ACCESSION: MSBNK-LCSB-LU097106
RECORD_TITLE: Brucine; LC-ESI-QFT; MS2; CE: 90; R=17500; [M+H]+
DATE: 2020.08.19
AUTHORS: Elapavalore, A.; Kondić, T.; Singh, R.; Schymanski, E.
LICENSE: CC BY
COPYRIGHT: Copyright © 2019 by Environmental Cheminformatics, LCSB, University of Luxembourg, Luxembourg
PUBLICATION: Elapavalore, A.; Kondić, T.; et al., Adding Open Spectral Data to MassBank and PubChem Using Open Source Tools to Support Non-Targeted Exposomics of Mixtures (submitted).
PROJECT: ENTACT U.S. Environmental Protection Agency’s Non-Targeted Analysis Collaborative Trial
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 971
COMMENT: DATASET 20200303_ENTACT_RP_MIX502
COMMENT: DATA_PROCESSING MERGING RMBmix ver. 0.2.7
COMMENT: DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0
COMMENT: ORIGINAL_ACQUISITION_NO 5841
COMMENT: ORIGINAL_PRECURSOR_SCAN_NO 5839
COMMENT: RAW_DATA available as MSV000091754 at [DOI:10.25345/C5S46HG75]
CH$NAME: Brucine
CH$NAME: (4aR,5aS,8aR,13aS,15aS,15bR)-10,11-dimethoxy-4a,5,5a,7,8,13a,15,15a,15b,16-decahydro-2H-4,6-methanoindolo[3,2,1-ij]oxepino[2,3,4-de]pyrrolo[2,3-h]quinolin-14-one
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C23H26N2O4
CH$EXACT_MASS: 394.1893
CH$SMILES: COC1=CC2=C(C=C1OC)[C@@]13CCN4CC5=CCO[C@H]6CC(=O)N2[C@H]1[C@H]6[C@H]5C[C@@H]34
CH$IUPAC: InChI=1S/C23H26N2O4/c1-27-16-8-14-15(9-17(16)28-2)25-20(26)10-18-21-13-7-19-23(14,22(21)25)4-5-24(19)11-12(13)3-6-29-18/h3,8-9,13,18-19,21-22H,4-7,10-11H2,1-2H3/t13-,18-,19-,21-,22-,23+/m0/s1
CH$LINK: CAS
357-57-3
CH$LINK: CHEBI
3193
CH$LINK: KEGG
C09084
CH$LINK: PUBCHEM
CID:442021
CH$LINK: INCHIKEY
RRKTZKIUPZVBMF-IBTVXLQLSA-N
CH$LINK: CHEMSPIDER
390579
AC$INSTRUMENT: Q Exactive Orbitrap (Thermo Scientific)
AC$INSTRUMENT_TYPE: LC-ESI-QFT
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 90
AC$MASS_SPECTROMETRY: RESOLUTION 17500
AC$CHROMATOGRAPHY: COLUMN_NAME Acquity BEH C18 1.7um, 2.1x150mm (Waters)
AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0-2 min, 0/100 at 15-20 min, 90/10 at 20.1-30 min
AC$CHROMATOGRAPHY: FLOW_RATE 0.20 mL/min
AC$CHROMATOGRAPHY: RETENTION_TIME 11.177 min
AC$CHROMATOGRAPHY: SOLVENT A 0.1% formic acid
AC$CHROMATOGRAPHY: SOLVENT B methanol
MS$FOCUSED_ION: BASE_PEAK 79.0211
MS$FOCUSED_ION: PRECURSOR_M/Z 395.1965
