ACCESSION: MSBNK-Athens_Univ-AU282006
RECORD_TITLE: Paramethasone; LC-ESI-QTOF; MS2; CE: Ramp 23.5-35.2 eV; R=35000; [M+H]+
DATE: 2019.05.31
AUTHORS: Nikiforos Alygizakis, Katerina Galani, Nikolaos Thomaidis, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2019 Department of Chemistry, University of Athens
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 2820
CH$NAME: Paramethasone
CH$NAME: (6S,8S,9S,10R,11S,13S,14S,16R,17R)-6-fluoro-11,17-dihydroxy-17-(2-hydroxyacetyl)-10,13,16-trimethyl-7,8,9,11,12,14,15,16-octahydro-6H-cyclopenta[a]phenanthren-3-one
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C22H29FO5
CH$EXACT_MASS: 392.1999022
CH$SMILES: [H][C@@]12C[C@@H](C)[C@](O)(C(=O)CO)[C@@]1(C)C[C@H](O)[C@@]1([H])[C@@]2([H])C[C@H](F)C2=CC(=O)C=C[C@]12C
CH$IUPAC: InChI=1S/C22H29FO5/c1-11-6-14-13-8-16(23)15-7-12(25)4-5-20(15,2)19(13)17(26)9-21(14,3)22(11,28)18(27)10-24/h4-5,7,11,13-14,16-17,19,24,26,28H,6,8-10H2,1-3H3/t11-,13+,14+,16+,17+,19-,20+,21+,22+/m1/s1
CH$LINK: CAS
53-33-8
CH$LINK: CHEBI
7922
CH$LINK: KEGG
D07464
CH$LINK: PUBCHEM
CID:5875
CH$LINK: INCHIKEY
MKPDWECBUAZOHP-AFYJWTTESA-N
CH$LINK: CHEMSPIDER
5664
CH$LINK: COMPTOX
DTXSID3023421
AC$INSTRUMENT: Bruker maXis Impact
AC$INSTRUMENT_TYPE: LC-ESI-QTOF
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE CID
AC$MASS_SPECTROMETRY: COLLISION_ENERGY Ramp 23.5-35.2 eV
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME Acclaim RSLC C18 2.2um, 2.1x100mm, Thermo
AC$CHROMATOGRAPHY: FLOW_GRADIENT 99/1 at 0-1 min, 61/39 at 3 min, 0.1/99.9 at 14-16 min, 99/1 at 16.1-20 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 uL/min at 0-3 min, 400 uL/min at 14 min, 480 uL/min at 16-19 min, 200 uL/min at 19.1-20 min
AC$CHROMATOGRAPHY: RETENTION_TIME 8.494 min
AC$CHROMATOGRAPHY: SOLVENT A 90:10 water:methanol with 0.01% formic acid and 5mM ammonium formate
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.01% formic acid and 5mM ammonium formate
MS$FOCUSED_ION: BASE_PEAK 393.2071
MS$FOCUSED_ION: PRECURSOR_M/Z 393.2072
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE identity on assigned fragments and MS1
MS$DATA_PROCESSING: WHOLE RMassBank 2.10.1
PK$SPLASH: splash10-01ya-0692000000-a2294a46de1df700bf59
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
57.0332 C3H5O+ 2 57.0335 -4.91
69.0338 C4H5O+ 2 69.0335 5.18
69.0693 C5H9+ 2 69.0699 -7.75
71.0494 C4H7O+ 2 71.0491 3.31
81.0693 C6H9+ 2 81.0699 -7.05
93.0699 C7H9+ 2 93.0699 0
95.0505 C3H8FO2+ 2 95.0503 2.45
95.0855 C7H11+ 2 95.0855 -0.13
107.086 C8H11+ 2 107.0855 4.2
109.1014 C8H13+ 2 109.1012 1.66
