ 1 232.1247 0.42
233.1322 C18H17+ 1 233.1325 -1.19
234.1037 C17H14O+ 1 234.1039 -0.99
234.1277 C17H16N+ 1 234.1277 0.09
234.1402 C18H18+ 1 234.1403 -0.44
235.1116 C17H15O+ 1 235.1117 -0.7
235.1354 C17H17N+ 1 235.1356 -0.79
235.1481 C18H19+ 1 235.1481 -0.16
236.1199 C17H16O+ 1 236.1196 1.46
236.1433 C17H18N+ 1 236.1434 -0.37
237.1274 C17H17O+ 1 237.1274 0.13
237.151 C17H19N+ 1 237.1512 -0.73
237.1631 C18H21+ 1 237.1638 -3.06
238.1236 C16H16NO+ 1 238.1226 4.14
238.1589 C17H20N+ 1 238.159 -0.64
239.1066 C16H15O2+ 1 239.1067 -0.17
239.1428 C17H19O+ 1 239.143 -0.91
239.1663 C17H21N+ 1 239.1669 -2.33
240.1384 C16H18NO+ 1 240.1383 0.28
240.1746 C17H22N+ 1 240.1747 -0.39
241.1221 C16H17O2+ 1 241.1223 -0.69
241.1455 C16H19NO+ 1 241.1461 -2.42
241.1586 C17H21O+ 1 241.1587 -0.21
242.1538 C16H20NO+ 1 242.1539 -0.56
243.1379 C16H19O2+ 1 243.138 -0.07
243.1618 C16H21NO+ 1 243.1618 -0.03
244.1697 C16H22NO+ 1 244.1696 0.25
245.1322 C19H17+ 1 245.1325 -1.22
247.1486 C19H19+ 1 247.1481 1.75
248.1203 C18H16O+ 1 248.1196 3.15
248.1432 C18H18N+ 1 248.1434 -0.75
249.1272 C18H17O+ 1 249.1274 -0.76
249.152 C18H19N+ 1 249.1512 3.14
249.1636 C19H21+ 1 249.1638 -0.85
250.1356 C18H18O+ 1 250.1352 1.53
250.1593 C18H20N+ 1 250.159 0.95
251.1429 C18H19O+ 1 251.143 -0.4
251.1657 C18H21N+ 1 251.1669 -4.61
252.1379 C17H18NO+ 1 252.1383 -1.39
252.1745 C18H22N+ 1 252.1747 -0.88
253.1227 C17H17O2+ 1 253.1223 1.49
253.1454 C17H19NO+ 1 253.1461 -2.81
253.1588 C18H21O+ 1 253.1587 0.55
254.1292 C17H18O2+ 1 254.1301 -3.72
254.1536 C17H20NO+ 1 254.1539 -1.28
254.1909 C18H24N+ 1 254.1903 2.17
255.1378 C17H19O2+ 1 255.138 -0.69
256.1691 C17H22NO+ 1 256.1696 -1.82
257.1539 C17H21O2+ 1 257.1536 1.26
262.1353 C19H18O+ 1 262.1352 0.44
262.1588 C19H20N+ 1 262.159 -0.98
263.1432 C19H19O+ 1 263.143 0.52
263.1667 C19H21N+ 1 263.1669 -0.55
263.1791 C20H23+ 1 263.1794 -1.26
264.1746 C19H22N+ 1 264.1747 -0.47
265.1443 C18H19NO+ 1 265.1461 -6.91
265.1587 C19H21O+ 1 265.1587 0.21
265.1826 C19H23N+ 1 265.1825 0.19
266.1537 C18H20NO+ 1 266.1539 -0.73
266.1673 C19H22O+ 1 266.1665 2.93
266.1899 C19H24N+ 1 266.1903 -1.57
267.161 C18H21NO+ 1 267.1618 -2.82
267.1744 C19H23O+ 1 267.1743 0.25
268.1695 C18H22NO+ 1 268.1696 -0.46
269.1534 C18H21O2+ 1 269.1536 -0.7