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$FOCUSED_ION: PRECURSOR_INTENSITY 8191074
MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1
MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included
MS$DATA_PROCESSING: WHOLE RMassBank 2.99.2
PK$SPLASH: splash10-01w1-2980000000-75ba2eb088e1431c3b0a
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
53.0386 C4H5+ 1 53.0386 0.95
55.0179 C3H3O+ 1 55.0178 0.39
55.0543 C4H7+ 1 55.0542 0.79
56.0495 C3H6N+ 1 56.0495 0.25
65.0385 C5H5+ 1 65.0386 -1.53
66.0464 C5H6+ 1 66.0464 -0.34
67.0416 C4H5N+ 1 67.0417 -1.2
67.0542 C5H7+ 1 67.0542 -0.44
68.0494 C4H6N+ 1 68.0495 -0.95
69.0334 C4H5O+ 1 69.0335 -1.73
70.0651 C4H8N+ 1 70.0651 -1
77.0385 C6H5+ 1 77.0386 -0.39
78.0335 C5H4N+ 1 78.0338 -3.94
79.0542 C6H7+ 1 79.0542 -0.88
80.0494 C5H6N+ 1 80.0495 -0.36
81.0335 C5H5O+ 1 81.0335 -0.5
81.0573 C5H7N+ 1 81.0573 -0.19
81.0699 C6H9+ 1 81.0699 -0.32
82.0651 C5H8N+ 1 82.0651 -0.69
83.0489 C5H7O+ 1 83.0491 -2.85
84.0445 C4H6NO+ 1 84.0444 1.37
91.0542 C7H7+ 1 91.0542 0.2
92.0495 C6H6N+ 1 92.0495 0.09
93.0573 C6H7N+ 1 93.0573 0.36
93.0698 C7H9+ 1 93.0699 -0.57
94.0652 C6H8N+ 1 94.0651 0.38
95.0492 C6H7O+ 1 95.0491 0.15
95.073 C6H9N+ 1 95.073 0.49
95.0855 C7H11+ 1 95.0855 -0.43
96.0444 C5H6NO+ 1 96.0444 -0.28
96.0807 C6H10N+ 1 96.0808 -0.61
98.06 C5H8NO+ 1 98.06 -0.23
103.0541 C8H7+ 1 103.0542 -0.85
104.0494 C7H6N+ 1 104.0495 -1.07
105.0447 C6H5N2+ 1 105.0447 -0.19
105.07 C8H9+ 1 105.0699 0.99
106.0651 C7H8N+ 1 106.0651 0.11
107.0493 C7H7O+ 1 107.0491 1.27
107.0729 C7H9N+ 1 107.073 -0.42
107.0853 C8H11+ 1 107.0855 -1.73
108.0808 C7H10N+ 1 108.0808 0.04
109.0648 C7H9O+ 1 109.0648 0.13
110.0599 C6H8NO+ 1 110.06 -1.19
115.0541 C9H7+ 1 115.0542 -1.07
117.0573 C8H7N+ 1 117.0573 -0.17
117.0698 C9H9+ 1 117.0699 -0.26
118.0651 C8H8N+ 1 118.0651 -0.33
119.0731 C8H9N+ 1 119.073 0.92
119.0855 C9H11+ 1 119.0855 -0.13
120.0443 C7H6NO+ 1 120.0444 -1.14
120.0809 C8H10N+ 1 120.0808 1.07
121.0522 C7H7NO+ 1 121.0522 -0.09
121.0648 C8H9O+ 1 121.0648 0.27
122.06 C7H8NO+ 1 122.06 -0.05
122.0964 C8H12N+ 1 122.0964 0.13
124.0757 C7H10NO+ 1 124.0757 0.38
128.0621 C10H8+ 1 128.0621 0.66
129.0699 C10H9+ 1 129.0699 0.32
130.0652 C9H8N+ 1 130.0651 0.83
131.0491 C9H7O+ 1 131.0491 -0.4
131.073 C9H9N+ 1 131.073 0.61
131.0852 C10H11+ 1 131.0855 -2.21
132.0445 C8H6NO+ 1 132.0444 0.8