111.0809 C7H11O+ 2 111.0804 3.73
115.0548 C6H8FO+ 2 115.0554 -4.52
117.0699 C9H9+ 2 117.0699 0.42
119.0853 C9H11+ 2 119.0855 -1.74
121.0642 C8H9O+ 2 121.0648 -4.78
121.1005 C9H13+ 2 121.1012 -5.95
122.067 C7[13]CH9O+ 1 122.0687 -13.48
122.1046 C8[13]CH13+ 1 122.1051 -3.82
123.0801 C8H11O+ 2 123.0804 -2.45
125.0589 C7H9O2+ 2 125.0597 -6.15
125.0961 C8H13O+ 2 125.0961 0.42
128.0608 C10H8+ 2 128.0621 -9.62
129.0681 C10H9+ 2 129.0699 -14.11
131.0852 C10H11+ 2 131.0855 -2.76
132.0569 C9H8O+ 2 132.057 -0.21
133.0651 C9H9O+ 2 133.0648 2.02
133.0995 C10H13+ 2 133.1012 -12.38
135.0794 C9H11O+ 2 135.0804 -7.86
136.0826 C8[13]CH11O+ 1 136.0843 -12.95
137.0593 C8H9O2+ 2 137.0597 -2.77
137.0958 C9H13O+ 2 137.0961 -2.32
139.0735 C8H11O2+ 2 139.0754 -13.19
141.0693 C11H9+ 2 141.0699 -3.86
143.0835 C11H11+ 2 143.0855 -13.94
144.0556 C10H8O+ 2 144.057 -9.62
145.0638 C10H9O+ 2 145.0648 -6.79
145.1001 C11H13+ 2 145.1012 -7.68
146.0692 C10H10O+ 1 146.0726 -23.31
147.0795 C10H11O+ 2 147.0804 -6.38
148.0826 C9[13]CH11O+ 1 148.0843 -11.74
149.0241 C5H6FO4+ 2 149.0245 -2.26
149.0947 C10H13O+ 2 149.0961 -9.3
150.0974 C9[13]CH13O+ 1 150.1 -17
151.0754 C9H11O2+ 2 151.0754 -0.04
151.1101 C10H15O+ 2 151.1117 -10.92
153.0901 C9H13O2+ 2 153.091 -5.8
154.0945 C8[13]CH13O2+ 1 154.0949 -2.39
155.0695 C8H11O3+ 2 155.0703 -4.7
155.0865 C9H12FO+ 2 155.0867 -1.32
156.0905 C12H12+ 1 156.0934 -18.36
157.0657 C8H10FO2+ 2 157.0659 -1.31
157.1002 C12H13+ 2 157.1012 -6.06
158.072 C11H10O+ 2 158.0726 -3.62
159.0795 C11H11O+ 2 159.0804 -5.86
159.1176 C9H16FO+ 2 159.118 -2.11
160.0831 C10[13]CH11O+ 1 160.0843 -7.58
161.0952 C11H13O+ 2 161.0961 -5.82
162.098 C10[13]CH13O+ 1 162.1 -12.19
163.076 C7H12FO3+ 2 163.0765 -3.25
163.1117 C11H15O+ 2 163.1117 -0.39
165.0895 C10H13O2+ 2 165.091 -8.91
167.0859 C13H11+ 2 167.0855 2.29
167.1054 C10H15O2+ 2 167.1067 -7.51
169.0632 C12H9O+ 2 169.0648 -9.18
169.0862 C9H13O3+ 2 169.0859 1.49
169.1013 C13H13+ 2 169.1012 0.88
171.0799 C12H11O+ 2 171.0804 -3.01
171.1165 C13H15+ 2 171.1168 -1.87
172.083 C11[13]CH11O+ 1 172.0843 -8.01
173.0953 C12H13O+ 2 173.0961 -4.46
174.0979 C11[13]CH13O+ 1 174.1 -12.08
175.0757 C11H11O2+ 2 175.0754 1.82
175.1113 C12H15O+ 2 175.1117 -2.74
177.0902 C11H13O2+ 2 177.091 -4.81
178.0954 C11H14O2+ 1 178.0988 -19.36
179.0843 C14H11+ 2 179.0855 -7.02
180.0901 C14H12+ 2 180.0934 -17.97
181.1004 C14H13+ 2 181.1012 -4.1
183.0796 C13H11O+ 2 183.0804 -4.36
183.1168 C14H15+ 2 183.1168 0.02
185.096 C13H13O+ 2 185.0961 -0.61
186.0991 C12[13]CH13O+ 1 186.1 -4.73
187.0747 C12H11O2+ 2 187.0754 -3.53
187.1102 C13H15O+ 2 187.1117 -8.1