273.1643 C21H21+ 1 273.1638 2
274.1591 C20H20N+ 1 274.159 0.3
275.1668 C20H21N+ 1 275.1669 -0.07
276.1748 C20H22N+ 1 276.1747 0.33
277.1455 C19H19NO+ 1 277.1461 -2.32
278.1541 C19H20NO+ 1 278.1539 0.73
278.1902 C20H24N+ 1 278.1903 -0.51
279.1615 C19H21NO+ 1 279.1618 -1.06
280.1694 C19H22NO+ 1 280.1696 -0.77
281.1759 C19H23NO+ 1 281.1774 -5.47
281.1908 C20H25O+ 1 281.19 2.88
282.1852 C19H24NO+ 1 282.1852 -0.3
283.1692 C19H23O2+ 1 283.1693 -0.1
284.201 C19H26NO+ 1 284.2009 0.49
286.1583 C21H20N+ 1 286.159 -2.62
287.1676 C21H21N+ 1 287.1669 2.77
288.1744 C21H22N+ 1 288.1747 -0.87
290.1904 C21H24N+ 1 290.1903 0.11
291.1743 C21H23O+ 1 291.1743 -0.02
292.1697 C20H22NO+ 1 292.1696 0.37
294.1853 C20H24NO+ 1 294.1852 0.19
296.2005 C20H26NO+ 1 296.2009 -1.33
301.1824 C22H23N+ 1 301.1825 -0.21
302.1901 C22H24N+ 1 302.1903 -0.76
304.1687 C21H22NO+ 1 304.1696 -2.91
304.2069 C22H26N+ 1 304.206 3.19
305.1764 C21H23NO+ 1 305.1774 -3.33
306.1845 C21H24NO+ 1 306.1852 -2.56
307.1933 C21H25NO+ 1 307.1931 0.89
308.2011 C21H26NO+ 1 308.2009 0.55
309.1848 C21H25O2+ 1 309.1849 -0.26
312.1749 C23H22N+ 1 312.1747 0.75
314.1903 C23H24N+ 1 314.1903 -0.2
316.1689 C22H22NO+ 1 316.1696 -2.27
317.1767 C22H23NO+ 1 317.1774 -2.2
318.1855 C22H24NO+ 1 318.1852 0.74
319.1933 C22H25NO+ 1 319.1931 0.61
320.2007 C22H26NO+ 1 320.2009 -0.67
328.2059 C24H26N+ 1 328.206 -0.13
329.1769 C23H23NO+ 1 329.1774 -1.53
329.2121 C24H27N+ 1 329.2138 -5.17
330.1847 C23H24NO+ 1 330.1852 -1.65
331.193 C23H25NO+ 1 331.1931 -0.2
332.2006 C23H26NO+ 1 332.2009 -0.88
333.2083 C23H27NO+ 1 333.2087 -1.19
334.2169 C23H28NO+ 1 334.2165 1.16
339.198 C25H25N+ 1 339.1982 -0.32
344.2016 C24H26NO+ 1 344.2009 2.12
345.2091 C24H27NO+ 1 345.2087 1.02
346.2165 C24H28NO+ 1 346.2165 -0.07
348.2321 C24H30NO+ 1 348.2322 -0.23
354.222 C26H28N+ 1 354.2216 1.02
357.2084 C25H27NO+ 1 357.2087 -1.02
358.2172 C25H28NO+ 1 358.2165 1.93
359.2255 C25H29NO+ 1 359.2244 3.17
360.2321 C25H30NO+ 1 360.2322 -0.34
372.2322 C26H30NO+ 1 372.2322 -0.04
390.243 C26H32NO2+ 1 390.2428 0.55
397.2394 C28H31NO+ 1 397.24 -1.45
400.2274 C27H30NO2+ 1 400.2271 0.78
412.2634 C29H34NO+ 1 412.2635 -0.27
415.2505 C28H33NO2+ 1 415.2506 -0.11
430.2741 C29H36NO2+ 1 430.2741 0.17
PK$NUM_PEAK: 273
PK$PEAK: m/z int. rel.int.