132.0808 C9H10N+ 1 132.0808 0.16
133.0522 C8H7NO+ 1 133.0522 -0.45
134.06 C8H8NO+ 1 134.06 0.03
134.0963 C9H12N+ 1 134.0964 -0.83
142.0652 C10H8N+ 1 142.0651 0.21
143.073 C10H9N+ 1 143.073 0.55
144.0568 C10H8O+ 1 144.057 -1.4
144.0808 C10H10N+ 1 144.0808 -0.17
145.0525 C9H7NO+ 1 145.0522 1.81
145.0647 C10H9O+ 1 145.0648 -0.63
146.06 C9H8NO+ 1 146.06 0.04
147.0679 C9H9NO+ 1 147.0679 0.48
148.0394 C8H6NO2+ 1 148.0393 0.35
148.0757 C9H10NO+ 1 148.0757 0.19
154.0651 C11H8N+ 1 154.0651 -0.04
155.0728 C11H9N+ 1 155.073 -0.81
156.0808 C11H10N+ 1 156.0808 0.39
158.0601 C10H8NO+ 1 158.06 0.29
158.0726 C11H10O+ 1 158.0726 -0.01
159.0679 C10H9NO+ 1 159.0679 0.12
160.0757 C10H10NO+ 1 160.0757 0.15
161.0471 C9H7NO2+ 1 161.0471 0.03
161.0834 C10H11NO+ 1 161.0835 -0.49
162.0549 C9H8NO2+ 1 162.055 -0.13
163.0628 C9H9NO2+ 1 163.0628 0.07
164.07 C9H10NO2+ 1 164.0706 -3.72
167.0729 C12H9N+ 1 167.073 -0.07
168.0808 C12H10N+ 1 168.0808 0.22
169.0522 C11H7NO+ 1 169.0522 -0.17
170.06 C11H8NO+ 1 170.06 0.03
171.0678 C11H9NO+ 1 171.0679 -0.14
172.0757 C11H10NO+ 1 172.0757 -0.21
173.0838 C11H11NO+ 1 173.0835 1.39
174.055 C10H8NO2+ 1 174.055 0.22
174.0676 C11H10O2+ 1 174.0675 0.11
174.0915 C11H12NO+ 1 174.0913 0.96
175.0628 C10H9NO2+ 1 175.0628 0.32
176.0705 C10H10NO2+ 1 176.0706 -0.71
177.0784 C10H11NO2+ 1 177.0784 -0.43
178.0863 C10H12NO2+ 1 178.0863 0.27
180.0809 C13H10N+ 1 180.0808 0.7
182.0601 C12H8NO+ 1 182.06 0.43
183.068 C12H9NO+ 1 183.0679 0.53
184.0758 C12H10NO+ 2 184.0757 0.38
185.0836 C12H11NO+ 2 185.0835 0.23
186.055 C11H8NO2+ 1 186.055 0.21
186.0914 C12H12NO+ 2 186.0913 0.49
187.0628 C11H9NO2+ 1 187.0628 0.06
187.0868 C11H11N2O+ 1 187.0866 1.09
188.0707 C11H10NO2+ 1 188.0706 0.65
189.0784 C11H11NO2+ 1 189.0784 -0.38
189.0912 C12H13O2+ 1 189.091 1.05
190.0862 C11H12NO2+ 1 190.0863 -0.52
191.073 C14H9N+ 2 191.073 0.28
192.0658 C10H10NO3+ 2 192.0655 1.64
192.0808 C14H10N+ 2 192.0808 0.3
193.089 C14H11N+ 1 193.0886 1.99
194.0601 C13H8NO+ 2 194.06 0.31
194.0963 C14H12N+ 2 194.0964 -0.44
195.0677 C13H9NO+ 2 195.0679 -0.84
196.0758 C13H10NO+ 2 196.0757 0.75
197.0473 C12H7NO2+ 1 197.0471 0.74
197.0835 C13H11NO+ 2 197.0835 -0.08
198.055 C12H8NO2+ 1 198.055 0.38
198.0909 C13H12NO+ 2 198.0913 -2.05
199.063 C12H9NO2+ 1 199.0628 1.17
199.0994 C13H13NO+ 2 199.0992 1.05
200.0707 C12H10NO2+ 1 200.0706 0.27
