ACCESSION: MSBNK-Athens_Univ-AU282004
RECORD_TITLE: Paramethasone; LC-ESI-QTOF; MS2; CE: 40 eV; R=35000; [M+H]+
DATE: 2019.05.31
AUTHORS: Nikiforos Alygizakis, Katerina Galani, Nikolaos Thomaidis, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2019 Department of Chemistry, University of Athens
COMMENT: CONFIDENCE standard compound
COMMENT: INTERNAL_ID 2820
CH$NAME: Paramethasone
CH$NAME: (6S,8S,9S,10R,11S,13S,14S,16R,17R)-6-fluoro-11,17-dihydroxy-17-(2-hydroxyacetyl)-10,13,16-trimethyl-7,8,9,11,12,14,15,16-octahydro-6H-cyclopenta[a]phenanthren-3-one
CH$COMPOUND_CLASS: N/A; Environmental Standard
CH$FORMULA: C22H29FO5
CH$EXACT_MASS: 392.1999022
CH$SMILES: [H][C@@]12C[C@@H](C)[C@](O)(C(=O)CO)[C@@]1(C)C[C@H](O)[C@@]1([H])[C@@]2([H])C[C@H](F)C2=CC(=O)C=C[C@]12C
CH$IUPAC: InChI=1S/C22H29FO5/c1-11-6-14-13-8-16(23)15-7-12(25)4-5-20(15,2)19(13)17(26)9-21(14,3)22(11,28)18(27)10-24/h4-5,7,11,13-14,16-17,19,24,26,28H,6,8-10H2,1-3H3/t11-,13+,14+,16+,17+,19-,20+,21+,22+/m1/s1
CH$LINK: CAS
53-33-8
CH$LINK: CHEBI
7922
CH$LINK: KEGG
D07464
CH$LINK: PUBCHEM
CID:5875
CH$LINK: INCHIKEY
MKPDWECBUAZOHP-AFYJWTTESA-N
CH$LINK: CHEMSPIDER
5664
CH$LINK: COMPTOX
DTXSID3023421
AC$INSTRUMENT: Bruker maXis Impact
AC$INSTRUMENT_TYPE: LC-ESI-QTOF
AC$MASS_SPECTROMETRY: MS_TYPE MS2
AC$MASS_SPECTROMETRY: ION_MODE POSITIVE
AC$MASS_SPECTROMETRY: IONIZATION ESI
AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE CID
AC$MASS_SPECTROMETRY: COLLISION_ENERGY 40 eV
AC$MASS_SPECTROMETRY: RESOLUTION 35000
AC$CHROMATOGRAPHY: COLUMN_NAME Acclaim RSLC C18 2.2um, 2.1x100mm, Thermo
AC$CHROMATOGRAPHY: FLOW_GRADIENT 99/1 at 0-1 min, 61/39 at 3 min, 0.1/99.9 at 14-16 min, 99/1 at 16.1-20 min
AC$CHROMATOGRAPHY: FLOW_RATE 200 uL/min at 0-3 min, 400 uL/min at 14 min, 480 uL/min at 16-19 min, 200 uL/min at 19.1-20 min
AC$CHROMATOGRAPHY: RETENTION_TIME 8.524 min
AC$CHROMATOGRAPHY: SOLVENT A 90:10 water:methanol with 0.01% formic acid and 5mM ammonium formate
AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.01% formic acid and 5mM ammonium formate
MS$FOCUSED_ION: BASE_PEAK 393.2062
MS$FOCUSED_ION: PRECURSOR_M/Z 393.2072
MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+
MS$DATA_PROCESSING: RECALIBRATE identity on assigned fragments and MS1
MS$DATA_PROCESSING: WHOLE RMassBank 2.10.1
PK$SPLASH: splash10-00dj-0980000000-32ed1d5464b845727421
PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm)
115.0531 C9H7+ 2 115.0542 -9.98
116.0597 C9H8+ 1 116.0621 -19.88
117.068 C9H9+ 1 117.0699 -15.91
119.085 C9H11+ 2 119.0855 -4.65
120.0896 C8[13]CH11+ 1 120.0894 1.8