55.0178 8280 7
55.0542 4129 3
57.0335 3492.3 3
67.0541 7960.7 7
69.0334 4675 4
69.0698 9357.4 8
79.0542 11253.2 9
81.0698 22616.9 19
83.049 9046.6 7
85.0648 3538 3
91.054 18636.5 16
93.0699 48059 42
95.0492 9895.3 8
95.0855 29225.8 25
97.0647 59100.9 52
105.0699 28467.5 25
107.0491 16522.5 14
107.0729 11616.5 10
107.0855 42097.6 37
109.0647 39352.1 34
109.101 12668.7 11
111.0803 8098.4 7
117.0699 20412.1 18
119.0855 92739.5 81
120.0808 33578.6 29
121.0646 15790.1 13
121.0886 153664.8 135
121.1011 50209.4 44
122.0963 271337.4 239
123.0804 40174.7 35
125.0961 21357.2 18
129.0698 31027.4 27
131.0856 42018.7 37
132.0808 9228.3 8
133.0648 55633.6 49
133.0891 2903.1 2
133.1012 42141.5 37
134.0963 935085.4 826
135.0804 129685.3 114
136.112 3936.2 3
137.0961 36229.4 32
141.0697 10987.9 9
143.0854 31684.8 28
145.0649 14238.8 12
145.1011 76907.9 67
146.0965 21774.7 19
147.0803 88634 78
147.1043 14388 12
147.1166 11040.1 9
148.0756 61374.6 54
148.112 267868.7 236
149.096 86009.7 76
150.0913 8268.5 7
151.075 3749.9 3
155.0853 25902.9 22
157.0649 31322.5 27
157.0883 2978.8 2
157.1012 26001.1 22
158.0961 15070.7 13
159.0804 133984.2 118
159.1045 15883.3 14
159.1167 17613.6 15
160.112 162276.3 143
161.096 145707.4 128
161.12 17880.7 15
162.1277 109566.3 96
163.1116 44517.2 39
167.0858 15492.3 13
169.1011 29870.5 26
171.0805 14966.8 13
171.1041 9807.1 8
171.1165 18662.4 16
172.112 100395.1 88
173.0961 150529.9 133
173.1197 39051.4 34
174.1277 100056.2 88
175.1118 30756.4 27
175.1354 44977.2 39
176.1434 7659.7 6
179.0855 7812.2 6
181.1012 26697.4 23
183.0803 13292 11
183.1168 20477.4 18
184.1121 17383.8 15
185.0961 54380.1 48
185.1198 20754.5 18
185.1321 9334.2 8
186.1276 120456.2 106
187.1116 66170.7 58
187.1356 39296 34
188.1433 137469.3 121
189.1276 8711.9 7
190.1227 5870.2 5
191.0853 4724.4 4
193.1012 19556 17
195.0803 7094.1 6
195.117 23852.4 21
197.0961 42669.8 37
197.1325 11590.8 10
198.1039 5374.4 4
198.1276 33655 29
199.1117 64229.6 56
199.1354 18261.4 16
200.1196 4796.8 4
200.1432 28427.4 25
201.1273 15355.4 13
202.1225 4018.8 3
205.1011 7088.9 6
207.1169 28370.1 25
208.1238 2974.3 2
209.0958 34866.7 30
209.1322 26500.4 23
210.1042 4189.7 3
210.1277 9912.2 8
211.1117 85465.6 75
211.1354 8976.5 7
212.1193 3573.1 3
212.1433 40181.7 35
213.1274 68061.1 60
213.1511 28497.9 25
214.1225 7540.8 6
214.1348 3132.7 2
214.1589 58514.7 51
215.1066 39060.3 34
215.1433 6014.3 5
217.1009 5044.2 4
219.1171 10629.4 9
220.124 4078.6 3
221.096 8486.9 7
221.1324 20385.6 18
222.1278 10059.9 8
223.1117 53977 47
223.1363 6767.9 5
223.148 17316.3 15
224.1436 33649.1 29
225.1273 79179.7 69