201.0784 C12H11NO2+ 1 201.0784 -0.24
202.0501 C11H8NO3+ 2 202.0499 0.97
202.0861 C12H12NO2+ 1 202.0863 -0.89
204.0648 C11H10NO3+ 1 204.0655 -3.33
204.0808 C15H10N+ 2 204.0808 0.12
204.1021 C12H14NO2+ 1 204.1019 1.04
206.0599 C14H8NO+ 2 206.06 -0.45
206.0813 C14H10N2+ 2 206.0838 -12.25
206.0865 C14H10N2+ 1 206.0838 12.63
206.0965 C15H12N+ 2 206.0964 0.4
207.0679 C14H9NO+ 2 207.0679 0.39
208.0758 C14H10NO+ 2 208.0757 0.35
208.1122 C15H14N+ 2 208.1121 0.74
209.0837 C14H11NO+ 2 209.0835 1.1
210.055 C13H8NO2+ 1 210.055 0.37
210.0914 C14H12NO+ 2 210.0913 0.25
211.063 C13H9NO2+ 1 211.0628 0.83
211.0995 C14H13NO+ 2 211.0992 1.44
212.0706 C13H10NO2+ 1 212.0706 -0.01
213.0784 C13H11NO2+ 1 213.0784 -0.13
214.0499 C12H8NO3+ 2 214.0499 0.16
214.0859 C13H12NO2+ 1 214.0863 -1.59
215.0577 C12H9NO3+ 2 215.0577 0.25
215.0817 C12H11N2O2+ 1 215.0815 1.01
215.0944 C13H13NO2+ 1 215.0941 1.71
216.102 C13H14NO2+ 1 216.1019 0.24
217.0886 C16H11N+ 2 217.0886 0.18
218.0964 C16H12N+ 2 218.0964 0
219.0678 C15H9NO+ 2 219.0679 -0.42
219.1043 C16H13N+ 2 219.1043 0.03
220.0756 C15H10NO+ 2 220.0757 -0.32
220.1125 C16H14N+ 2 220.1121 1.86
221.0835 C15H11NO+ 2 221.0835 -0.09
222.0548 C14H8NO2+ 1 222.055 -0.5
222.0914 C15H12NO+ 2 222.0913 0.08
223.099 C15H13NO+ 2 223.0992 -0.58
224.0707 C14H10NO2+ 1 224.0706 0.51
224.1069 C15H14NO+ 2 224.107 -0.21
225.0788 C14H11NO2+ 1 225.0784 1.49
226.0502 C13H8NO3+ 2 226.0499 1.48
226.0863 C14H12NO2+ 1 226.0863 0.09
227.0585 C13H9NO3+ 2 227.0577 3.58
227.0939 C14H13NO2+ 1 227.0941 -0.89
228.0656 C13H10NO3+ 2 228.0655 0.38
228.1016 C14H14NO2+ 1 228.1019 -1.13
229.0734 C13H11NO3+ 2 229.0733 0.28
230.0814 C13H12NO3+ 2 230.0812 1.1
230.0965 C17H12N+ 2 230.0964 0.25
232.0756 C16H10NO+ 2 232.0757 -0.45
232.1125 C17H14N+ 2 232.1121 1.94
233.0835 C16H11NO+ 2 233.0835 -0.16
234.0553 C15H8NO2+ 1 234.055 1.6
234.0914 C16H12NO+ 2 234.0913 0.19
235.0635 C15H9NO2+ 1 235.0628 3.11
235.0992 C16H13NO+ 2 235.0992 0.02
236.0707 C15H10NO2+ 1 236.0706 0.41
236.1069 C16H14NO+ 2 236.107 -0.4
237.0785 C15H11NO2+ 1 237.0784 0.43
237.1146 C16H15NO+ 2 237.1148 -0.95
238.0863 C15H12NO2+ 1 238.0863 0.2
239.0938 C15H13NO2+ 1 239.0941 -0.99
240.0652 C14H10NO3+ 2 240.0655 -1.37
240.1016 C15H14NO2+ 1 240.1019 -1.47
241.074 C14H11NO3+ 2 241.0733 2.52
242.0815 C14H12NO3+ 2 242.0812 1.34