121.0639 C8H9O+ 2 121.0648 -7.42
121.1005 C9H13+ 2 121.1012 -5.63
122.0679 C7[13]CH9O+ 1 122.0687 -6.23
123.0793 C8H11O+ 2 123.0804 -9.51
125.0588 C7H9O2+ 2 125.0597 -6.89
125.0941 C8H13O+ 2 125.0961 -15.56
128.0614 C10H8+ 2 128.0621 -5.33
129.0687 C10H9+ 2 129.0699 -9.16
130.0762 C10H10+ 2 130.0777 -11.33
131.0474 C9H7O+ 2 131.0491 -13.35
131.0843 C10H11+ 2 131.0855 -9.23
132.055 C9H8O+ 2 132.057 -14.63
132.0886 C9[13]CH11+ 1 132.0894 -6.54
133.063 C9H9O+ 2 133.0648 -13.61
133.1002 C10H13+ 2 133.1012 -7.48
134.0727 C9H10O+ 2 134.0726 0.31
135.0791 C9H11O+ 2 135.0804 -9.68
137.0586 C8H9O2+ 2 137.0597 -8.2
137.0751 C9H10F+ 1 137.0761 -7.06
137.0946 C9H13O+ 2 137.0961 -10.95
141.0685 C11H9+ 2 141.0699 -9.61
142.0758 C11H10+ 2 142.0777 -13.24
143.0842 C11H11+ 2 143.0855 -9.4
144.0554 C10H8O+ 2 144.057 -11.13
144.0882 C10[13]CH11+ 1 144.0894 -8.24
145.0634 C10H9O+ 2 145.0648 -9.62
145.1 C11H13+ 2 145.1012 -7.97
147.079 C10H11O+ 2 147.0804 -9.5
148.0823 C9[13]CH11O+ 1 148.0843 -13.8
149.0219 C8H5O3+ 2 149.0233 -9.68
149.0948 C10H13O+ 2 149.0961 -8.45
151.0734 C9H11O2+ 2 151.0754 -12.79
151.1108 C10H15O+ 2 151.1117 -6.47
153.0686 C12H9+ 2 153.0699 -8.38
153.089 C9H13O2+ 2 153.091 -12.88
155.0838 C12H11+ 2 155.0855 -10.86
156.09 C12H12+ 1 156.0934 -21.51
157.0639 C11H9O+ 2 157.0648 -5.96
157.0995 C9H14FO+ 2 157.1023 -18.01
158.0709 C11H10O+ 2 158.0726 -10.85
158.1067 C8[13]CH14FO+ 1 158.1062 3.28
159.0788 C11H11O+ 2 159.0804 -10.37
160.083 C10[13]CH11O+ 1 160.0843 -8.32
161.0573 C10H9O2+ 2 161.0597 -14.84
161.095 C11H13O+ 2 161.0961 -6.68
162.0977 C10[13]CH13O+ 1 162.1 -14.09
163.0752 C10H11O2+ 2 163.0754 -1.06
163.1104 C11H15O+ 2 163.1117 -8.3
165.0696 C13H9+ 2 165.0699 -1.74
165.0897 C10H13O2+ 2 165.091 -7.86
166.0771 C13H10+ 2 166.0777 -3.89
167.0843 C13H11+ 2 167.0855 -7.18
167.1039 C10H15O2+ 2 167.1067 -16.28
168.055 C12H8O+ 2 168.057 -11.6
169.0624 C12H9O+ 2 169.0648 -14.41
169.0995 C13H13+ 2 169.1012 -9.94
170.0705 C12H10O+ 2 170.0726 -12.37
171.079 C12H11O+ 2 171.0804 -8.42
171.1152 C13H15+ 2 171.1168 -9.64
172.0831 C11[13]CH11O+ 1 172.0843 -7.03
173.095 C12H13O+ 2 173.0961 -6.19
174.0976 C11[13]CH13O+ 1 174.1 -13.91
175.0738 C11H11O2+ 2 175.0754 -9.17
175.1104 C12H15O+ 2 175.1117 -7.61
177.0892 C11H13O2+ 2 177.091 -9.93
178.0765 C14H10+ 2 178.0777 -6.99
179.085 C14H11+ 2 179.0855 -2.96
180.0896 C14H12+ 1 180.0934 -20.67
181.0628 C13H9O+ 2 181.0648 -11.24
181.1001 C14H13+ 2 181.1012 -5.86
182.0725 C13H10O+ 2 182.0726 -0.43
182.1079 C14H14+ 2 182.109 -6.16
183.0783 C13H11O+ 2 183.0804 -11.51