188.0798 C11[13]CH11O2+ 1 188.0793 2.74
189.0675 C15H9+ 2 189.0699 -12.76
189.0902 C12H13O2+ 2 189.091 -4.43
191.0831 C15H11+ 2 191.0855 -12.52
191.1079 C9H16FO3+ 2 191.1078 0.36
192.0923 C15H12+ 2 192.0934 -5.43
193.0851 C11H13O3+ 2 193.0859 -4.48
193.1011 C15H13+ 2 193.1012 -0.54
195.0775 C14H11O+ 2 195.0804 -15.17
195.1002 C11H15O3+ 2 195.1016 -7.08
195.1143 C15H15+ 2 195.1168 -13.17
196.0858 C14H12O+ 2 196.0883 -12.65
197.0949 C14H13O+ 2 197.0961 -6.03
197.1339 C12H18FO+ 3 197.1336 1.22
198.1008 C14H14O+ 2 198.1039 -15.88
199.0749 C13H11O2+ 2 199.0754 -2.35
199.1101 C14H15O+ 2 199.1117 -8.42
200.1114 C13[13]CH15O+ 1 200.1156 -21.25
200.1214 C11H17FO2+ 2 200.1207 3.55
201.0927 C10H14FO3+ 2 201.0921 2.74
201.1266 C14H17O+ 2 201.1274 -4.13
203.1063 C13H15O2+ 2 203.1067 -1.85
204.0933 C16H12+ 2 204.0934 -0.04
205.0985 C16H13+ 2 205.1012 -13.05
206.106 C16H14+ 2 206.109 -14.68
207.1158 C16H15+ 2 207.1168 -5.11
208.0878 C15H12O+ 2 208.0883 -2.13
209.0956 C15H13O+ 2 209.0961 -2.41
209.1324 C16H17+ 2 209.1325 -0.6
210.1012 C15H14O+ 2 210.1039 -13.03
211.1109 C15H15O+ 2 211.1117 -3.85
212.1167 C14[13]CH15O+ 1 212.1156 5.16
213.0923 C11H14FO3+ 2 213.0921 0.93
213.1267 C15H17O+ 2 213.1274 -3.48
214.1298 C14[13]CH17O+ 1 214.1313 -6.9
215.1059 C14H15O2+ 2 215.1067 -3.47
215.1413 C15H19O+ 2 215.143 -8.33
216.1104 C13[13]CH15O2+ 1 216.1106 -0.8
217.1042 C14H14FO+ 3 217.1023 8.63
219.1169 C17H15+ 2 219.1168 0.31
220.0891 C13H13FO2+ 2 220.0894 -1.56
220.1218 C17H16+ 2 220.1247 -13.04
221.0955 C16H13O+ 2 221.0961 -2.53
221.1327 C17H17+ 2 221.1325 0.98
222.1027 C16H14O+ 2 222.1039 -5.26
223.1115 C16H15O+ 2 223.1117 -1.06
224.1172 C16H16O+ 2 224.1196 -10.63
225.0897 C15H13O2+ 2 225.091 -5.71
225.1263 C13H18FO2+ 2 225.1285 -9.98
226.1322 C12[13]CH18FO2+ 1 226.1324 -1.15
227.1049 C15H15O2+ 2 227.1067 -7.6
227.1424 C16H19O+ 2 227.143 -2.84
229.0856 C14H13O3+ 2 229.0859 -1.43
231.1139 C18H15+ 2 231.1168 -12.79
232.1242 C17[13]CH15+ 1 232.1207 15.05
233.0938 C17H13O+ 2 233.0961 -9.62
234.1031 C17H14O+ 2 234.1039 -3.28
235.1104 C17H15O+ 2 235.1117 -5.59
235.1482 C18H19+ 3 235.1481 0.25
236.117 C16[13]CH15O+ 1 236.1156 5.88
236.1548 C18H20+ 2 236.156 -4.83
237.127 C17H17O+ 2 237.1274 -1.6
238.1307 C16[13]CH17O+ 1 238.1313 -2.34
239.1049 C16H15O2+ 2 239.1067 -7.27
239.1423 C17H19O+ 2 239.143 -3.16
240.1123 C16H16O2+ 2 240.1145 -9.12
240.1465 C16[13]CH19O+ 1 240.1469 -1.96
241.1226 C16H17O2+ 2 241.1223 1.4
241.1589 C17H21O+ 2 241.1587 1
242.1261 C16H18O2+ 2 242.1301 -16.62
243.1162 C19H15+ 2 243.1168 -2.75
245.0947 C18H13O+ 2 245.0961 -5.83