243.0529 C13H9NO4+ 2 243.0526 1.27
243.0892 C14H13NO3+ 2 243.089 0.67
244.0971 C14H14NO3+ 2 244.0968 1.07
246.0549 C16H8NO2+ 1 246.055 -0.11
246.0917 C17H12NO+ 2 246.0913 1.46
247.0628 C16H9NO2+ 1 247.0628 -0.03
247.0992 C17H13NO+ 2 247.0992 -0.06
248.0704 C16H10NO2+ 1 248.0706 -0.8
248.1072 C17H14NO+ 2 248.107 0.7
249.0782 C16H11NO2+ 1 249.0784 -0.77
249.102 C16H13N2O+ 2 249.1022 -1.04
249.1152 C17H15NO+ 2 249.1148 1.46
250.0502 C15H8NO3+ 2 250.0499 1.18
250.0863 C16H12NO2+ 1 250.0863 0.11
250.1227 C17H16NO+ 2 250.1226 0.38
251.0941 C16H13NO2+ 1 251.0941 0.25
252.0655 C15H10NO3+ 2 252.0655 -0.18
252.1022 C16H14NO2+ 1 252.1019 1.06
254.0819 C15H12NO3+ 2 254.0812 2.99
254.1176 C16H16NO2+ 1 254.1176 0.14
256.0968 C15H14NO3+ 2 256.0968 0.04
258.0909 C18H12NO+ 2 258.0913 -1.53
259.0979 C18H13NO+ 2 259.0992 -4.74
260.0712 C17H10NO2+ 1 260.0706 2.2
260.1072 C18H14NO+ 2 260.107 0.64
261.0781 C17H11NO2+ 1 261.0784 -1.35
261.1157 C18H15NO+ 2 261.1148 3.41
262.0861 C17H12NO2+ 1 262.0863 -0.57
262.1222 C18H16NO+ 2 262.1226 -1.76
263.0942 C17H13NO2+ 1 263.0941 0.56
264.0655 C16H10NO3+ 2 264.0655 -0.14
264.1021 C17H14NO2+ 1 264.1019 0.75
265.0738 C16H11NO3+ 2 265.0733 1.67
265.0964 C16H13N2O2+ 1 265.0972 -2.84
265.1102 C17H15NO2+ 1 265.1097 1.86
266.0813 C16H12NO3+ 2 266.0812 0.59
266.1176 C17H16NO2+ 1 266.1176 -0.01
267.0893 C16H13NO3+ 2 267.089 1.13
268.0974 C16H14NO3+ 2 268.0968 2.34
272.1069 C19H14NO+ 2 272.107 -0.38
273.0785 C18H11NO2+ 1 273.0784 0.29
274.0867 C18H12NO2+ 1 274.0863 1.58
274.1238 C19H16NO+ 2 274.1226 4.34
275.0945 C18H13NO2+ 1 275.0941 1.43
276.1013 C18H14NO2+ 1 276.1019 -2.37
277.0951 C17H13N2O2+ 1 277.0972 -7.56
277.1102 C18H15NO2+ 1 277.1097 1.68
278.0811 C17H12NO3+ 2 278.0812 -0.31
278.1176 C18H16NO2+ 1 278.1176 0.21
279.1122 C17H15N2O2+ 1 279.1128 -2.01
280.0973 C17H14NO3+ 2 280.0968 1.8
286.0861 C19H12NO2+ 1 286.0863 -0.42
288.1013 C19H14NO2+ 1 288.1019 -1.98
290.0822 C18H12NO3+ 2 290.0812 3.56
290.118 C19H16NO2+ 1 290.1176 1.64
292.0971 C18H14NO3+ 2 292.0968 0.85
294.1125 C18H16NO3+ 2 294.1125 -0.06
301.1117 C20H15NO2+ 1 301.1097 6.43
304.0967 C19H14NO3+ 2 304.0968 -0.54
306.1126 C19H16NO3+ 2 306.1125 0.38
316.0969 C20H14NO3+ 2 316.0968 0.1
337.1551 C20H21N2O3+ 1 337.1547 1.29
379.1671 C22H23N2O4+ 1 379.1652 4.98
PK$NUM_PEAK: 259
PK$PEAK: m/z int. rel.int.