183.1147 C14H15+ 2 183.1168 -11.78
184.086 C13H12O+ 2 184.0883 -12.35
185.0567 C12H9O2+ 2 185.0597 -16.31
185.0945 C13H13O+ 2 185.0961 -8.83
186.0981 C12[13]CH13O+ 1 186.1 -10.14
187.0739 C12H11O2+ 2 187.0754 -7.57
187.111 C13H15O+ 2 187.1117 -4.19
188.0775 C11[13]CH11O2+ 1 188.0793 -9.41
189.0681 C15H9+ 2 189.0699 -9.36
189.0909 C12H13O2+ 2 189.091 -0.57
189.1266 C13H17O+ 2 189.1274 -4.03
190.0747 C15H10+ 2 190.0777 -15.55
191.087 C12H12FO+ 3 191.0867 1.61
192.0912 C15H12+ 2 192.0934 -11.42
193.1 C15H13+ 2 193.1012 -6.25
194.0712 C14H10O+ 2 194.0726 -7.08
194.106 C15H14+ 2 194.109 -15.36
195.0792 C14H11O+ 2 195.0804 -6.18
195.1142 C15H15+ 2 195.1168 -13.23
196.0857 C14H12O+ 2 196.0883 -12.85
196.1204 C14[13]CH15+ 1 196.1207 -1.73
197.0941 C14H13O+ 2 197.0961 -10.03
197.1309 C15H17+ 2 197.1325 -7.77
198.0993 C14H14O+ 1 198.1039 -23.39
199.0732 C13H11O2+ 2 199.0754 -10.89
199.1098 C14H15O+ 2 199.1117 -9.76
201.0879 C13H13O2+ 2 201.091 -15.58
201.1266 C14H17O+ 2 201.1274 -4.03
203.0842 C16H11+ 2 203.0855 -6.57
204.0918 C16H12+ 2 204.0934 -7.72
205.0995 C16H13+ 2 205.1012 -8.1
206.108 C16H14+ 2 206.109 -4.83
207.078 C15H11O+ 2 207.0804 -11.56
207.1158 C16H15+ 2 207.1168 -5.01
208.0873 C15H12O+ 2 208.0883 -4.76
208.1205 C16H16+ 1 208.1247 -19.99
209.0945 C15H13O+ 2 209.0961 -7.7
209.1312 C16H17+ 2 209.1325 -6.24
210.102 C15H14O+ 2 210.1039 -9.14
210.1324 C15[13]CH17+ 1 210.1364 -18.96
211.1102 C15H15O+ 2 211.1117 -7.43
211.1491 C13H20FO+ 3 211.1493 -0.7
212.1161 C15H16O+ 2 212.1196 -16.46
213.0917 C11H14FO3+ 2 213.0921 -1.97
213.1266 C15H17O+ 2 213.1274 -3.63
214.1294 C14[13]CH17O+ 1 214.1313 -8.7
215.0849 C17H11+ 2 215.0855 -3.1
215.1052 C14H15O2+ 2 215.1067 -6.74
216.0931 C17H12+ 2 216.0934 -1.12
216.1096 C13[13]CH15O2+ 1 216.1106 -4.22
217.1016 C17H13+ 2 217.1012 2.05
218.108 C17H14+ 2 218.109 -4.38
219.0767 C16H11O+ 2 219.0804 -17.21
219.1148 C17H15+ 2 219.1168 -9.43
220.0871 C16H12O+ 2 220.0883 -5.5
220.1227 C17H16+ 2 220.1247 -8.96
221.0953 C16H13O+ 2 221.0961 -3.39
221.1306 C17H17+ 2 221.1325 -8.67
222.1024 C16H14O+ 2 222.1039 -6.67
222.1366 C17H18+ 2 222.1403 -16.78
223.1102 C16H15O+ 2 223.1117 -6.73
224.1172 C16H16O+ 2 224.1196 -10.54
225.0909 C15H13O2+ 2 225.091 -0.45
225.1255 C16H17O+ 2 225.1274 -8.25
226.0967 C15H14O2+ 2 226.0988 -9.54
226.1306 C16H18O+ 1 226.1352 -20.62
227.1053 C15H15O2+ 2 227.1067 -5.95
227.1417 C16H19O+ 2 227.143 -5.96
228.1447 C15[13]CH19O+ 1 228.1469 -9.7
229.0994 C18H13+ 2 229.1012 -7.94
230.1079 C18H14+ 2 230.109 -4.86
231.1155 C18H15+ 2 231.1168 -5.86
232.0847 C17H12O+ 2 232.0883 -15.25