245.1313 C19H17+ 2 245.1325 -4.7
246.1027 C18H14O+ 2 246.1039 -4.8
246.1377 C19H18+ 2 246.1403 -10.61
247.1111 C18H15O+ 2 247.1117 -2.52
247.1487 C19H19+ 3 247.1481 2.27
248.1207 C15H17FO2+ 2 248.1207 0.14
249.1269 C18H17O+ 2 249.1274 -1.78
249.1625 C19H21+ 2 249.1638 -4.94
250.1322 C18H18O+ 2 250.1352 -12.22
250.1668 C19H22+ 2 250.1716 -19.29
251.1057 C17H15O2+ 2 251.1067 -3.67
251.143 C18H19O+ 2 251.143 -0.1
252.1091 C17H16O2+ 1 252.1145 -21.24
252.149 C18H20O+ 2 252.1509 -7.59
253.1209 C17H17O2+ 2 253.1223 -5.45
253.1576 C18H21O+ 2 253.1587 -4.42
254.1266 C17H18O2+ 2 254.1301 -13.85
254.1631 C17[13]CH21O+ 1 254.1626 2.13
255.138 C17H19O2+ 2 255.138 0.36
256.1409 C17H20O2+ 2 256.1458 -18.93
259.1109 C19H15O+ 2 259.1117 -3.22
259.1473 C20H19+ 2 259.1481 -3.14
260.1201 C19H16O+ 2 260.1196 2.18
261.1263 C19H17O+ 2 261.1274 -4.32
261.1627 C20H21+ 2 261.1638 -4.02
262.1349 C19H18O+ 2 262.1352 -1.21
263.1111 C15H16FO3+ 2 263.1078 12.7
263.1425 C19H19O+ 2 263.143 -2.09
264.1493 C18[13]CH19O+ 1 264.1469 9
265.1234 C15H18FO3+ 2 265.1234 -0.22
265.1585 C19H21O+ 2 265.1587 -0.84
266.164 C19H22O+ 2 266.1665 -9.63
267.1373 C18H19O2+ 2 267.138 -2.43
267.175 C16H24FO2+ 2 267.1755 -1.78
268.1403 C17[13]CH19O2+ 1 268.1419 -5.7
268.1792 C19H24O+ 2 268.1822 -11.15
272.1213 C17H17FO2+ 2 272.1207 2.16
273.125 C20H17O+ 2 273.1274 -8.66
273.1599 C21H21+ 2 273.1638 -14.37
274.1338 C20H18O+ 2 274.1352 -5.32
275.1435 C20H19O+ 2 275.143 1.49
276.1502 C20H20O+ 2 276.1509 -2.39
277.123 C16H18FO3+ 2 277.1234 -1.59
277.159 C20H21O+ 2 277.1587 0.95
278.1299 C19H18O2+ 2 278.1301 -0.85
278.1659 C20H22O+ 2 278.1665 -2.28
279.1741 C20H23O+ 2 279.1743 -1.04
280.1475 C16H21FO3+ 2 280.1469 1.93
280.1774 C19[13]CH23O+ 1 280.1782 -2.84
281.1524 C19H21O2+ 2 281.1536 -4.31
281.189 C20H25O+ 2 281.19 -3.66
283.1465 C22H19+ 2 283.1481 -5.78
283.1667 C19H23O2+ 2 283.1693 -8.87
286.1378 C21H18O+ 2 286.1352 9.15
287.1389 C20[13]CH18O+ 1 287.1391 -0.64
289.1596 C21H21O+ 2 289.1587 3.11
290.1307 C20H18O2+ 2 290.1301 1.93
290.1621 C20[13]CH21O+ 1 290.1626 -1.86
291.1376 C20H19O2+ 2 291.138 -1.19
291.1745 C21H23O+ 2 291.1743 0.45
292.1771 C20[13]CH23O+ 1 292.1782 -4.03
293.1556 C17H22FO3+ 2 293.1547 2.99
294.1571 C20H22O2+ 2 294.1614 -14.73
295.1335 C19H19O3+ 2 295.1329 2.07
295.1693 C20H23O2+ 2 295.1693 0.13
296.1341 C18[13]CH19O3+ 1 296.1368 -9.07
296.1753 C20H24O2+ 2 296.1771 -5.94
297.1463 C19H21O3+ 2 297.1485 -7.64
297.1823 C20H25O2+ 2 297.1849 -8.92
298.1886 C19[13]CH25O2+ 1 298.1888 -0.61
301.1593 C19H22FO2+ 2 301.1598 -1.8
302.1636 C18[13]CH22FO2+ 1 302.1637 -0.52