53.0386 43377.6 92
55.0179 46238.5 99
55.0543 10347.8 22
56.0495 36321.8 77
65.0385 19868 42
66.0464 3950.2 8
67.0416 17635.9 37
67.0542 42823.3 91
68.0494 34026.1 72
69.0334 9073.5 19
70.0651 16765.7 35
77.0385 7979 17
78.0335 3581.4 7
79.0542 90228.9 193
80.0494 107736.9 230
81.0335 10964.4 23
81.0573 20651.4 44
81.0699 32270.1 69
82.0651 16800.3 35
83.0489 3954.1 8
84.0445 3486.2 7
91.0542 95784.3 205
92.0495 15357.9 32
93.0573 159672.2 341
93.0698 19059.4 40
94.0652 61338 131
95.0492 69333.2 148
95.073 5242.6 11
95.0855 4025.9 8
96.0444 17384 37
96.0807 24334.4 52
98.06 4170 8
103.0541 16355.2 35
104.0494 6763.9 14
105.0447 17859.5 38
105.07 17107.3 36
106.0651 145753.1 312
107.0493 6091.2 13
107.0729 12722.5 27
107.0853 3818.5 8
108.0808 42759.3 91
109.0648 2741.9 5
110.0599 5502.9 11
115.0541 25211 53
117.0573 22070.5 47
117.0698 21492.2 46
118.0651 25849 55
119.0731 4508.4 9
119.0855 4179.9 8
120.0443 14676.5 31
120.0809 14818.4 31
121.0522 3675.9 7
121.0648 12124.7 25
122.06 46142.8 98
122.0964 3005.4 6
124.0757 15217.6 32
128.0621 10836.4 23
129.0699 28059.2 60
130.0652 48092.8 102
131.0491 8986 19
131.073 7969.8 17
131.0852 4002.2 8
132.0445 23544.4 50
132.0808 15992.6 34
133.0522 14786.8 31
134.06 18646.4 39
134.0963 5291.4 11
142.0652 56138 120
143.073 20599.2 44
144.0568 10146.3 21
144.0808 23752.9 50
145.0525 5281.5 11
145.0647 34596.9 74
146.06 70976.5 151
147.0679 39936.3 85
148.0394 31375 67
148.0757 17422.7 37
154.0651 88516.6 189
155.0728 34891.8 74
156.0808 55348.6 118
158.0601 108539.7 232
158.0726 10005.7 21
159.0679 20747.5 44
160.0757 50490.8 108
161.0471 6187.4 13
161.0834 6082 13
162.0549 24077.8 51
163.0628 23622.4 50
164.07 3561.8 7
167.0729 22234.6 47
168.0808 23132.9 49
169.0522 32932 70
170.06 422091.7 903
171.0678 37480.7 80
172.0757 170980.1 366
173.0838 32409.2 69
174.055 30593.9 65
174.0676 18582.7 39
174.0915 5316.4 11
175.0628 12677.6 27
176.0705 19911.7 42
177.0784 10858.6 23
178.0863 10164.6 21
180.0809 38316.8 82
182.0601 89295.1 191
183.068 99503.4 213
184.0758 208969.5 447
185.0836 369704.9 791
186.055 223981.7 479
186.0914 28761 61
187.0628 19712.1 42
187.0868 5976.7 12
188.0707 31822.5 68
189.0784 7919.7 16
189.0912 7410 15
190.0862 24346.3 52
191.073 17095.7 36
192.0658 14541.1 31
192.0808 26879.5 57
193.089 14139.6 30
194.0601 26082.9 55
194.0963 15811.4 33
195.0677 14251 30
196.0758 81838.9 175
197.0473 7353.2 15
197.0835 66314.4 142
198.055 466493.5 999
198.0909 27922.2 59
199.063 24798.8 53
199.0994 6468.4 13