225.1511 9414.6 8
226.1225 6326.4 5
226.159 27523.9 24
227.1308 4887.1 4
227.1428 56092.3 49
228.1378 14296.9 12
228.1748 3733.4 3
229.1222 4026.5 3
231.1173 4990.6 4
232.1247 3502.4 3
233.1322 16596.5 14
234.1037 3482.1 3
234.1277 3201.8 2
234.1402 4376.2 3
235.1116 21501.7 19
235.1354 5833.6 5
235.1481 15857.2 14
236.1199 7682 6
236.1433 114577.2 101
237.1274 39214.6 34
237.151 12542.7 11
237.1631 5228.7 4
238.1236 3402.4 3
238.1589 55826.3 49
239.1066 11295.2 9
239.1428 21095.9 18
239.1663 10647.6 9
240.1384 17182.7 15
240.1746 64797.5 57
241.1221 8667.1 7
241.1455 5745.3 5
241.1586 10220 9
242.1538 76022.2 67
243.1379 24902.2 22
243.1618 4559.3 4
244.1697 8300.5 7
245.1322 5354.4 4
247.1486 7515.3 6
248.1203 3578 3
248.1432 4628.9 4
249.1272 29562.1 26
249.152 14285.7 12
249.1636 22862.5 20
250.1356 6117.3 5
250.1593 23452.9 20
251.1429 85493.7 75
251.1657 20499.6 18
252.1379 6833.9 6
252.1745 12175.8 10
253.1227 7593.5 6
253.1454 6727.7 5
253.1588 12619.6 11
254.1292 3471.8 3
254.1536 10802.2 9
254.1909 8273 7
255.1378 11193.8 9
256.1691 31403.2 27
257.1539 6073.8 5
262.1353 11175.8 9
262.1588 14187.2 12
263.1432 30289.2 26
263.1667 10943.4 9
263.1791 6394.6 5
264.1746 80656.1 71
265.1443 5831.6 5
265.1587 58036 51
265.1826 3494.1 3
266.1537 8481.3 7
266.1673 5001.3 4
266.1899 56006.3 49
267.161 11032.6 9
267.1744 31941.7 28
268.1695 38865.6 34
269.1534 219762.5 194
273.1643 7888.2 6
274.1591 12334.7 10
275.1668 3946.7 3
276.1748 12655.2 11
277.1455 3549.5 3
278.1541 10060.5 8
278.1902 39320.1 34
279.1615 10877.2 9
280.1694 149370.5 132
281.1759 36095.4 31
281.1908 8177.4 7
282.1852 85971.8 75
283.1692 22207.2 19
284.201 12220.7 10
286.1583 3855.9 3
287.1676 3478.2 3
288.1744 63886.2 56
290.1904 15456.3 13
291.1743 80572 71
292.1697 10570.2 9
294.1853 24391 21
296.2005 35663.9 31
301.1824 9734.1 8
302.1901 19580 17
304.1687 5513.2 4
304.2069 5147.7 4
305.1764 6023.5 5
306.1845 36858.2 32
307.1933 5658.1 5
308.2011 29501.9 26
309.1848 125219.3 110
312.1749 4533.1 4
314.1903 11228.2 9
316.1689 4380.6 3
317.1767 6964.2 6
318.1855 9166 8
319.1933 10262.2 9
320.2007 18607.5 16
328.2059 4741.4 4
329.1769 3452.3 3
329.2121 2781.8 2
330.1847 5928.2 5
331.193 10732.4 9
332.2006 73092.8 64
333.2083 9005.2 7
334.2169 14119.7 12
339.198 4073.7 3
344.2016 6794.6 6
345.2091 3907.5 3
346.2165 35184.8 31
348.2321 45245.2 39
354.222 18895.5 16
357.2084 9699.4 8
358.2172 10017.3 8
359.2255 13151.5 11
360.2321 65310 57
372.2322 964421.8 852
390.243 31768.2 28
397.2394 20484.7 18
400.2274 5811.4 5
412.2634 110948.1 98
415.2505 271506.2 239
430.2741 1130203.6 999
//