304.1477 C18H21FO3+ 2 304.1469 2.66
306.1619 C21H22O2+ 2 306.1614 1.51
307.1685 C21H23O2+ 2 307.1693 -2.37
308.1741 C21H24O2+ 2 308.1771 -9.62
309.184 C18H26FO3+ 2 309.186 -6.6
310.19 C17[13]CH26FO3+ 1 310.19 0.14
311.1642 C20H23O3+ 2 311.1642 0.04
312.1679 C19[13]CH23O3+ 1 312.1681 -0.63
313.1723 C20H25O3+ 1 313.1798 -24.06
319.17 C22H23O2+ 2 319.1693 2.31
320.1732 C21[13]CH23O2+ 1 320.1732 0.01
325.1792 C21H25O3+ 2 325.1798 -1.77
326.1822 C20[13]CH25O3+ 1 326.1837 -4.72
327.1954 C21H27O3+ 2 327.1955 -0.11
328.1958 C21H28O3+ 1 328.2033 -22.75
337.1799 C22H25O3+ 2 337.1798 0.15
338.1829 C21[13]CH25O3+ 1 338.1837 -2.45
339.1905 C22H27O3+ 2 339.1955 -14.59
345.1884 C21H26FO3+ 1 345.186 6.86
355.1913 C22H27O4+ 2 355.1904 2.45
356.1945 C21[13]CH27O4+ 1 356.1943 0.46
357.2006 C22H29O4+ 2 357.206 -15.09
373.2041 C22H29O5+ 1 373.201 8.49
374.2053 C21[13]CH29O5+ 1 374.2049 1.31
375.2012 C22H28FO4+ 1 375.1966 12.14
PK$NUM_PEAK: 253
PK$PEAK: m/z int. rel.int.
57.0332 512 16
69.0338 356 11
69.0693 576 19
71.0494 752 24
81.0693 364 12
93.0699 356 11
95.0505 496 16
95.0855 1164 38
107.086 696 23
109.1014 400 13
111.0809 368 12
115.0548 612 20
117.0699 476 15
119.0853 2196 72
121.0642 5680 188
121.1005 2544 84
122.067 564 18
122.1046 320 10
123.0801 1908 63
125.0589 1352 44
125.0961 1004 33
128.0608 508 16
129.0681 660 21
131.0852 2096 69
132.0569 376 12
133.0651 1552 51
133.0995 1448 48
135.0794 7796 258
136.0826 796 26
137.0593 712 23
137.0958 2476 82
139.0735 336 11
141.0693 576 19
143.0835 2004 66
144.0556 352 11
145.0638 1900 63
145.1001 1332 44
146.0692 532 17
147.0795 30128 999
148.0826 2940 97
149.0241 524 17
149.0947 3860 127
150.0974 468 15
151.0754 1876 62
151.1101 952 31
153.0901 4012 133
154.0945 512 16
155.0695 324 10
155.0865 596 19
156.0905 492 16
157.0657 476 15
157.1002 1360 45
158.072 904 29
159.0795 6596 218
159.1176 388 12
160.0831 1264 41
161.0952 7196 238
162.098 836 27
163.076 888 29
163.1117 656 21
165.0895 984 32
167.0859 484 16
167.1054 2236 74
169.0632 836 27
169.0862 304 10
169.1013 984 32
171.0799 13468 446
171.1165 1180 39
172.083 2428 80
173.0953 10208 338
174.0979 1620 53
175.0757 600 19
175.1113 1204 39
177.0902 2728 90
178.0954 588 19
179.0843 768 25
180.0901 412 13
181.1004 644 21
183.0796 1276 42
183.1168 452 14
185.096 7680 254
186.0991 860 28
187.0747 3600 119
187.1102 2780 92
188.0798 532 17
189.0675 316 10
189.0902 1396 46
191.0831 384 12
191.1079 472 15
192.0923 376 12
193.0851 408 13
193.1011 1136 37
195.0775 988 32
195.1002 644 21
195.1143 956 31
196.0858 796 26
197.0949 4500 149
197.1339 544 18