232.1223 C18H16+ 2 232.1247 -10.27
233.0953 C17H13O+ 2 233.0961 -3.59
233.1318 C18H17+ 2 233.1325 -2.85
234.1029 C17H14O+ 2 234.1039 -4.23
234.1372 C18H18+ 2 234.1403 -13.1
235.1106 C17H15O+ 2 235.1117 -4.79
235.1477 C18H19+ 2 235.1481 -1.78
236.1148 C17H16O+ 1 236.1196 -20.26
236.1592 C15H21FO+ 3 236.1571 8.87
237.126 C17H17O+ 2 237.1274 -6.04
237.1611 C18H21+ 2 237.1638 -11.23
238.0959 C16H14O2+ 2 238.0988 -12.24
238.1305 C16[13]CH17O+ 1 238.1313 -3.24
239.1047 C16H15O2+ 2 239.1067 -8.07
239.1424 C17H19O+ 2 239.143 -2.75
240.1098 C15[13]CH15O2+ 1 240.1106 -3.19
241.1219 C16H17O2+ 2 241.1223 -1.76
242.1192 C12H18O5+ 1 242.1149 17.95
243.1141 C19H15+ 2 243.1168 -11.36
244.1217 C19H16+ 2 244.1247 -12.18
245.0944 C18H13O+ 2 245.0961 -7.09
245.1291 C19H17+ 2 245.1325 -13.62
246.1009 C18H14O+ 2 246.1039 -12.2
246.1376 C19H18+ 2 246.1403 -11.13
247.1107 C18H15O+ 2 247.1117 -4.13
247.1469 C19H19+ 2 247.1481 -4.94
248.1179 C18H16O+ 2 248.1196 -6.53
249.1262 C18H17O+ 2 249.1274 -4.81
249.1614 C19H21+ 2 249.1638 -9.58
250.1309 C18H18O+ 2 250.1352 -17.25
250.172 C19H22+ 3 250.1716 1.58
251.1026 C17H15O2+ 2 251.1067 -16.04
251.1418 C18H19O+ 2 251.143 -4.75
251.1802 C16H24FO+ 3 251.1806 -1.31
252.1098 C17H16O2+ 2 252.1145 -18.6
252.1489 C18H20O+ 2 252.1509 -7.97
253.1209 C17H17O2+ 2 253.1223 -5.57
253.1556 C18H21O+ 2 253.1587 -12.4
254.1253 C16[13]CH17O2+ 1 254.1262 -3.47
254.1616 C17[13]CH21O+ 1 254.1626 -4.02
255.1367 C17H19O2+ 2 255.138 -4.97
257.1317 C20H17+ 2 257.1325 -3.14
258.1031 C19H14O+ 2 258.1039 -3.16
258.1414 C17H19FO+ 3 258.1414 -0.15
259.1119 C19H15O+ 2 259.1117 0.75
259.1467 C20H19+ 2 259.1481 -5.61
260.1164 C19H16O+ 2 260.1196 -12.1
261.1264 C19H17O+ 2 261.1274 -3.63
261.1638 C20H21+ 3 261.1638 -0.02
262.1338 C19H18O+ 2 262.1352 -5.37
263.1033 C18H15O2+ 2 263.1067 -12.6
263.1415 C19H19O+ 2 263.143 -5.92
264.1115 C18H16O2+ 2 264.1145 -11.39
264.1484 C19H20O+ 2 264.1509 -9.33
265.1565 C18[13]CH20O+ 1 265.1548 6.41
266.1606 C19H22O+ 1 266.1665 -22.21
267.137 C18H19O2+ 2 267.138 -3.67
267.174 C18[13]CH22O+ 1 267.1704 13.4
271.1122 C20H15O+ 2 271.1117 1.75
271.1464 C21H19+ 2 271.1481 -6.32
272.1164 C20H16O+ 2 272.1196 -11.82
273.1261 C20H17O+ 2 273.1274 -4.82
273.1628 C21H21+ 3 273.1638 -3.49
274.1359 C17H19FO2+ 2 274.1364 -1.82
275.1412 C20H19O+ 2 275.143 -6.65
276.1493 C20H20O+ 2 276.1509 -5.54
277.1212 C19H17O2+ 2 277.1223 -4.12
277.1563 C20H21O+ 2 277.1587 -8.63
278.1267 C19H18O2+ 2 278.1301 -12.16
278.164 C20H22O+ 2 278.1665 -8.98
279.1399 C16H20FO3+ 2 279.1391 2.86
279.1724 C20H23O+ 2 279.1743 -7.1