200.0707 163806.6 350
201.0784 84746.2 181
202.0501 3473.2 7
202.0861 18188.8 38
204.0648 4759.8 10
204.0808 39230.7 84
204.1021 4352.2 9
206.0599 23641.1 50
206.0813 3061.7 6
206.0865 3199.6 6
206.0965 27497.7 58
207.0679 17218 36
208.0758 91478 195
208.1122 9480.7 20
209.0837 30458.4 65
210.055 22758.7 48
210.0914 83332.3 178
211.063 22446.7 48
211.0995 5871.2 12
212.0706 127717.6 273
213.0784 326259.6 698
214.0499 259542.1 555
214.0859 31357.5 67
215.0577 6526.4 13
215.0817 8207 17
215.0944 9868.2 21
216.102 113425.8 242
217.0886 29762.8 63
218.0964 27427.7 58
219.0678 20617.2 44
219.1043 5561 11
220.0756 107086.3 229
220.1125 10858.5 23
221.0835 46385.5 99
222.0548 17755.8 38
222.0914 56301.5 120
223.099 31724.6 67
224.0707 61239.7 131
224.1069 11367.2 24
225.0788 23598.4 50
226.0502 7915.5 16
226.0863 39653.9 84
227.0585 2669 5
227.0939 18638.7 39
228.0656 69245.9 148
228.1016 15132.3 32
229.0734 138262.2 296
230.0814 7439.7 15
230.0965 11470.4 24
232.0756 28423.3 60
232.1125 8787.7 18
233.0835 30801.1 65
234.0553 19145.8 41
234.0914 93685.7 200
235.0635 8188.2 17
235.0992 42441.2 90
236.0707 138921.3 297
236.1069 70237.6 150
237.0785 16548.2 35
237.1146 5181.7 11
238.0863 47497.3 101
239.0938 8642 18
240.0652 14521 31
240.1016 15092.4 32
241.074 4478.2 9
242.0815 9135.2 19
243.0529 5641.7 12
243.0892 4594 9
244.0971 37783.8 80
246.0549 15444.3 33
246.0917 23702.7 50
247.0628 6778.1 14
247.0992 20674.3 44
248.0704 61366.6 131
248.1072 44646.6 95
249.0782 29552.9 63
249.102 7752.8 16
249.1152 11150.9 23
250.0502 6041.4 12
250.0863 46782.5 100
250.1227 14012.9 30
251.0941 41785.4 89
252.0655 52288.1 111
252.1022 13102 28
254.0819 6214.4 13
254.1176 11201.4 23
256.0968 4121.8 8
258.0909 19403.2 41
259.0979 3291.6 7
260.0712 6834.6 14
260.1072 18523.9 39
261.0781 7041.1 15
261.1157 4352.8 9
262.0861 35699.7 76
262.1222 14390.8 30
263.0942 38294.6 82
264.0655 26886.3 57
264.1021 42338 90
265.0738 8664.4 18
265.0964 4289.3 9
265.1102 4931.3 10
266.0813 7400.8 15
266.1176 12121.5 25
267.0893 17514.2 37
268.0974 2828.4 6
272.1069 4059.5 8
273.0785 6409.7 13
274.0867 19219.8 41
274.1238 3730.8 7
275.0945 5980.9 12
276.1013 18553.1 39
277.0951 3589.5 7
277.1102 6326.5 13
278.0811 8865.3 18
278.1176 28343.2 60
279.1122 3056.2 6
280.0973 10550.3 22
286.0861 5775.6 12
288.1013 18254.1 39
290.0822 3659.3 7
290.118 9215.4 19
292.0971 9787.5 20
294.1125 4784.3 10
301.1117 3245.6 6
304.0967 4680.1 10
306.1126 18206.2 38
316.0969 4200.4 8
337.1551 7942.2 17
379.1671 3163.1 6
//