198.1008 1252 41
199.0749 532 17
199.1101 3704 122
200.1114 452 14
200.1214 364 12
201.0927 540 17
201.1266 664 22
203.1063 992 32
204.0933 440 14
205.0985 680 22
206.106 420 13
207.1158 868 28
208.0878 1060 35
209.0956 3148 104
209.1324 988 32
210.1012 1764 58
211.1109 8604 285
212.1167 2360 78
213.0923 804 26
213.1267 5144 170
214.1298 632 20
215.1059 4684 155
215.1413 388 12
216.1104 684 22
217.1042 320 10
219.1169 1696 56
220.0891 356 11
220.1218 792 26
221.0955 2552 84
221.1327 556 18
222.1027 2800 92
223.1115 6680 221
224.1172 2684 88
225.0897 620 20
225.1263 3728 123
226.1322 748 24
227.1049 576 19
227.1424 1680 55
229.0856 364 12
231.1139 860 28
232.1242 304 10
233.0938 676 22
234.1031 952 31
235.1104 5192 172
235.1482 616 20
236.117 1676 55
236.1548 432 14
237.127 16204 537
238.1307 4472 148
239.1049 1400 46
239.1423 8156 270
240.1123 572 18
240.1465 2104 69
241.1226 1892 62
241.1589 692 22
242.1261 832 27
243.1162 580 19
245.0947 308 10
245.1313 580 19
246.1027 592 19
246.1377 464 15
247.1111 756 25
247.1487 524 17
248.1207 1604 53
249.1269 3440 114
249.1625 824 27
250.1322 1348 44
250.1668 524 17
251.1057 504 16
251.143 2212 73
252.1091 424 14
252.149 1088 36
253.1209 2308 76
253.1576 3848 127
254.1266 748 24
254.1631 868 28
255.138 1200 39
256.1409 476 15
259.1109 904 29
259.1473 612 20
260.1201 1280 42
261.1263 2324 77
261.1627 736 24
262.1349 2440 80
263.1111 492 16
263.1425 8480 281
264.1493 2600 86
265.1234 540 17
265.1585 2076 68
266.164 704 23
267.1373 2628 87
267.175 1352 44
268.1403 560 18
268.1792 524 17
272.1213 680 22
273.125 604 20
273.1599 648 21
274.1338 1312 43
275.1435 3584 118
276.1502 2788 92
277.123 944 31
277.159 7488 248
278.1299 452 14
278.1659 6840 226
279.1741 26060 864
280.1475 340 11
280.1774 6680 221
281.1524 1520 50
281.189 1516 50
283.1465 544 18
283.1667 416 13
286.1378 1260 41
287.1389 480 15
289.1596 3904 129
290.1307 380 12
290.1621 996 33
291.1376 536 17
291.1745 7404 245
292.1771 2312 76
293.1556 1060 35
294.1571 340 11
295.1335 928 30
295.1693 4188 138
296.1341 308 10
296.1753 1732 57
297.1463 308 10
297.1823 2352 77
298.1886 684 22
301.1593 3100 102
302.1636 936 31
304.1477 388 12
306.1619 556 18
307.1685 3272 108
308.1741 1228 40
309.184 4396 145
310.19 920 30
311.1642 3392 112
312.1679 984 32
313.1723 436 14
319.17 6628 219
320.1732 1800 59
325.1792 1440 47
326.1822 488 16
327.1954 868 28
328.1958 368 12
337.1799 7472 247
338.1829 2040 67
339.1905 400 13
345.1884 320 10
355.1913 12432 412
356.1945 3632 120
357.2006 644 21
373.2041 1188 39
374.2053 492 16
375.2012 300 9
//