280.1771 C19[13]CH23O+ 1 280.1782 -4.22
281.1535 C19H21O2+ 2 281.1536 -0.41
281.186 C20H25O+ 2 281.19 -14.26
282.1585 C19H22O2+ 2 282.1614 -10.4
286.1339 C21H18O+ 2 286.1352 -4.54
287.1353 C20[13]CH18O+ 1 287.1391 -13.31
289.157 C21H21O+ 2 289.1587 -5.72
290.1304 C20H18O2+ 2 290.1301 1.05
290.1585 C20[13]CH21O+ 1 290.1626 -14.13
291.1361 C20H19O2+ 2 291.138 -6.3
291.1732 C21H23O+ 2 291.1743 -3.79
292.1407 C20H20O2+ 2 292.1458 -17.25
292.1779 C21H24O+ 2 292.1822 -14.71
293.1554 C17H22FO3+ 2 293.1547 2.28
295.1691 C20H23O2+ 2 295.1693 -0.42
296.1763 C20H24O2+ 2 296.1771 -2.58
297.1835 C20H25O2+ 2 297.1849 -4.77
301.157 C22H21O+ 2 301.1587 -5.52
304.1439 C21H20O2+ 2 304.1458 -6.11
306.1615 C21H22O2+ 2 306.1614 0.33
307.1677 C21H23O2+ 2 307.1693 -5.19
308.1758 C21H24O2+ 2 308.1771 -4
309.1882 C18H26FO3+ 2 309.186 7.11
319.1702 C22H23O2+ 2 319.1693 2.97
320.1706 C21[13]CH23O2+ 1 320.1732 -8.08
325.1796 C21H25O3+ 2 325.1798 -0.64
PK$NUM_PEAK: 249
PK$PEAK: m/z int. rel.int.
115.0531 808 28
116.0597 316 11
117.068 1020 35
119.085 3296 115
120.0896 480 16
121.0639 7464 260
121.1005 1456 50
122.0679 1008 35
123.0793 956 33
125.0588 672 23
125.0941 512 17
128.0614 2632 92
129.0687 1508 52
130.0762 588 20
131.0474 636 22
131.0843 3576 125
132.055 1244 43
132.0886 592 20
133.063 1628 56
133.1002 1756 61
134.0727 520 18
135.0791 5516 192
137.0586 368 12
137.0751 332 11
137.0946 1976 69
141.0685 1464 51
142.0758 1048 36
143.0842 4508 157
144.0554 564 19
144.0882 788 27
145.0634 4880 170
145.1 1988 69
147.079 28576 999
148.0823 3404 119
149.0219 1380 48
149.0948 1848 64
151.0734 896 31
151.1108 532 18
153.0686 760 26
153.089 856 29
155.0838 2024 70
156.09 908 31
157.0639 604 21
157.0995 2708 94
158.0709 2592 90
158.1067 316 11
159.0788 10836 378
160.083 1780 62
161.0573 616 21
161.095 5008 175
162.0977 784 27
163.0752 560 19
163.1104 500 17
165.0696 1316 46
165.0897 468 16
166.0771 388 13
167.0843 1388 48
167.1039 436 15
168.055 348 12
169.0624 1176 41
169.0995 1584 55
170.0705 852 29
171.079 15156 529
171.1152 1224 42
172.0831 2436 85
173.095 9788 342
174.0976 1392 48
175.0738 456 15
175.1104 1136 39
177.0892 940 32
178.0765 768 26
179.085 2012 70
180.0896 676 23
181.0628 696 24
181.1001 1456 50
182.0725 796 27
182.1079 404 14
183.0783 2264 79
183.1147 844 29
184.086 1100 38
185.0567 376 13
185.0945 7000 244
186.0981 1020 35
187.0739 2764 96
187.111 2576 90
188.0775 380 13
189.0681 628 21
189.0909 940 32
189.1266 320 11
190.0747 436 15
191.087 996 34
192.0912 1096 38
193.1 2736 95
194.0712 488 17
194.106 1064 37
195.0792 1908 66
195.1142 1532 53
196.0857 2068 72
196.1204 320 11
197.0941 5856 204
197.1309 732 25
198.0993 1604 56
199.0732 364 12
199.1098 2052 71
201.0879 496 17
201.1266 424 14
203.0842 668 23
204.0918 1896 66
205.0995 1272 44
206.108 948 33
207.078 628 21
207.1158 1856 64
208.0873 2656 92
208.1205 616 21
209.0945 5436 190
209.1312 1612 56
210.102 3376 118
210.1324 336 11
211.1102 6236 218
211.1491 416 14
212.1161 3080 107
213.0917 408 14
213.1266 2872 100
214.1294 688 24
215.0849 352 12
215.1052 2332 81
216.0931 516 18
216.1096 424 14
217.1016 700 24
218.108 708 24
219.0767 328 11
219.1148 2936 102
220.0871 932 32
220.1227 1032 36
221.0953 3660 127
221.1306 1152 40
222.1024 7552 264
222.1366 436 15
223.1102 9432 329
224.1172 3364 117
225.0909 476 16
225.1255 2892 101
226.0967 484 16
226.1306 1064 37
227.1053 380 13
227.1417 1452 50
228.1447 392 13
229.0994 420 14
230.1079 848 29
231.1155 796 27
232.0847 580 20
232.1223 596 20
233.0953 1448 50
233.1318 752 26
234.1029 1368 47
234.1372 388 13
235.1106 4692 164
235.1477 712 24
236.1148 2236 78
236.1592 616 21
237.126 9500 332
237.1611 804 28
238.0959 456 15
238.1305 2124 74
239.1047 1336 46
239.1424 4548 158
240.1098 308 10
241.1219 560 19
242.1192 340 11
243.1141 832 29
244.1217 692 24
245.0944 1392 48
245.1291 812 28
246.1009 988 34
246.1376 768 26
247.1107 2220 77
247.1469 612 21
248.1179 3116 108
249.1262 3668 128
249.1614 492 17
250.1309 1644 57
250.172 432 15
251.1026 300 10
251.1418 1844 64
251.1802 364 12
252.1098 332 11
252.1489 1636 57
253.1209 1424 49
253.1556 1616 56
254.1253 400 13
254.1616 348 12
255.1367 900 31
257.1317 692 24
258.1031 528 18
258.1414 316 11
259.1119 1496 52
259.1467 736 25
260.1164 1492 52
261.1264 2704 94
261.1638 868 30
262.1338 4420 154
263.1033 424 14
263.1415 7728 270
264.1115 528 18
264.1484 3380 118
265.1565 1128 39
266.1606 780 27
267.137 1092 38
267.174 328 11
271.1122 868 30
271.1464 524 18
272.1164 840 29
273.1261 748 26
273.1628 340 11
274.1359 1524 53
275.1412 1528 53
276.1493 2436 85
277.1212 328 11
277.1563 4144 144
278.1267 416 14
278.164 3560 124
279.1399 432 15
279.1724 6628 231
280.1771 1480 51
281.1535 596 20
281.186 332 11
282.1585 400 13
286.1339 1268 44
287.1353 396 13
289.157 1160 40
290.1304 316 11
290.1585 340 11
291.1361 680 23
291.1732 1096 38
292.1407 420 14
292.1779 400 13
293.1554 436 15
295.1691 632 22
296.1763 612 21
297.1835 404 14
301.157 1012 35
304.1439 408 14
306.1615 644 22
307.1677 896 31
308.1758 376 13
309.1882 308 10
319.1702 944 33
320.1706 332 11
325.1796 372 13
//
